ABSTRACT More than 100 air-fall volcanic tephra beds are currently documented from Devonian strata in the eastern United States. These beds act as key sources of various geological data. These include within-basin to basin-to-basin correlation, globally useful geochronologic age dates, and a relatively detailed, if incomplete, record of Acadian–Neoacadian silicic volcanism. The tephras occur irregularly through the vertical Devonian succession, in clusters of several beds, or scattered as a few to single beds. In this contribution, their vertical and lateral distribution and recent radiometric dates are reviewed. Current unresolved issues include correlation of the classic Eifelian-age (lower Middle Devonian) Tioga tephras and dates related to the age of the Onondaga-Marcellus contact in the Appalachian Basin. Here, we used two approaches to examine the paleovolcanic record of Acadian–Neoacadian silicic magmatism and volcanism. Reexamination of volcanic phenocryst distribution maps from the Tioga tephras indicates not one but four or more volcanic sources along the orogen, between southeastern Pennsylvania and northern North Carolina. Finally, radiometric and relative ages of the sedimentary basin tephras are compared and contrasted with current radiometric ages of igneous rocks from New England. Despite data gaps and biases in both records, their comparisons provide insights into Devonian silicic igneous activity in the eastern United States, and into various issues of recognition, deposition, and preservation of tephras in the sedimentary rock record.

ABSTRACT This study examines the usefulness of accommodation plots (Fischer plots) as a means of correlating mixed carbonate-siliciclastic strata in the subsurface. Fischer plots have been widely used to extract accommodation changes from carbonate platforms, but there are few published studies of siliciclastic or mixed carbonate-siliciclastic environments. The Middle Devonian of the Appalachian Basin is penetrated by thousands of wells, is exposed in numerous exceptional outcrops, and is an excellent place to test the usefulness of accommodation history plots as correlation tools. In the past, researchers have used cores, well cuttings, well logs, and outcrop gamma-ray profiles to correlate between outcrop and subsurface data, but all these methods have their limitations. Gamma-ray logs for wells penetrating the Middle Devonian from eight locations, from Preston County in the east to Wetzel County, West Virginia, in the west, were used in this study. Accommodation cycle thicknesses were measured from gamma-ray logs, printed at a vertical scale of one inch per ten feet (2.5 cm/3 m). The accommodation cycle thickness data were entered into Antun Husinec’s FISCHERPLOTS program to produce accommodation plots. Next, well-documented, outcrop-based sequence stratigraphy was used to help interpret the results of the accommodation plots. This study demonstrates that using accommodation plots is a novel way of overcoming the uncertainties and biases of other methods. The use of this approach in other mixed carbonate-siliciclastic successions with abundant subsurface data would help to demonstrate that Fischer plots are a novel and useful approach that can help remove many of the uncertainties and biases encountered in stratigraphic correlation.

ABSTRACT Beautifully fossiliferous strata in the Hamilton Group (Middle Devonian, central New York) constitute a rich “ecological archive” sufficient to probe and test foundational concepts in paleontology. The evident community stability of Hamilton faunas over 4–6 m.y.—including two proposed mechanisms for coordinated stasis—has ignited controversy. Resolving community structure and both taxonomic and ecological temporal persistence within the Hamilton Group thus becomes critical to testing whether these Hamilton communities are stable and whether they are ecologically “locked.” Toward this end, we conducted multivariate analyses (cluster and correspondence analysis) of marine faunas in 81 large samples (~300 specimens each) in shallowing-upward sequences of the Cardiff and Pecksport Members (Marcellus Subgroup, Oatka Creek Formation) of the Hamilton Group. Eight statistically and ecologically distinctive benthic communities characterize the vertical gradient, from depauperate, deeper-water dark shales below to species-rich shelf siltstones above. These communities correlate strongly with grain size, bioturbation intensity, bedding thickness, density of fossils, and faunal and ecological diversity. Species richness varies inversely with weight percent organic matter. We characterized taxonomic distributions using multivariate statistics; these statistical analyses were based on percentages of 50 taxa. In order of decreasing depth, the communities are: Cephalopod- Pterochaenia , Pterochaenia-Eumetabolotoechia , Eumetabolotoechia , Emanuella , Eumetabolotoechia-Ambocoelia , Arcuaminetes-Eumetabolotoechia , Arcuaminetes-Ambocoelia , and Mucrospirifer- Ambocoelia . The Cephalopod- Pterochaenia community represents a mixed benthic-pelagic fauna associated with the deepest and finest-grained facies. The Pterochaenia-Eumetabolotoechia , Eumetabolotoechia , and Emanuella communities have low to moderate species richness and are dominated by epifaunal, active suspension feeders, especially the small epibyssate bivalve Pterochaenia fragilis , and the pedunculate brachiopods Eumetabolotoechia multicostata and Emanuella subumbona . The Pterochaenia-Eumetabolotoechia community is an opportunistic fauna that developed when the substrate first became favorable for colonization by benthic organisms. To a lesser extent, this probably also holds true for the Eumetabolotoechia assemblage. Communities near the top of the shallowing-upward cycle— Eumetabolotoechia- Ambocoelia , Arcuaminetes-Eumetabolotoechia , Arcuaminetes-Ambocoelia , and Mucrospirifer-Ambocoelia —have higher taxonomic and ecological heterogeneity, with a more diverse array of trophic and locomotory groups than their counterparts in the finer-grained, and inferred deeper, facies. Cluster significance tests applied to all pairs of communities known from adequate numbers of samples demonstrated that the communities are statistically valid and distinctive. Multivariate means of all communities were significantly different; furthermore, most pairs of communities were drawn from populations that showed no overlap in terms of rectangular distributions. The community sequence and an ordination derived from the first two axes of the correspondence analysis provided relative depth curves. Our communities, with two exceptions, do not have clear counterparts among upper Hamilton Group faunas. The ecological locking model proposed to explain the stability of Hamilton faunas is not supported by our quantitative tests to date.

ABSTRACT An evaluation of an integrated data set collected over the past 12 years designed to identify the parameters controlling reservoir quality and production properties in organic, siliceous mudrocks reveals the key diagenetic processes affecting the development of brittleness in siliceous mudrocks. This work was motivated by the failure of early efforts to correlate brittleness to x-ray diffraction (XRD) mineralogy. The outcome of this analysis has been the recognition of two, often overlapping, pathways to brittleness that are determined at the time of deposition by the relative proportions of clay, detrital quartz, and biogenic silica present in the original sediment and are later affected by burial history. One pathway begins with a phyllosilicate–mud-dominated sediment, and the other begins with a sediment containing common or abundant biogenic silica (opal-A). Both pathways are characterized by compactional porosity loss and both eventually include the generation of authigenic quartz cement; however, the source of that authigenic quartz is different between the two pathways. The authigenic quartz that characterizes the first pathway is developed from the illitization of smectite and is precipitated as a cement within the argillaceous matrix. This authigenic quartz is detectable along with the detrital quartz by XRD analysis. All other factors being equal, the volume of brittle, authigenic quartz cement derived from the alteration of smectite is proportional to the volume of original clay. As a result, the effectiveness of this cement to increase the brittleness of the rock may be impacted by the presence of the ductile clays. In the alternate pathway, authigenic quartz is derived from the transformation of biogenic opal-A and is independent of the amount of clay. Much of the XRD quartz volume in rocks derived from biogenic–silica-rich sediment that contained little or no detrital quartz will comprise a brittle, authigenic cement.

ABSTRACT Scanning electron microscopy (SEM) has revolutionized our understanding of shale petroleum systems through microstructural characterization of dispersed organic matter (OM). However, as a result of the low atomic weight of carbon, all OM appears black in SEM (BSE [backscattered electron] image) regardless of differences in thermal maturity or OM type (kerogen types or solid bitumen). Traditional petrographic identification of OM uses optical microscopy, where reflectance (%R o ), form, relief, and fluorescence can be used to discern OM types and thermal maturation stage. Unfortunately, most SEM studies of shale OM do not employ correlative optical techniques, leading to misidentifications or to the conclusion that all OM (i.e., kerogen and solid bitumen) is the same. To improve the accuracy of SEM identifications of dispersed OM in shale, correlative light and electron microscopy (CLEM) was used during this study to create optical and SEM images of OM in the same fields of view (500× magnification) under white light, blue light, secondary electron (SE), and BSE conditions. Samples ( n = 8) of varying thermal maturities and typical of the North American shale petroleum systems were used, including the Green River Mahogany Zone, Bakken Formation, Ohio Shale, Eagle Ford Formation, Barnett Formation, Haynesville Formation, and Woodford Shale. The CLEM image sets demonstrate the importance of correlative microscopy by showing how easily OM can be misidentified when viewed by SEM alone. Without CLEM techniques, petrographic data from SEM such as observations of organic nanoporosity may be misinterpreted, resulting in false or ambiguous results and impairing an improved understanding of organic diagenesis and catagenesis.

ABSTRACT A new model is proposed to predict porosity in organic matter for unconventional shale reservoirs. This model is based on scanning electron microscopic (SEM) observations that reveal porosity in organic matter is associated with secondary porosity developed within organic matter cement that fills void space preserved prior to oil generation. The organic matter cement is interpreted as solid bitumen resulting from the thermal alteration of residual oil retained in the source rock following oil expulsion. Pores are interpreted to develop within the solid bitumen as a result of thermal cracking and gas generation at increased levels of thermal maturity, transforming the solid bitumen to pyrobitumen. The pyrobitumen porosity model is an improvement over existing kerogen porosity models that lack petrographic validation. Organic matter porosity is predicted by first estimating the potential volume of organic matter cement by deriving the matrix porosity available at the onset of oil generation from extrapolations of lithologic specific compaction profiles. The fraction of organic matter cement converted to porosity in the gas window is then calculated by applying porosity conversion ratios derived from SEM digital image analysis of analogous shale reservoirs. Further research is required to refine and test the porosity prediction model.