Abstract In Groundwater-Dependent Terrestrial Ecosystems (GWDTEs), atmospheric nitrogen (N) inputs have often been studied in isolation from terrestrial groundwater and surface water inputs. We describe for the first time the development and application of a combined atmospheric and terrestrial N source apportionment methodology, able to identify contributing catchment and N loadings to GWDTEs. We combined all N inputs using a site-specific conceptual model supported by 12 months’ monitoring for a Chalk-fed GWDTE at Newbald Becksies, East Yorkshire. We discuss implications for effective catchment management, wetland protection and development of a source apportionment methodology. Potential sources of nitrate include: atmospheric deposition, mineralization, leaching from agricultural soils, manure heaps, septic tanks, sewer and mains water leakage. Atmospheric deposition was calculated from measurements of ammonia and nitrogen dioxide concentrations together with rainfall inputs of ammonium and nitrate. Quantification of agricultural sources used the FarmScoper modelling tool to estimate nitrate leaching in the groundwater catchment. Comparison between modelled nitrate concentrations in leachate (15–17 mg N l −1 ) and observed groundwater nitrate concentrations (12.3–19.8 mg N l −1 ) are good. The majority of nitrate is leached from arable land. FarmScoper allows mitigation scenarios to be tested, supporting measures to reduce nitrate within a groundwater catchment.

The end-Permian mass extinction was associated with the onset of anoxia in widespread marine environments; however, the extent of this anoxia remains controversial. Proposed models range from near-universal “superanoxia” in the Panthalassic Basin to a more limited expansion of anoxia in the upper water column in response to enhanced primary productivity. The Peck Creek and Ursula Creek sections of northern British Columbia were deposited at ~200 m water depth in the Ishbel Trough, on the margin of cratonic North America. This trough was generally contiguous with the Slide Mountain Ocean, and thus with the broader Panthalassic Ocean, though it may have been partially separated by structural highs at various times during the Permian. Both sections include continuous Wordian to Changhsingian sedimentary successions, which span the end-Permian mass extinction boundary and continue into the earliest Triassic. The extinction is recognizable as the disappearance of biogenic silica from the environment, which defines the contact between the Fantasque Formation and overlying Grayling Formation. This surface also corresponds with the onset of anoxia, and the accumulation of redox-sensitive trace metals. The covariation trends in these metals, and in other isotopic proxies, can be used as tools to trace the degree of communication between the Ishbel Trough–Slide Mountain Ocean and the broader Panthalassic Basin. Molybdenum-uranium covariation trends indicate that the northern Slide Mountain Ocean and Ishbel Trough remained in communication with the larger global ocean throughout this interval, suggesting inversion of the Wordian structural high to form a depositional subbasin by the Changhsingian. This is in contrast to the Opal Creek section of southern Alberta, which shows evidence for some degree of restriction, suggesting that the Slide Mountain Ocean may have maintained a north–south gradient in water chemistry. Several lines of evidence suggest that this onset of anoxia was not related to expansion of an upwelling-driven oxygen minimum zone. No clear changes in primary productivity, as recorded by organic carbon or authigenic phosphorus and barium, are observed across the extinction horizon. Changhsingian nitrogen isotope values are generally in the 2 to 3‰ range, suggesting minimal denitrification at thermocline water depths, and these values decreased in the earliest Triassic, likely in response to enhanced nitrogen fixation. This suggests that anoxia was driven by shoaling of a chemocline that developed due to stratification of the Slide Mountain Ocean, rather than western-boundary upwelling effects.