Abstract Many archaeological sites with jadeitite artefacts are known in the Caribbean region, but defining the source of the raw material is a major problem because of great mineralogical heterogeneity both in potential sources and in artefacts. The archaeological settlement site of Playa Grande on the northern coast of the Dominican Republic is particularly significant because it yielded evidence of on-site axe manufacture, and lies only 20–30 km NE of a recently discovered potential source area of serpentinite mélanges in the nearby Río San Juan Complex (RSJC). A suite of nine artefacts was chosen from a collection of over 100 excavated woodworking tools rich in jadeite, as well as two blueschist artefacts. Permission to perform destructive analysis allowed data on petrography, mineral chemistry and bulk-rock chemistry to be obtained. Seven of the nine artefacts are jadeitite sensu stricto (>90 vol% jadeite), which are identical to material known from the RSJC. Two artefacts are jadeite–lawsonite rocks. These and the two blueschists show only minor differences from corresponding rocks of the RSJC source. With this direct linking of source and site material, it is now possible to better define source discriminators for the Caribbean and to assess sampling bias.

Abstract Eclogites in the high-pressure (HP) and ultrahigh-pressure (UHP) belts record subduction-zone processes; exhumed eclogites of seafloor protoliths record low-temperature (mostly <600°C), high-pressure and ‘wet’ environments: that is, relatively ‘cold’ subduction with highly hydrous minerals such as lawsonite. In contrast, eclogites formed by the continental subduction record relatively ‘hot’ ( T > 650°C) and ‘dry’ ultrahigh-pressure metamorphic (UHPM) conditions with syncollisional magmatism. Here, we investigate some eclogites from two ophiolite sequences that intercalated in the North Qaidam UHPM belt, which is genetically associated with continental subduction/collision. The observations of lawsonite pseudomorphs in garnets, garnet compositional zoning, mineral and fluid inclusions in zircons, and zircons with distinct trace-element patterns and U–Pb ages all suggest that these eclogites represent two exhumation episodes of subduction-zone metamorphic rocks: the early ‘cold’ and ‘wet’ lawsonite eclogite and the late ‘hot’ and ‘dry’ UHP kyanite eclogite. The early lawsonite-bearing eclogite gives metamorphic ages of 470–445 Ma and the later kysnite-bearing eclogite gives metamorphic ages of 438–420 Ma, with a time gap of c. 7–10 myr. This gap may represent the timescale for transition from oceanic subduction and continental subduction to depths greater than 100 km. We conclude that evolution from oceanic subduction to continental collision and subduction was a continuous process. In addition, we find that titanium contents in zircons have a positive correlation with U contents. Ti-in-zircon thermometry is likely to be invalid or limited for low-temperature eclogites.

ABSTRACT The subduction thrust interface represents a zone of concentrated deformation coupled to fluid generation, flow, and escape. Here, we review the internal structure of the megathrust as exposed in exhumed accretionary complexes, and we identify a deformation sequence that develops as material entering the trench is subducted through the seismogenic zone. Initial ductile flow in soft sediment generates dismembered, folded, and boudinaged bedding that is crosscut by later brittle discontinuities. Veins formed along early faults, and filling hydrofractures with the same extension directions as boudins in bedding, attest to fluid-assisted mass transfer during the shallow transition from ductile flow to brittle deformation. In higher-metamorphic-grade rocks, veins crosscut foliations defined by mineral assemblages stable at temperatures beyond those at the base of the seismogenic zone. The veins are, however, themselves ductilely deformed by diffusion and/or dislocation creep, and thus they record fracture and fluid flow at a deeper brittle-to-ductile transition. The results of numerical models and mineral equilibria modeling show that compaction of pore spaces may occur over a wide zone, as underconsolidated sediments carry water under the accretionary prism to the region where the last smectite breaks down at a temperature of ≤150 °C. However, at temperatures above clay stability, no large fluid release occurs until temperatures reach the zone where lawsonite and, subsequently, chlorite break down, i.e., generally in excess of 300 °C. In thermal models and strength calculations along overpressured subduction interfaces, where phyllosilicates form an interconnected network that controls rheology, as is generally observed, the deep brittle-viscous transition—analogous to the base of the seismogenic zone—occurs at temperatures less than 300 °C. We therefore suggest that the seismogenic zone does not produce fluids in significant volumes; however, major fluid release occurs at or near the base of the seismogenic zone. These deep fluids are either trapped, thus enabling embrittlement and features such as episodic tremor and slow slip, or flow updip along a permeable interface. Overall, we highlight fluid production as spatially intermittent, but fluid distribution as controlled also by the permeability of a deforming zone, where secondary porosity is both generated and destroyed, commonly in sync with the generation and movement of fluids.