ABSTRACT A combined petrographic and chemical study of ejecta particles from the Cretaceous-Paleogene boundary sequence of El Guayal, Tabasco, Mexico (520 km SW of Chicxulub crater), was carried out to assess their formation conditions and genetic relation during the impact process. The reaction of silicate ejecta particles with hot volatiles during atmospheric transport may have induced alteration processes, e.g., silicification and cementation, observed in the ejecta deposits. The various microstructures of calcite ejecta particles are interpreted to reflect different thermal histories at postshock conditions. Spherulitic calcite particles may represent carbonate melts that were quenched during ejection. A recrystallized microstructure may indicate short, intense thermal stress. Various aggregates document particle-particle interactions and intermixing of components from lower silicate and upper sedimentary target lithologies. Aggregates of recrystallized calcite with silicate melt indicate the consolidation of a hot suevitic component with sediments at ≳750 °C. Accretionary lapilli formed in a turbulent, steam-condensing environment at ~100 °C by aggregation of solid, ash-sized particles. Concentric zones with smaller grain sizes of accreted particles indicate a recurring exchange with a hotter environment. Our results suggest that during partial ejecta plume collapse, hot silicate components were mixed with the fine fraction of local surface-derived sediments, the latter of which were displaced by the preceding ejecta curtain. These processes sustained a hot, gas-driven, lateral basal transport that was accompanied by a turbulent plume at a higher level. The exothermic back-reaction of CaO from decomposed carbonates and sulfates with CO 2 to form CaCO 3 may have been responsible for a prolonged release of thermal energy at a late stage of plume evolution.

Abstract Preserved rocks in the Jurassic Ferrar Large Igneous Province consist mainly of intrusions, and extrusive rocks, the topic of this chapter, comprise the remaining small component. They crop out in a limited number of areas in the Transantarctic Mountains and southeastern Australia. They consist of thick sequences of lavas and sporadic occurrences of volcaniclastic rocks. The latter occur mainly beneath the lavas and represent the initial eruptive activity, but also are present within the lava sequence. The majority are basaltic phreatomagmatic deposits and in at least two locations form immense phreatocauldrons filled with structureless tuff breccias and lapilli tuffs with thicknesses of as much as 400 m. Stratified sequences of tuff breccias, lapilli tuffs and tuffs are up to 200 m thick. Thin tuff beds are sparsely distributed in the lava sequences. Lava successions are mainly 400–500 m thick, and comprise individual lavas ranging from 1 to 230 m thick, although most are in the range of 10–100 m. Well-defined colonnade and entablature are seldom displayed. Lava sequences were confined topographically and locally ponded. Water played a prominent role in eruptive activity, as exhibited by phreatomagmatism, hyaloclastites, pillow lava and quenching of lavas. Vents for lavas have yet to be identified.

Abstract The Antarctic Peninsula is distinguished by late Neogene volcanic activity related to a series of northerly younging ridge crest–trench collisions and the progressive opening of ‘slab windows’ in the subjacent mantle. The outcrops were amongst the last to be discovered in the region, with many occurrences not visited until the 1970s and 1980s. The volcanism consists of several monogenetic volcanic fields and small isolated centres. It is sodic alkaline to tholeiitic in composition, and ranges in age between 7.7 Ma and present. No eruptions have been observed (with the possible, but dubious, exception of Seal Nunataks in 1893) but very young isotopic ages for some outcrops suggest that future eruptions are a possibility. The eruptions were overwhelmingly glaciovolcanic and the outcrops have been a major source of information on glaciovolcano construction. They have also been highly influential in advancing our understanding of the configuration of the Plio-Pleistocene Antarctic Peninsula Ice Sheet. However, our knowledge is hindered by a paucity of modern, precise isotopic ages. In particular, there is no obvious relationship between the age of ridge crest–trench collisions and the timing of slab-window volcanism, a puzzle that may only be resolved by new dating.

Abstract Two small monogenetic volcanoes are exposed at Mount Early and Sheridan Bluff, in the upper reaches of Scott Glacier. In addition, the presence of abundant fresh volcanic detritus in moraines at two other localities suggests further associated volcanism, now obscured by the modern Antarctic ice sheet. One of those occurrences has been attributed to a small subglacial volcano only c. 200 km from South Pole, making it the southernmost volcano in the world. All of the volcanic outcrops in the Scott Glacier region are grouped in a newly defined Upper Scott Glacier Volcanic Field, which is part of the McMurdo Volcanic Group (Western Ross Supergroup). The volcanism is early Miocene in age ( c. 25–16 Ma), and the combination of tholeiitic and alkaline mafic compositions differs from the more voluminous alkaline volcanism in the West Antarctic Rift System. The Mount Early volcano was erupted subglacially, when the contemporary ice was considerably thicker than present. By contrast, lithologies associated with the southernmost volcano, currently covered by 1.5 km of modern ice, indicate that it was erupted when any associated ice was either much thinner or absent. The eruptive setting for Sheridan Bluff is uncertain and is still being investigated.

Abstract This study discusses the petrological and geochemical features of two monogenetic Miocene volcanoes, Mount Early and Sheridan Bluff, which are the above-ice expressions of Earth's southernmost volcanic field located at c. 87° S on the East Antarctic Craton. Their geochemistry is compared to basalts from the West Antarctic Rift System to test affiliation and resolve mantle sources and cause of melting beneath East Antarctica. Basaltic lavas and dykes are olivine-phyric and comprise alkaline (hawaiite and mugearite) and subalkaline (tholeiite) types. Trace element abundances and ratios (e.g. La/Yb, Nb/Y, Zr/Y) of alkaline compositions resemble basalts from the West Antarctic rift and ocean islands (OIB), while tholeiites are relatively depleted and approach the concentrations levels of enriched mid-ocean ridge basalt (E-MORB). The magmas evolved by fractional crystallization with contamination by crust; however, neither process can adequately explain the contemporaneous eruption of hawaiite and tholeiite at Sheridan Bluff. Our preferred scenario is that primary magmas of each type were produced by different degrees of partial melting from a compositionally similar mantle source. The nearly simultaneous generation of lower degrees of melting to produce alkaline types and higher degrees of melting forming tholeiite was most likely to have been facilitated by the detachment and dehydration of metasomatized mantle lithosphere.

Abstract Tephra beds are considered to be potential failure planes for submarine landslides. Here, we report on an example of a coarse-ash/lapilli-tuff bed influencing translational slides. The studied mass-transport deposit (MTD) is intercalated in the Pleistocene forearc basin fill exposed in east-central Japan. This MTD consists of stacked siltstone blocks resulting from repeated imbricate thrusts branching from the décollement. The basal slide plane is located immediately below a pumice-rich coarse ash/lapilli-tuff bed. The material comprising the slip zone is injected into the overlying coarse-ash/lapilli-tuff bed, suggesting an upwards escape of excess porewater that resulted from elevated pore pressure. To explain this mode of occurrence, we propose that the detachment preferentially occurred at the top and base of the coarse-ash-tuff-rich interval which appears to have been stronger relative to the adjacent silt-dominated interval. The pumiceous coarse-ash and lapilli-tuff bed behaved as a rigid plate on top of the high-pore-pressure slip zone, which sustained the translational slide on the gentle continental slope. Therefore, in translational submarine landslides, the preferential formation of a slide plane is caused by differing frictional resistances in the layered sediments.