ABSTRACT The Cretaceous and Paleogene pelagic limestone and marl formations of the Umbria-Marche Apennines of north-central Italy have proven to be exceptional recorders of the history of Earth and of life on Earth, and they have been the subject of numerous geological and paleontological studies over the last several decades. Founded a quarter century ago, in 1992, the Geological Observatory of Coldigioco is a research and teaching center focused on these exceptional rocks. This chapter is a historical introduction that briefly reviews the highlights of the lithologic, biostratigraphic, sedimentologic, magnetostratigraphic, impact-stratigraphic, geochemical, geochronological, time-scale, and cyclostratigraphical research done on the Umbria-Marche stratigraphic sequence, much of it facilitated by the Geological Observatory of Coldigioco. This review covers work up to the Coldigioco 25th anniversary Penrose conference in September 2017; it does not treat work presented at that conference or done since then. A remarkable irony is that a century ago, the Umbria-Marche Cretaceous–Paleogene sequence was so difficult to date that early work contained an error of ~35 m.y., but now there is a reasonable hope that this entire section may eventually be dated to an accuracy and precision of ~10,000 yr. This review begins with an homage to the little medieval city of Gubbio, its wild Festa dei Ceri, and its Bottaccione Gorge, where much of the research described here has been done. The review ends with three points of perspective. The first is the notion that sometimes geology can be done by looking up at the sky, and astronomy can be done by looking down at Earth, with much of the Coldigioco-based research being of this latter kind. The second is the observation that geology and paleontology are contributing far more new information to Big History—to our integrated knowledge of the past—than any other historical field in the humanities or sciences. The third is that three of the major scientific revolutions of geology in the twentieth century have direct connections to the Umbria-Marche stratigraphic sequence—the turbidite revolution, the development of plate tectonics, and the downfall of strict uniformitarianism.

ABSTRACT The geometry of collisional mountain belts, which were formed at the expense of passive continental margins, is often complex because orogenic structures, such as thrusts and related folds, commonly interfere with pre-orogenic extensional structures, namely, normal faults, resulting in kinematically complex, composite structural assemblages. In these settings, analysis of the relationships between depositional and structural features may provide very useful tools to correctly unravel the local sedimentary and deformational history and relative ages of structures. Analysis of the relationships between minor normal faults and slumps near Frontale in the Umbria-Marche Apennines of Italy made it possible to correctly unravel the local chronology of events and hence to infer the depositional and deformation history of a part of the Upper Cretaceous–Paleogene Scaglia Rossa Formation pelagic basin. The results of this investigation made it possible to ascribe the normal faults to events that predate the construction of the Umbria-Marche mountain belt. Therefore, the normal faults at Frontale are distinct from those that overprint the main compressional structures responsible for the present-day seismicity of central Italy.

ABSTRACT Dating detrital zircon grains from sands and sandstones has become an important geological technique for determining sediment provenance and dispersal patterns. Here, we report what we believe to be the first provenance study of zircon grains extracted by dissolving large samples of pelagic limestone. Our samples come from the Paleocene section of the Umbria-Marche Apennines, Italy. Recovery of these zircon grains was a fortunate by-product of a study on chromite grains aimed to determine the kinds of meteorites that have fallen on Earth through time. The zircons we recovered included both euhedral crystals interpreted as airborne ash from volcanic eruptions of the same age as the sediment in which they were found, and rounded grains interpreted as windblown detrital material with a history of sediment transport, probably derived from desert regions. This study focuses on the rounded grains, to provide constraints on the source region from which they came. Samples from five levels in the 12 m immediately above the Cretaceous-Paleogene boundary at Gubbio, Italy, yielded detrital zircon grains with ages clustered in eight bands extending back to the Neoarchean. A previous study of this outcrop using proxies for the noncarbonate detrital content had suggested a source region for this dust either in North Africa or in Central Asia. A comparison of our dates from the actual dust grains to geochronological studies from the literature suggests source regions in North Africa and/or the Iberian Peninsula, rather than in Central Asia. In reaching this conclusion, we considered the orogenic events that may have produced each of the eight age bands, the specific source regions that may have supplied zircons from each age group, and the implications for paleoclimate (especially aridity) and paleowind conditions for the few million years just after the Cretaceous-Paleogene boundary.

ABSTRACT The objective of this research was to determine the age relationships between Early Jurassic sedimentary units in the Umbria-Marche Apennines using strontium isotope stratigraphy. These age relations are critical for evaluating the mechanism by which the small platforms in the region formed. I present an alternative model for carbonate platform differentiation and evolution based on the strontium isotope data; this model relies primarily on growth of individual small platforms through differential sediment accumulation rather than the generally accepted model of extensive late-stage faulting. Strontium isotope stratigraphy provides a high-resolution correlation tool for the region. Because 87 Sr/ 86 Sr values steadily decrease in the Hettangian–Pliensbachian section of the Early Jurassic, they illuminate relationships in different carbonate facies very well. This is particularly valuable where physical and/or biostratigraphic correlation is difficult, such as in the Umbria-Marche carbonate platforms. Strontium isotopic ratios from measured basinal stratigraphic sections along the Burano and Bosso Rivers indicate that at least a 100 m section of the Corniola Formation was deposited while adjacent platforms continued to grow. The small Umbria-Marche platforms drowned synchronously in the late Sinemurian, based on 87 Sr/ 86 Sr values from several platforms at the end of Calcare Massiccio Formation deposition. Measured 87 Sr/ 86 Sr values for all platforms are the same within error. These stratigraphic relationships indicate that differentiation into shallow- and deep-water facies occurred in the latest Triassic/earliest Jurassic, early in the development of the margin. Current models explain the differentiation of platforms and basins by late-stage extensive normal faulting, requiring hundreds of meters of stratigraphic throw. Large-displacement faults are not consistent with the age relations determined by strontium isotope stratigraphy in the region. Minor faulting in the Late Triassic coupled with growth by differential sediment accumulation of small, shallow-water carbonate platforms continuing for several million years would produce the exposed platform/basin relationships. Inferred accumulation rates for the platform and basin sequences suggest that the observed relief of the platform escarpments was generated in less than 7 m.y., a time period consistent with the documented stratigraphy in the region.

ABSTRACT In the Umbria-Marche Apennines, direct evidence of earthquakes (including data from geodetic, geophysical, historical, and paleoseismological research) is not older than 20–10 ka, but the events themselves are influenced by the whole ~250 m.y. geological history of the region. For seismic sequences that have occurred in the past few decades, seismological data of increasing quality provide detailed images of the active NNW-SSE–trending normal fault systems in the upper 10 km of the crust. Major historical earthquakes and sparse paleoseismological data are also aligned parallel to the same lineaments, which clearly define the distribution of the major seismogenic sources of the region. The close connection between active tectonics and older Quaternary faults that border a series of extensional intramountain basins is demonstrated by the fact that seismogenic and Quaternary faults are distributed along the same alignments, formed within similarly oriented stress fields, and accommodate WSW-ENE extension coherently with the active strain field. The Quaternary to present tectonics form part of a long-lived extensional process, active over 15–20 m.y., which is migrating eastward through time across the Italian peninsula, superimposed on the previous compressional phase that created the Apennines. The older Umbria-Marche geological history, recorded in the Triassic to Paleogene stratigraphic succession of the region, also influences the present-day distribution of seismicity. Specifically, the complex mechanical stratigraphy of the region determines the superposition of rocks with different rheological behaviors and overall thickness of the seismogenic layer. Almost all of the earthquakes occur within the sedimentary cover, with main shocks located close to the basal contact with the underlying Paleozoic basement.

ABSTRACT The Popigai (100 km in diameter) and the Chesapeake Bay (40–85 km diameter) impact structures formed within ~10–20 k.y. in the late Eocene during a 2 m.y. period with enhanced flux of 3 He-rich interplanetary dust to Earth. Ejecta from the Siberian Popigai impact structure have been found in late Eocene marine sediments at numerous deep-sea drilling sites around the globe and also in a few marine sections outcropped on land, like the Massignano section near Ancona in Italy. In the Massignano section, the Popigai layer is associated with an iridium anomaly, shocked quartz, and abundant clinopyroxene-bearing (cpx) spherules, altered to smectite and flattened to “pancake spherules.” The ejecta are also associated with a significant enrichment of H-chondritic chromite grains (>63 μm), likely representing unmelted fragments of the impactor. The Massignano section also contains abundant terrestrial chrome-spinel grains, making reconstructions of the micrometeorite flux very difficult. We therefore searched for an alternative section that would be more useful for these types of studies. Here, we report the discovery of such a section, and also the first discovery of the Popigai ejecta in another locality in Italy, the Monte Vaccaro section, 90 km west of Ancona. The Monte Vaccaro section biostratigraphy was established based on calcareous nannoplankton, which allowed the identification of a sequence of distinct bioevents showing a good correlation with the Massignano section. In both the Monte Vaccaro and Massignano sections, the Popigai ejecta layer occurs in calcareous nannofossil zone CNE 19. The ejecta layer in the Monte Vaccaro section contains shocked quartz, abundant pancake spherules, and an iridium anomaly of 700 ppt, which is three times higher than the peak Ir measured in the ejecta layer at Massignano. In a 105-kg-size sample from just above the ejecta layer at Monte Vaccaro, we also found an enrichment of H-chondritic chromite grains. Because of its condensed nature and low content of terrestrial spinel grains, the Monte Vaccaro section holds great potential for reconstructions of the micrometeorite flux to Earth during the late Eocene using spinels.

ABSTRACT Results from laboratory analyses of thermophysical properties and mineralogical composition of rocks belonging to the main geological formations of the Umbria-Marche stratigraphic succession are presented. We carried out measurements of thermal conductivity, porosity, and density. The samples were mineralogically characterized by means of powder X-ray diffraction and by calcimetry. Scanning electron microscope analyses were conducted to ascertain the absence of mineralized veins, which could have biased the mineralogical composition. A mixing model was also applied to infer the thermal conductivity. The results can be useful to characterize the behavior of shallow geothermal systems in the study region.

ABSTRACT The complete and well-studied pelagic carbonate successions from the Umbria-Marche basin (Italy) permit the study of the event-rich stratigraphic interval around the Cretaceous-Paleogene boundary (e.g., Deccan volcanism, boundary impact, Paleocene recovery, and climate). To test the robustness of various proxy records (bulk carbonate δ 13 C, δ 18 O, 87 Sr/ 86 Sr, and Ca, Fe, Sr, and Mn concentrations) inside the Umbria-Marche basin, several stratigraphically equivalent sections were investigated (Bottaccione Gorge, Contessa Highway, Fornaci East quarry, Frontale, Morello, and Petriccio core). Besides the classical Gubbio sections of Bottaccione and Contessa, the new Morello section is put forward as an alternative location for this stratigraphic interval because it is less altered by burial diagenesis. Elemental profiles (Ca, Fe, Sr, Mn) acquired by handheld X-ray fluorescence (pXRF) efficiently provide regional chemostratigraphic and paleoenvironmental information. The Deccan volcanism, the Cretaceous-Paleogene boundary, the characteristic pattern of the Sr/Ca profile across the boundary driven by the extinction and recovery of coccolithophores, and the Dan-C2 hyperthermal event are examples of such recorded paleoenvironmental events. Moreover, cyclostratigraphic analyses of proxies of detrital input (magnetic susceptibility and Fe concentrations) show the imprint in the sedimentary record of a 2.4 m.y. eccentricity minimum around 66.45–66.25 Ma, and suggest that the occurrence of the Dan-C2 hyperthermal event was astronomically paced.

ABSTRACT The present-day ocean-climate system configuration took shape during the Miocene Epoch. Toward the end of the epoch, in the late Tortonian at ca. 8.5 Ma, there was an exceptional event: collisional disruption of an >150-km-diameter asteroid, which created the Veritas family of asteroids in the asteroid belt. This event increased the flux of interplanetary dust particles rich in 3 He to Earth and probably caused a period of increased dust in the atmosphere, with consequent alteration of global and local environmental conditions. A late Miocene 3 He anomaly likely related to the Veritas event has been registered in deep-sea sediments from Ocean Drilling Program (ODP) Site 926 (Atlantic Ocean), ODP Site 757 (Indian Ocean), and in the late Tortonian–early Messinian Monte dei Corvi section near Ancona, Italy. Here, we report the results of a study in the Monte dei Corvi section aimed to recover extraterrestrial chrome-spinel grains across the 3 He anomaly interval, as has been done for the similar late Eocene 3 He anomaly in the nearby Massignano section. In this study, three ~100 kg samples were collected from the Monte dei Corvi section: two within the 3 He peak interval and one outside the anomaly interval as a background reference sample. In total, 1151 chrome-spinel grains (>63 µm) were recovered, but based on chemical composition, none of the grains has a clear extraterrestrial origin. This supports the inference that the 3 He anomaly is indeed related to the Veritas event and not to an approximately coeval breakup of a smaller H-chondritic body in the asteroid belt, an event registered in meteoritic cosmic-ray exposure ages. Spectral studies of the Veritas asteroids indicate that they are made up of carbonaceous chondritic material. Such meteorites generally have very low chrome-spinel concentrations in the grain-size range considered here, contrary to the very chromite-rich ordinary chondrites. The terrestrial grains recovered were classified, and their composition showed that all the grains have an ophiolitic origin with no substantial compositional and distributional change through the section. The source area of the terrestrial grains was probably the Dinarides orogen.

ABSTRACT In this paper, we present a case study to demonstrate the potential of photogrammetry in cyclostratigraphic applications. To this end, we considered an ~300-m-thick section exposing the Lower Jurassic Calcare Massiccio Formation in the Marche Apennines of central Italy. The Calcare Massiccio comprises a thick succession of peritidal shallow-water carbonates displaying a prominent sedimentary cyclicity, where supratidal and subtidal facies alternate. The section investigated in this study is exposed on the wall of an active quarry and is almost completely inaccessible because it is vertical and because of safety and liability regulations. This setting prevents the application of standard sampling and facies analysis techniques on the whole series. An accurate three-dimensional model of the quarry wall was therefore produced by processing ~360 digital images through photogrammetry and generating a high-resolution (centimeter-scale) point cloud of the outcrop with red-green-blue (RGB) values associated with each point. An ~150-m-long log representing color variations on a continuous portion of the exposed succession was then extracted from the point cloud by converting the original RGB values to grayscale values. The main facies were directly investigated in an ~10-m-long accessible section that was logged and sampled, and it was established that supratidal facies with planar stromatolites and teepee structures are darker in color, while subtidal facies, made of bioturbated mudstones to floatstones with gastropods and oncoids, display lighter color. This provided ground-truth data with which to interpret the grayscale variations in terms of facies alternations. Time-series analysis was then carried out on the grayscale series, and this revealed prominent cyclicities. Because the biochronostratigraphic framework of the Calcare Massiccio is poor, the potential orbital origin of these frequencies was tested with the average spectral misfit technique. Preliminary results suggest that the observed spectral features are compatible with Milankovitch periods and that astronomical forcing might have been a major driver in the deposition of the Calcare Massiccio Formation. Furthermore, they testify to the great potential of photogrammetry in cyclostratigraphic applications, especially when large-scale, inaccessible outcrops have to be investigated.

ABSTRACT Two late Eocene impact spherule layers are known: the North America microtektite layer (from the Chesapeake Bay crater) and the slightly older clinopyroxene (cpx) spherule layer (from Popigai crater). Positive Ir anomalies occur at 5.61 m and 6.19 m above the base of a late Eocene section at Massignano, Italy. The age difference between the two anomalies is ~65 ± 20 k.y. The older Ir anomaly at 5.61 m appears to be associated with the cpx spherule layer. Although no impact spherules or shocked-mineral grains have been found associated with the upper Ir anomaly at 6.19 m, it has been proposed that it may be from the Chesapeake Bay impact. Comparison with other distal ejecta layers suggests that microtektites, but not shocked-mineral grains, from the Chesapeake Bay crater could have been thrown as far as Massignano. However, their absence neither supports nor disproves the hypothesis that the Ir anomaly at 6.19 m is from the Chesapeake Bay impact. On the other hand, the North American microtektite layer is not associated with an Ir anomaly. Furthermore, the average age difference between the cpx spherule layer and the North American microtektite layer appears to be ~18 ± 11 k.y., which is nearly one quarter the age difference between the two Ir anomalies at Massignano. This indicates that the Ir anomaly at 6.19 m is too young to be from the Chesapeake Bay impact, and thus is most likely not from the Chesapeake Bay impact.

ABSTRACT This study provides a composite record of 87 Sr/ 86 Sr, δ 18 O, and δ 13 C for three sections in the Tethyan Lower Cretaceous Maiolica formation, a pelagic limestone from the Umbria-Marche Apennines of Italy, carefully tied to a magnetostratigraphically and biostratigraphically calibrated time scale. Although the 87 Sr/ 86 Sr record accurately follows the trend of the global marine 87 Sr/ 86 Sr reference curve, individual Sr isotope ratio values are relatively high for their inferred stratigraphic position, with all 87 Sr/ 86 Sr ratios yielding a fairly uniform +0.00007 to +0.0001 discrepancy. This offset likely results from incorporation of excess 87 Sr through isotopic reequilibration with interstitial pore waters during progressive lithification of the calcareous ooze. Although the process occurs principally through dissolution-reprecipitation, buffering the contemporaneous seawater Sr isotopic signature, diffusive communication with the overlying water column and porous sediments will compete with the dissolution-precipitation process, homogenizing pore-fluid concentrations and isotope ratios throughout the sediment column. Because the secular trend in 87 Sr/ 86 Sr throughout the Maiolica time frame is one of constant increase before rebounding to lower 87 Sr/ 86 Sr ratios in the Barremian, the ratios of the Maiolica carbonates are systematically displaced from that of the seawater in which they were deposited toward more radiogenic (higher 87 Sr/ 86 Sr) values. In addition, the carbon and oxygen isotope record of the Maiolica limestone allows identification of the mid-Valanginian Weissert event, characterized by a positive excursion in the δ 13 C and the δ 18 O records. Furthermore, the Weissert event correlates with a positive spike (+0.0001) in 87 Sr/ 86 Sr. Both the Sr and O isotopic peak signals predate the maximum peak in the δ 13 C excursion. This is likely a diagenetic artifact and may support the hypothesis of diffusive communication during lithification of the calcareous ooze.

ABSTRACT The Umbria-Marche Apennine range, part of the Northern Apennines of Italy, is a classic example of a fold-and-thrust belt developed at the expense of a formerly rifted, passive continental margin that experienced various degrees of postorogenic extension and/or collapse. This setting comprises the outer zones of the Northern Apennines, a collisional orogen, and their adjacent Adriatic foreland domain, where the effects of superposed deformations are mild to very mild, making it possible to recognize and separate structures produced at different times and to correctly establish their relative chronology and time-space relationships. In this paper, we integrated subsurface data (seismic reflection profiles and well logs) and surface structural field evidence with the aim to reconstruct and refine the structural evolution of these two provinces, the Umbria-Marche Apennine range and adjacent Adriatic foreland, which were subject to repeated pulses of alternating extension and compression. The main outcome of this investigation is that the tectonic evolution of the study area may be effectively described in terms of a deformation history characterized by structural inheritance, where structures emanating from the basement and developed during the pre-orogenic rifting stage were effective in controlling stress localization along faults affecting younger sedimentary cover rocks during the subsequent orogenic and postorogenic events.

ABSTRACT The late Eocene was marked by multiple impact events, possibly related to a comet or asteroid shower. Marine sediments worldwide contain evidence for at least two closely spaced impactoclastic layers. The upper layer might be correlated with the North American tektite-strewn field (with the 85-km-diameter Chesapeake Bay impact structure [USA] as its source crater), although this is debated, whereas the lower, microkrystite layer (with clinopyroxene [cpx]-bearing spherules) was most likely derived from the 100-km-diameter Popigai impact crater (Russia). The Eocene-Oligocene global stratotype section and point is located at Massignano, Italy, and below the boundary, in the late Eocene, at the 5.61 m level, shocked quartz and pancake-shaped smectite spherules that contain (Ni- and Cr-rich) magnesioferrite spinel crystals are found. These are associated with a positive Ir anomaly in deposits with the same age as the Popigai-derived cpx spherule layer. This layer is overlain by another Ir-rich layer, likely due to another large impact event. From a large amount of “pancake-bearing” rock, we isolated a few hundred milligrams of this spinel-rich material. The tungsten isotopic composition of this material shows more or less a terrestrial composition. However, the spinel-rich materials have excess 54 Cr values (expressed as ε 54 Cr, which is the per ten thousand deviation of the 54 Cr/ 52 Cr ratio from a terrestrial standard) of around –0.4 to –0.5 ε 54 Cr, which distinctly point to an ordinary chondritic impactor. This result supports the asteroid impact interpretation but not the comet impact hypothesis.

ABSTRACT The massive Jurassic limestone making up the core of the Frasassi-Valmontagnana blind thrust anticline hosts a large sulfidic cave complex, which, due to Pleistocene tectonic uplift, has been incised by the Sentino River, forming the deep Frasassi Gorge. The Frasassi cave complex is organized into seven horizontal levels, with the youngest and presently active one at river level, and the oldest (ca. 1.2 Ma) one some 200 m above the Sentino River. Therefore, the Frasassi cave complex records the river incision history of this still-active Apennine mountain belt. In addition to an uplift rate of ~0.55 mm/yr for the Holocene, previous radioisotopic dating and surveying of phreatic calcite deposits revealed an overall tilting of the Frasassi anticline of ~0.2° toward N60E for the past 9000 or so years. Our study adds to this history of tectonic tilting by focusing on a group of 30 tilted stalagmites found at the bottom of the Abisso Ancona of the Grotta Grande del Vento (the largest room in the Frasassi complex). These stalagmites have a fairly uniform plunge of ~81° trending toward N30W, and we interpret this to record a tilt of the cave toward S30E during the formation of the stalagmites. From U-Th dating of these paleotiltmeters, we deduce that the Frasassi anticline was tilted by ~0.3° from 32 to 7 k.y. B.P., and the tilt rate gradually increased during this period. The 60° (NE) direction of oblique-slip faults in this area and the local focal mechanisms of recent seismic activity suggest that the tilting is caused by movement along a listric oblique strike-slip zone south of the Frasassi anticline. Our findings also demonstrate that given the right conditions, stalagmites can be used as paleotiltmeters that provide insight into recent crustal deformation.