ABSTRACT Two late Eocene impact spherule layers are known: the North America microtektite layer (from the Chesapeake Bay crater) and the slightly older clinopyroxene (cpx) spherule layer (from Popigai crater). Positive Ir anomalies occur at 5.61 m and 6.19 m above the base of a late Eocene section at Massignano, Italy. The age difference between the two anomalies is ~65 ± 20 k.y. The older Ir anomaly at 5.61 m appears to be associated with the cpx spherule layer. Although no impact spherules or shocked-mineral grains have been found associated with the upper Ir anomaly at 6.19 m, it has been proposed that it may be from the Chesapeake Bay impact. Comparison with other distal ejecta layers suggests that microtektites, but not shocked-mineral grains, from the Chesapeake Bay crater could have been thrown as far as Massignano. However, their absence neither supports nor disproves the hypothesis that the Ir anomaly at 6.19 m is from the Chesapeake Bay impact. On the other hand, the North American microtektite layer is not associated with an Ir anomaly. Furthermore, the average age difference between the cpx spherule layer and the North American microtektite layer appears to be ~18 ± 11 k.y., which is nearly one quarter the age difference between the two Ir anomalies at Massignano. This indicates that the Ir anomaly at 6.19 m is too young to be from the Chesapeake Bay impact, and thus is most likely not from the Chesapeake Bay impact.

ABSTRACT We measured stratigraphic sections and collected samples from Oceanic suite outcrops at Gay’s Cove and Bath Cliffs, Barbados, in order to restudy the late Eocene microtektite layer(s) and provide new geological context. We disaggregated and processed samples into separates of microfossils, microtektites, and heavy minerals, and we present up-to-date glass geochemistry, biostratigraphic analysis, and detrital zircon U-Pb analysis. Results from the new Barbadian microtektite glass chemistry analysis (Gay’s Cove) compare well with those from other published microtektite analyses, as well as those from the correlative North American strewn field. Micropaleontology confirms a late Eocene age for the Oceanic microtektite horizon at Gay’s Cove. Using U-Pb, we dated 24 Tertiary zircon grains, probably from volcanic ash-fall events, which at Gay’s Cove yielded a preliminary, poorly defined, and incorrect depositional age for the microtektite layer (≤31.84 ± 0.85 Ma; weighted mean of only three grains). Three additional new U-Pb depositional ages (≤38.52 ± 1.0 Ma, ≤39.23 ± 0.3 Ma, ≤35.25 ± 0.82 Ma) were obtained from bottom to top in the 24 m section at Bath Cliffs. We also dated 46 Paleozoic–Proterozoic zircon grains using U-Pb and discuss whether these “old” grains represent recycled (subducted and extruded) volcanic grains or windblown silt/sand from Africa.

The iron oxidation state and coordination number have been determined by Fe K-edge X-ray absorption–near edge spectroscopy (XANES) for six tektites from the North American tektite strewn field (four bediasites and two georgiaites) and a tektite fragment from the Deep Sea Drilling Project (DSDP) Site 612, which is part of the North American tektite strewn field. All tektite samples display a pre-edge peak, the components of which are consistent with the presence of divalent Fe. Comparison of pre-edge peak data (integrated intensity and centroid energy) with those of Fe model compounds allows us to quantitatively determine the Fe oxidation state and coordination number. The Fe 3+ /(Fe 2+ + Fe 3+ ) ratio is close to 0.05 (±0.03), consistent with tektites from all the other strewn fields. The average Fe coordination number is intermediate between 4 and 5. Accurate determination of this value is hindered by the scatter of pre-edge peak intensity of all the Fe model compounds; [4] Fe/( [4] Fe + [5] Fe) is estimated to be 0.26 ± 0.15. In contrast to North American microtektites, for which iron oxidation state and coordination numbers display significant variations across the North American strewn field, no significant variations in the Fe oxidation state and coordination number were found between the georgiaites, bediasites, and the DSDP 612 tektite fragment. It is remarkable that the tektite fragment from the DSDP 612 site showed no sign of oxidation despite the long burial period in marine sediments.

Multiple bolide impact events, possibly related to a comet or asteroid shower over a duration of ~2–3 m.y., may have played an important role in the deterioration of the global climate at the end of the Eocene. Upper Eocene marine sediments around the world contain evidence for at least two closely spaced impactoclastic layers, i.e., layers containing impact debris such as tektites and microtektites, shocked minerals, and rock fragments. The upper layer correlates with the North American tektite strewn field (mostly on the eastern side of North America), and the 85-km-diameter Chesapeake Bay crater (USA) has been suggested as its source crater, whereas the lower, microkrystite layer (with clinopyroxene-bearing spherules) was most likely derived from the 100-km-diameter Popigai impact crater (Russia). In summary, at least five impact structures with late Eocene ages are known. Disturbances in the climate at that time are documented, and connection with the impact events is likely. This contribution provides a short review of late Eocene impact craters and ejecta layers.

In order to better define the late Eocene clinopyroxene-bearing (cpx) spherule layer and to determine how the ejecta vary with distance from the presumed source crater (Popigai), we searched for the layer at 23 additional sites. We identified the layer at six (maybe seven) of these sites: Deep Sea Drilling Project (DSDP) and Ocean Drilling Program (ODP) Holes 592, 699A, 703A, 709C, 786A, 1090B, and probably 738B. The cpx spherule layer occurs in magnetochron 16n.1n, which indicates an age of ca. 35.4 ± 0.1 Ma for the layer. We found the highest abundance of cpx spherules and associated microtektites in Hole 709C in the northwest Indian Ocean, and we found coesite and shocked quartz in the cpx spherule layer at this site. We also found coesite in the cpx spherule layer at Site 216 in the northeast Indian Ocean. This is the first time that coesite has been found in the cpx spherule layer, and it provides additional support for the impact origin of this layer. In addition, the discovery of coesite and shocked quartz grains (with planar deformation features [PDFs]) supports the conclusion that the pancake-shaped clay spherules associated with quartz grains exhibiting PDFs are diagenetically altered cpx spherules. An Ir anomaly was found associated with the cpx spherule layer at all four of the new sites (699A, 709C, 738B, 1090B) for which we obtained Ir data. The geometric mean of the Ir fluence for the 12 sites with Ir data is 5.7 ng/cm 2 , which is ~10% of the fluence estimated for the Cretaceous-Tertiary boundary. Based on the geographic distribution of the 23 sites now known to contain the cpx spherule layer, and 12 sites where we have good chronostratigraphy but the cpx spherule layer is apparently absent, we propose that the cpx spherule strewn field may have a ray-like distribution pattern. Within one of the rays, the abundance of spherules decreases and the percent microtektites increases with distance from Popigai. Shocked quartz and coesite have been found only in this ray at the two sites that are closest to Popigai. At several sites in the Southern Ocean, an increase in δ 18 O in the bulk carbonate occurs immediately above the cpx spherule layer. This increase may indicate a drop in temperature coincident with the impact that produced the cpx spherule layer.

Crowleys Ridge in southeastern Missouri preserves Cretaceous to Eocene marginal marine sediments deposited in the northwestern portion of the Mississippi Embayment. Sandwiched between the Paleocene Porters Creek Formation and the uppermost Cretaceous Owl Creek Formation is the Paleocene Clayton Formation. Four trenches were excavated and a complete section of Clayton Formation was sampled at a large strip mine in Stoddard County, Missouri. The Clayton at this location consists of 185 cm of graded deposit, the lower part of which includes large Owl Creek rip-up clasts containing layers of microtektites, invertebrate fossils, and abundant terrestrial and marine palynomorphs. Driller's logs and electric logs covering ∼9000 km 2 were reviewed. Well data confirm the consistent thickness and lithology of the Clayton Formation in this part of the Mississippi Embayment. Based on sedimentological and palynological data from this study, the Clayton Formation in the northwestern Mississippi Embayment appears to be a megatsunami deposit resulting from post-impact effects (early Paleocene) associated with the Chicxulub impact event.