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Ozark Mountains
Geohydrology of the four largest spring systems in the Ozarks of Missouri and Arkansas, USA
ABSTRACT The four largest spring systems in the mid-continent receive recharge through large interconnected voids in fractured and solution-weathered dolostones of the Ordovician and Cambrian systems. Cumulative thickness of the carbonate bedrock aquifer ranges up to 700 m in the Ozark region. Recharge from the surface occurs through weathered overburden, sinkholes, and losing streams and has been traced up to 60 km (straight-line horizontal distance) using fluorescent dyes. Mean discharge of the combined flow of these four spring systems is ~1400 cubic feet/second (ft 3 /s) or 40 m 3 /second (m 3 /s). All four spring systems will be visited while discussing the karst terrane that recharges them. Environmental and engineering challenges in the region will be discussed, such as wastewater treatment systems, solid waste disposal, and failed reservoirs. Hodgson Mill Spring represents a branch of the Rainbow/North Fork/Hodgson Mill System. While it receives base flow from the main system, it also receives local recharge that Rainbow and North Fork springs do not. A portion of the Mammoth Spring recharge system will be viewed at Grand Gulf State Park in Missouri, where a cave collapse has created cliffs and a natural bridge and exposed a small losing tributary that flows into a cave that has been traced to the spring. Mammoth Spring State Park in Arkansas offers a historical perspective of the development and use of large springs. Greer Spring in Missouri was used as a power source for grist, flour, and lumber mills, but has now largely returned to its predevelopment state and is managed by the U.S. Forest Service. Big Spring, featured in a former state park in Missouri, is now part of the Ozark National Scenic Riverways.
The 2021 GSA Northeastern, Southeastern, joint North-Central/South-Central, and Cordilleran Section Meet-ings were held virtually in spring 2021 during continued restrictions on travel and large gatherings due to COVID-19. Eleven groups put together field guides, taking participants on treks to states from Connecticut to Nevada in the United States, to Mexico, and to Italy, and covering topics as varied as bedrock geologic map-ping, geochemistry, paleodrainage, barrier islands, karst, spring systems, a southern Appalachian transect, Ordo-vician and Mississippian stratigraphy, high-energy events, Cretaceous arc granites and dextral shear zones, and Mesoproterozoic igneous rocks. This volume serves as a valuable resource for those wishing to discover, learn more about, and travel through these geologically fascinating areas.
Paleotopography controls weathering of Cambrian-age profiles beneath the Great Unconformity, St. Francois Mountains, SE Missouri, U.S.A.
Geochemical investigations of the Woodford–Chattanooga and Fayetteville Shales: Implications for genesis of the Mississippi Valley–type zinc–lead ores in the southern Ozark Region and hydrocarbon exploration
Tournaisian (Mississippian) Carbonate Mounds in the Ozark Region, North America and Ireland: A Comparison
ABSTRACT Mississippian (Tournaisian–Viséan) carbonate mounds in the Compton and Pierson limestones, Ozark region, North America, have been called Waulsortian. However, European Waulsortian mounds contain features such as geopetals with multigenerations of carbonate mud (polymuds) and stromatactis cavity systems that are rare to absent in Ozark mounds. To determine similarities and differences, examine their origins, and clarify nomenclature, mounds in the Compton and Pierson limestones are compared with Waulsortian mounds in the Feltrim Limestone, Ireland. Features considered included mound size, geometry, style of aggradation, composition, depositional setting, and diagenetic history. Mounds in the Compton and Pierson limestones are <10 m (33 ft) thick and form singular knoll-form or aggregates with a strong lateral growth component. In contrast, individual Waulsortian mounds in the Feltrim Limestone range from 5 to > 30 m ( 16 – 100 ft ) thick, but coalesce and vertically aggrade to form complexes that exceed 500 m ( 1600 ft ) . Pierson mounds are crinoidal and grain-rich, whereas Compton and Feltrim mounds are bryozoan-rich and mud-dominated. All mounds have similar cement stratigraphy and diagenetic histories. Mud-rich Compton mounds and Feltrim mounds are interpreted as deeper water than skeletal-rich Pierson mounds. Limited accommodation constrained Compton and Pierson mound size and forced lateral aggradation. Subsidence-driven accommodation in the Dublin Basin allowed Feltrim mounds to grow larger, coalesce, and aggrade vertically. Three types of mounds are recognized: true Waulsortian in the Feltrim Limestone, mud-cored Waulsortian-type Compton and Pierson mounds, and Pierson transported bioaccumulation mounds. Small dimensions of Waulsortian-type Pierson and Compton mounds limit their potential as oil and gas reservoirs, whereas Pierson crinoidal sediment piles are known to form reservoir-size accumulations.
ABSTRACT Four conodont biozones, including three subzones, are interpreted within a revised lithostratigraphic framework for the upper Boone Group and Mayes Group in northeastern Oklahoma and adjacent parts of Missouri, Kansas, and Arkansas. Although revised lithostratigraphy is principally based on observed lithologic characteristics and stratigraphic relationships, conodont biostratigraphic data played an important role in correlation and final organization of units. Within the upper Boone Group, Biozone 1 (lower Meramecian) includes the Ritchey Formation and the Tahlequah limestone and Biozone 2 (middle Meramecian) includes the Moccasin Bend Formation and Quapaw Limestone. The Mayes Group spans Biozone 3 and Biozone 4. Biozone 3 (upper Meramecian) is represented by the Bayou Manard Member of the Pryor Creek Formation (new name). Biozone 4 marks the appearance of definitive Chesterian conodont fauna. The lower two subzones within Biozone 4 correspond to the Lindsey Bridge (Biozone 4L) and Ordnance Plant (Biozone 4M) members of the Pryor Creek Formation, whereas the upper subzone consists of the Hindsville Formation (Biozone 4U). Documentation of conodont taxa and recognition of the proposed biozones provides relative time constraints for genetically meaningful interpretations of regional geology and subsequent evaluation of the Mayes Group and upper Boone Group within a broader interregional context.
ABSTRACT Lithologies, depositional environments, stratigraphic architecture, and conodont biostratigraphy of Lower to Middle Mississippian rocks in the western Ozarks comprise five depositional sequences in ramps on the southern Burlington shelf. Aggradational ramps in the Kinderhookian to early Osagean St. Joe group were relatively strongly overprinted by Ouachita-related tectonism involving inferred recurrent passage of fore-bulge highs and associated basins across central and southern parts of the outcrop area. Significant effects of tectonism are southward facies shallowing onto the broad Kanoka ridge paleotopographic high associated with locally extensive marine and lesser subaerial erosion, sediment thickening and deposition of generally northward down-lapping, resedimented wedges with dislodged reef blocks and conglomerates into relatively rapidly subsiding basins, and formation of a regionally extensive paleosol at the top of the group. Back-stepping subsidence due to middle Osagean foundering of the Kanoka ridge was followed by rapid, long-distance progradation of middle- and outer-ramp facies in the Bentonville and Reeds Spring limestones. Tectonism at this time resulted variously in local folding, uplift, marine and subaerial erosion, and reversal of shelf bathymetry. Southward erosion of the Reeds Spring and Bentonville occurred at least in Oklahoma on rejuvenated segments of the Kanoka ridge. Overlying lower Meramecian limestones are shallow-water deposits truncated by a major unconformity.
ABSTRACT Petrographic, geochemical, and fluid inclusion analysis of dolomite and calcite cements has been conducted on Mississippian carbonates collected from the surface and subsurface of the southern midcontinent of the United States (Oklahoma, Missouri, Kansas, and Arkansas). Fracture and vug, intergrain, and intragrain porosity are filled with calcite, authigenic quartz, and dolomite cements. Primary limestone porosity is filled partially by early marine and meteoric calcite cements. Equant (blocky) calcite cements were precipitated under seawater or mixed meteoric-seawater conditions in the phreatic zone and in the deep phreatic zone under late (burial) diagenetic conditions. Fracture- and breccia-filling saddle dolomite cements that were observed are late diagenetic and are likely related to the nearby Tri-State Mississippi Valley-type (MVT) mineral district. Carbon and oxygen isotope values of dolomite cements range from δ 18 O (VPDB) = −9.5 to −2.7‰ and from δ 13 C (VPDB) = −4.0 to −0.4‰. Values for calcite cements range from δ 18 O (VPDB) = −11.6 to −1.9‰ and from δ 13 C (VPDB) = −12.2 to +4.6‰. These values are consistent with three types of diagenetic fluids: seawater, seawater modified by meteoric water, and evolved basinal water. Analysis of fluid inclusions in late calcite, dolomite, and quartz cements indicates the presence of both dilute and high salinity end-member fluids. Homogenization temperatures (T h ) of fluid inclusions range from 57°C to 175°C and salinities range from 0 to 25 equivalent weight % NaCl. Fluid inclusion T h values and salinities are consistent with a saline basinal fluid variably diluted by fluids of meteoric or mixed seawater and meteoric origin. Petroleum inclusions were observed in late diagenetic calcite and dolomite cements.The late diagenetic cements filled porosity retained after early diagenetic cementation indicating that some original porosity in the Mississippian carbonate rocks remained open during petroleum migration. Elevated fluid inclusion T h values over a broad region, not just in the Tri-State Mineral District, imply that the regional thermal maturity of rocks may be higher than believed previously. This study indicates that the Mississippian carbonate resource play on the southern midcontinent has a very complex diagenetic history, continuing long after early diagenetic cementation. Possibly the most important diagenetic events affecting these rocks occurred during burial and basinal fluid migration through these strata.
Isotope Chemostratigraphy of the Lower Mississippian St. Joe Group in Northeastern Oklahoma and Southwestern Missouri
ABSTRACT The St. Joe group (Lower Mississippian, Tournaisian) is petrographically and isotopically analyzed using δ 13 C and δ 18 O bulk sample stable isotopes in central, northeastern Oklahoma, and southwestern Missouri. Determined to be conformable in Oklahoma, this group represents deposition in the mid- to outer-ramp setting during one long-term depositional cycle and can be used as a reference section for geochemical chronostratigraphy. Minor diagenetic alteration did not overprint the initial isotope signal, and the resulting curve is similar to those from previous studies and is integrated with published conodont biostratigraphy. The resulting correlation indicates that the St. Joe group was deposited in the upper Tournaisian Stage.
ABSTRACT The Mississippian system in the midcontinent of the United States is a complex carbonate- and chert-dominated system with a large degree of reservoir variability and heterogeneity. An outcrop study was done in the state of Arkansas on the Middle Mississippian (Visean) Burlington-Keokuk Formation to analyze the depositional setting and high-resolution sequence stratigraphic architecture to better understand the reservoir distribution of similar units in the subsurface. The outcrop location, in the northwestern portion of the state of Arkansas, was studied using an integrated sequence stratigraphic approach, combining high-resolution photography for tracing bed boundaries and lithologic contacts along with facies determination from outcrop and thin section analysis. A range of skeletal packstones to grainstones dominated by crinoidal fragments and an abundance of void-filling syntaxial calcite cements comprised the majority of the outcrop facies. Nodular to bedded siliceous limestone to carbonate-rich chert facies were observed containing up to approximately 50% microporosity. Based upon facies assemblages and the presence of meter-scale sand waves with faint cross bedding on outcrop, these units were likely deposited in a high-energy sand shoal or sand bar in a proximal position on a distally steepened ramp. Within the outcrop, multiple shoaling upward packages were observed, consisting of siliceous limestones and cherts at the bases overlain by coarsening and thickening upward grainstone bodies. This stacking pattern was observed at two different scales. Larger-scale packages 15 to 35 feet (5–10 m) thick were mappable and continuous across the entire outcrop (1320 ft [400 m]), and are inferred to be controlled by eustatic sea-level change. A smaller-scale stacking pattern was observed on the meter (several feet) scale and were mappable for 165–500 ft (50–150 m) laterally. The lack of limited lateral correlation is inferred to be due to autocyclic controls within the active sand body. The observed shoaling upward patterns create a hierarchy of stacked reservoir and seal units with superimposed variability. These findings illustrate the potential for high-frequency sea-level change and autocyclic control on facies and reservoir distribution that may be seen in the subsurface. Two-dimensional geostatistical modeling further illustrates the need for this level of characterization, as variogram inputs are biased significantly by the segregation of high-frequency sequences and dominant eustatic or autocyclic controls on deposition.
ABSTRACT Facies analysis utilizing a conodont biostratigraphic framework is a powerful tool for evaluating genetic relationships of Osagean–basal Meramecian strata within the Ozark region (Arkansas–Missouri–Oklahoma) of the southern midcontinent. This investigation builds upon previous work cited herein, and suggests that some lithostratigraphic divisions, although useful in differentiating strata in a localized setting, may not be suitable for regional correlations within the Boone Group. High-resolution conodont biostratigraphy demonstrates the diachronous nature of lithostratigraphic divisions within the Boone Group, with both the Reeds Spring Formation and Bentonville Formation (Burlington–Keokuk) clearly becoming younger as they are traced from southwestern Missouri into northern Arkansas and northeastern Oklahoma. Subsequent facies analysis shows that the Reeds Spring Formation represents deposition within outer ramp through proximal middle ramp settings (low to moderate energy), whereas the Bentonville Formation (Burlington–Keokuk) records deposition within proximal middle ramp to inner ramp settings (moderate to high energy). Integration of facies analysis and conodont biostratigraphy-based relative chronostratigraphy provides the basis for construction of four time-slice maps illustrating the distribution of time-correlative facies belts. Together, these time-slice maps deliver a clearer representation of the evolution of Boone Group carbonate ramp deposition during the Osagean, which was characterized by overall shallowing-upward and progradation to south and southwest.
ABSTRACT Late diagenesis records a common history of fluid flow in sub-Permian strata in the midcontinent, where fluid inclusion Th are higher than burial temperatures and Tm ice show evolving salinity. Most negative δ 18 O dolomite and highest Th are at the top of the Mississippian. Fluid inclusion and geochemical data point to advective fluid flow out of basins utilizing Cambrian–Ordovician–Mississippian strata as an aquifer for hydrothermal fluids. The Pennsylvanian was a leaky confining unit. This system evolved from: Stage 1 Pennsylvanian–early Permian pulsed hydrothermal migration of connate brine and gas; between Stages 1 and 2, low-temperature Permian brine reflux; Stage 2 mixing between high-temperature and low-temperature brines during the Permian; and Stage 3 large-scale migration of hydrothermal brines and oil later during the Permian or after. Stages 1–3 were the most important late processes affecting Mississippian reservoirs, and record an inverted thermal structure with most impact of hot fluids at the top of the Mississippian. Stage 4 shows radiogenic 87 Sr/ 86 Sr in calcite, supporting a transition to localized fault pumping from basement, likely driven by Laramide fault reactivation. Stage 5 is the current system, with Ozark and Front Range uplift-driven fluid flow and potential for small-scale sporadic fault pumping.
Abstract: A comprehensive study of the Cambrian–Ordovician Arbuckle Group suggests that multiple fluid migration events have affected reservoir porosity via fractures and preferred stratigraphic horizons. Fluid inclusion homogenization temperatures from late-stage precipitates yield temperatures higher than can be explained by burial conditions or an elevated geothermal gradient. Fluid inclusion melting temperatures yield salinity values that indicate multiple fluids evolving through time. Hydrocarbon fluid inclusions in late-stage baroque dolomite suggest oil migration concurrent with hydrothermal fluid flow. Depleted δ 13 C and δ 18 O values provide evidence for a high-temperature basinal fluid source as well as for the preferential flow of hydrothermal fluids through permeable zones in the Mississippian and Arbuckle Group, where pore systems related to paleokarst are overlain by less permeable units. Radiogenic strontium isotopic data support fluid–rock interaction with siliciclastic material or basement rock at some point during the fluid migration history. Variable 87 Sr/ 86 Sr values suggest multiple sources for the fluids responsible for the cements and a transition from an advective fluid flow system to a vertical fluid flow system. The ancient aquifer system was vertically connected during migration of hydrothermal fluids, and a temperature-controlled vertical density gradient appears to have played an important role in late-stage porosity evolution, focusing the hottest fluids in the upper sections of permeable layers.
Thermochronology links denudation of the Great Unconformity surface to the supercontinent cycle and snowball Earth
A Quality Control Method for Teleseismic P ‐Wave Receiver Functions
Long-Term Leachate Water Quality Trends from a Broiler-Litter-Amended Udult in a Karst Region
Sulfamethazine Transport in Agroforestry and Cropland Soils
2-D and 3-D Resistivity Imaging of Karst Sites in Missouri, USA
Abstract This field trip provides an overview of geological features in southwestern Missouri that are related to the American Civil War and to human culture. This includes the geology and history of the Wilson’s Creek National Battlefield (where the second important battle of the American Civil War was fought on 10 August 1861), Zágonyi’s Charge (25 October 1861), the Battle of Springfield (8 January 1863), and the gravestones and monuments of the National Cemetery in Springfield in which many of those who fought at Wilson’s Creek and other Civil War conflicts are buried. Other stops include the Springfield Underground and the quarries and facilities at what was once the town of Phenix (which, along with Carthage, Missouri, was the home of some of the largest dimension-stone quarries west of the Mississippi River); and a reconstructed mill site in Point Lookout, just south of Branson. Most of the field trip involves outcrops, quarries, and bedrock composed of the Mississippian Burlington-Keokuk limestones (undivided), providing numerous chances to examine outcrops and products made of limestone and chert.
Civil War and cultural geology of southwestern Missouri, part 2: Geologic influences on the Battle of Forsyth, guerrilla activities, and post-war vigilantism
Abstract Climate and terrain, especially stream drainage basins and topography, greatly influenced European-American settlement patterns, agricultural practices, transportation networks, and the cultural and economic development of the southern Missouri Ozarks from the early 1800s to the American Civil War (1861-1865). These also were key factors, together with land cover and natural resources, that predicated the course of military operations and tactics during the war. The same factors affected widespread partisan conflicts during the war and vigilantism during the Bald Knob-ber era, a mid-1880s cultural extension of the Civil War in Taney, Christian, Douglas, and Stone counties. This field trip will examine the geology of selected areas in and around Branson in southwestern Taney County and integrate historical events and anecdotes, which illustrate the influence of geologic factors.