ABSTRACT The Edwards aquifers are typically faulted, karstified, and transmissive. Water quality is generally excellent; the hydrochemical facies is mostly a calcium bicarbonate water with total dissolved solids (TDS) <500–1000 mg/L. Exceptions to this result from both natural and anthropogenic factors. In the Edwards Plateau, mixing of the formation water with underlying water from the Trinity aquifers or Permian rocks increases salinity to the west. Along the Balcones fault zone, the southern and eastern borders of the Edwards (Balcones Fault Zone) Aquifer are demarcated by a bad-water line where salinity rises to over 1000 mg/L. Detailed studies show that this line is a band, because salinities in the aquifer are not uniform with depth. The bad-water (or saline-water) zone is relatively stable over time, and six hydrochemical facies were identified, which are created by different combinations of dissolution of evaporite and other minerals, mixing with basinal brines, dedolomitization, and cross-formational flow from underlying formations. Flow in this zone is restricted, the waters are reducing, and recent studies suggest that microbes play important chemical and physical roles. The bad-water zone has sufficient water in storage and sufficient permeability so that desalination could be a future water-source option.

ABSTRACT Geophysical methods have been an important component of effective hydrogeologic investigations over the Edwards and Trinity Aquifers in central Texas. Various electrical and electromagnetic methods have been used to map stratigraphy and geologic structure and to locate buried karst features. Geophysical methods can also characterize faults and fractures in the Balcones fault zone. Six case studies across three segments (San Antonio, Barton Springs, and Northern segments) of the Edwards Aquifer show that the locations of buried caves and sinkholes, on all three segments, are best defined using a combination of two- and three-dimensional resistivity imaging and natural potential (self-potential) methods. Localization and characterization of the Haby Crossing and Mount Bonnell faults, which are known to be the most significant faults in the Balcones fault zone, are best accomplished by integrating multiple geophysical methods (e.g., electrical resistivity, natural potential, magnetic, ground-penetrating radar, conductivity, and seismic refraction tomography). It is noted, however, that other karstic regions could respond differently to different geophysical methods and require different primary geophysical methods.