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high-level waste
The Effect of Unloading Path on the Time-Dependent Behavior of Beishan Granite
Experimental Study on Physical and Mechanical Properties of Beishan Granite after Cyclic Heating and Cooling with Water
Natural and Anthropogenic Analogues for High-Level Nuclear Waste Disposal Repositories: A Review
Mineralogical and hydraulic characteristics of mudstone in the Tamusu candidate area in northwest China for high-level radioactive waste geological disposal
Columnar-jointed bentonite below a Doleritic Sill, Tideswell Dale, Derbyshire, UK: formation during prograde contact metamorphism
Swelling characteristics of bentonite after long-term dissolution in alkaline solution
Reactive Transport Modeling: A Key Performance Assessment Tool for the Geologic Disposal of Nuclear Waste
Comparison of microstructural features of three compacted and water-saturated swelling clays: MX-80 bentonite and Na- and Ca-purified bentonite
New results of Boda Claystone research: Genesis, mineralogy, geochemistry, petrophysics
Abstract Boda Claystone is a very tight clayey rock with extreme low porosity and permeability, nano-size pores and small amounts of swelling clays. Due to this character it is ideal as a potential host rock for research into the possibilities of high-level waste deposition in geological formation. Though the research started more than 30 years ago, the genesis, the geotectonic history of the Boda Claystone Formation (BCF) and the geology of surrounding areas has only been sketched out recently. On the basis of research of the past few years the process of sedimentation of different blocks was able to be reconstructed. Equipment and methodological developments were needed for the investigation of reservoir geological and hydrodynamic behaviour of this rock, which began in the early 2000s. Based on them the pore structure and reservoir could be characterized in detail. Only theoretical approaches were available for the chemical composition of free porewater. Traditional water-extracting methods were not adaptable because of excessively low porosity and nano-scale pore size distribution. Hence, new ways have to be found for getting enough water for analysis. These new results of BCF research help to prepare more sophisticated and directed experiments, in which there is a great interest internationally.
Site screening of clay formations in NW China as host rocks for a high-level radioactive waste disposal repository
Abstract Deep geological disposal of high-level radioactive waste (HLW) in a repository with a system of engineered and natural barriers has been recognized as an appropriate disposal concept by Chinese authorities since 2003, and both crystalline rocks and argillaceous rocks are considered as the candidate host rocks for HLW disposal repository. The 1:200 000 regional survey indicated that there are potential clay formations in Mesozoic–Cenozoic sedimentary basins in NW China. Five candidate areas have been suggested with potential clay formations including the Tamusu and Suhongtu areas with upper K 1 Bayingebi clay formations in the east Bayingebi Basin, in the Inner Mongolia Autonomous Region. On the basis of a detailed ground geological, hydrological and geophysical surveys, two test boreholes drilled to a depth of 800 m in the Tamusu area revealed that there are three lacustrine-facies clay formations (K 1 b 2-3 , K 1 b 2-2 and K 1 b 2-1 ). The thickness of the K 1 b 2-3 and K 1 b 2-2 clay formations is about 300–600 m with sandstone and siltstone interbeds, while the thickness of the K 1 b 2-1 homogeneous clay formation is more than 200 m with the depth of 450 m below the surface. The spatial extension of the clay formations could meet the fundamental criteria to ensure the long-term safety of the repository. Initial mineralogical studies on core samples indicated that the mineral assemblage is dominated by analcite, kaolinite, illite and dolomite. The homogeneous argillaceous rocks rich in analcite in Tamusu area could be a new type of host rock for a HLW disposal repository.
Abstract In a deep geological repository (DGR) for the long-term containment of radioactive waste, gases could be generated through a number of processes. If gas production exceeds the containment capacity of the engineered barriers or host rock, these gases could migrate through these barriers and potentially expose people and the environment to radioactivity. Expansive soils, such as bentonite-based materials, are currently the preferred choice of seal materials. Understanding the long-term performance of these seals as barriers against gas migration is an important component in the design and long-term safety assessment of a DGR. This study proposes a hydro-mechanical linear poro-elastic visco-capillary mathematical model for advective-diffusive controlled two-phase flow through a low-permeability expansive soil. It is based on the theoretical framework of poromechanics, incorporates Darcy’s Law for both the porewater and poregas, and a modified Bishop’s effective stress principle. Using the finite element method (FEM), the model was used to numerically simulate 1D flow through a low-permeability expansive soil. The results were verified against experimental results found in the current literature. Parametric studies were performed to determine the influence on the flow behaviour. Based on the results, the mathematical model looks promising and will be improved to model flow through preferential pathways.
A workflow for parametric sensitivity analysis of heat and gas release from a deep geological repository for SF/HLW
Abstract A key component of the site comparison planned for the deep geological disposal of spent fuel and high-level waste (SF/HLW) in Switzerland is the assessment of the evolution of repository-induced perturbations in the repository nearfield associated with thermal effects from heat production due to radioactive decay of radionuclides, as well as gas pressures developing in the backfilled underground structures from the anaerobic corrosion of the steel waste canisters and tunnel support materials. The assessment of such effects is integrated in the site comparison through safety indicators used to evaluate repository performance. In this context, probabilistic assessments need to integrate the uncertainty of the entire ensemble of input parameters, and estimate the propagation to these indicators in a reliable and computationally efficient manner. This paper presents the development of a methodology for an indicator-based assessment of heat- and gas-induced effects in a SF/HLW repository in Opalinus Clay integrating a probabilistic treatment of parametric uncertainty. The workflow is demonstrated using preliminary data, repository configurations and indicators. Complementary simulations are presented to demonstrate the feedback to the optimization of repository design in order to mitigate repository-induced effects that can potentially compromise the safety function of the engineered and natural barriers.
Abstract Piping and erosion phenomena are serious problems affecting the integrity of buffer materials, which are an element of engineered barrier systems in the geological disposal of high-level radioactive waste. In this study, the outflow behaviour and the condition of buffer materials are investigated using a test pit drilled into host rock at the Horonobe Underground Research Laboratory to consider countermeasures to contain the outflow of the buffer material. The results are as follows: (1) Piping and erosion phenomena occur irrespective of the injection flow rate. However, when the rate is small, the buffer material is considered to be self-repairing and the outflow of the buffer material can be suppressed. (2) When the injection water contains large amounts of electrolytes, the surface of the buffer material peels off and precipitates, probably decreasing the waterproof performance. (3) Bentonite pellets are likely to be an effective countermeasure against piping and erosion.
Abstract Colloid concentration is an important parameter in models of colloid-facilitated transport. The purpose of the present study is to characterize colloid concentrations and colloid stability in natural groundwater from the Horonobe Underground Research Laboratory (URL) in Hokkaido, Japan. The particle sizes of colloids in groundwaters from the Horonobe URL range from several nanometres to c . 500 nm, with a mode particle size of c . 120 nm. Evaluation of colloid stability by DLVO theory suggests that larger colloids (i.e. >100 nm in diameter) would be more stable than smaller colloids in some groundwaters. The estimated colloid particle concentrations when considering the results of DLVO calculations ranged from 2.33 × 10 6 to 1.12 × 10 8 particles/ml, and mass concentrations were estimated to range from 45 to 1540 µg l −1 for diameters greater than 100 nm. Colloids in Horonobe groundwaters appear to be less stable, with a moderate potential for transport, than colloids investigated in similar international studies. This reduced stability may be due to relatively higher ionic strengths and moderate dissolved organic concentrations in Horonobe groundwaters compared to their international counterparts.
A resistivity-based approach to determining the rates of groundwater seepage into buffer materials
Abstract Bentonite-based buffer materials play an important safety role in engineered barriers planned for use in geological disposal repositories for radioactive high-level waste (HLW) in Japan. The effectiveness of buffer materials is dependent on the status of groundwater saturation during resaturation of the repository. Accordingly, it is important to determine the behaviour of buffer materials during saturation and predict post-saturation conditions such as the distribution of residual dry density and chemical alteration. In this study, the rate of groundwater uptake into a buffer material was determined to clarify the behaviour of the material during the saturation process. As mechanical changes and chemical alteration of buffer materials are generated by groundwater permeation, knowledge of the water uptake rate is necessary for the prediction of post-permeation conditions. In the experiment reported here, one-dimensional permeation by distilled water and a NaCl water solution at a constant rate was monitored over a period of more than seven years. The results indicated that the seepage and saturation front moved in proportion to the square root of the seepage time. The coefficient of the relationships between the seepage and the saturation fronts with time of the reference bentonite used in Japan was determined.
Modelling the Prototype Repository
Abstract The Prototype Repository (PR) tunnel is located at the Äspö Hard Rock Laboratory near Oskarshamn in the southeast of Sweden. In the PR tunnel, six full-sized deposition holes (8.37 m deep and 1.75 m in diameter) have been constructed. Each deposition hole is designed to mimic the Swedish reference system for the disposal of nuclear fuel, KBS-3V. The PR experiment is designed to provide a full-scale simulation of the emplacement of heat-generating waste. There are three phases to the experiment: (1) the open tunnel phase following construction, where both the tunnel and deposition holes are open to atmospheric conditions; (2) the emplacement of canisters (containing heaters), backfill and seal in the first section of the tunnel; and (3) the emplacement of canisters, backfill and seal in the second section of the tunnel. This work describes the numerical modelling, performed as part of the engineered barrier systems (EBS) Task Force, to understand the thermo-hydraulic (TH) evolution of the PR experiment and to provide a better understanding of the interaction between the fractured rock and bentonite surrounding the canister at the scale of a single deposition tunnel. A coupled integrated TH model for predicting the wetting and the temperature of bentonite emplaced in fractured rock was developed, accounting for the heterogeneity of the fractured rock. In this model, geometrical uncertainties of fracture locations are modelled by using several stochastic realizations of the fracture network. The modelling methodology utilized information available at early stages of site characterization and included site statistics for fracture occurrence and properties, as well as proposed installation properties of the bentonite. The adopted approach provides an evaluation of the predictive capability of models, it gives an insight of the uncertainties to data and demonstrates that a simplified equivalent homogeneous description of the fractured host rock is insufficient to represent the bentonite resaturation.
Predictions of the wetting of bentonite emplaced in a crystalline rock based on generic site characterization data
Abstract A geological disposal facility (GDF) is the widely accepted long-term solution for the management of higher-activity radioactive waste. It consists of an engineered facility constructed in a suitable host rock. The facility is designed to inhibit the release of radioactivity by using a system consisting of engineered and natural barriers. The engineered barriers include the wasteform, used to immobilize the waste, the waste disposal container and any buffer material used to protect the container. The natural barrier includes the rocks in which the facility is constructed. The careful design of this multi-barrier system enables the harmful effects of the radioactivity on humans and biota in the surface environment to be reduced to safe levels. Bentonite is an important buffer material used as a component of a multi-barrier disposal system. For example, compacted bentonite rings and blocks are used to protect the copper container, used for the disposal of spent fuel, in the KBS-3 disposal system. As the bentonite saturates, through contact with groundwater from the host rock, it swells and provides a low hydraulic conductivity barrier, enabling the container to be protected from deleterious processes, such as corrosion. The characteristic swelling behaviour of bentonite is due to the presence of significant quantities of sodium montmorillonite. Recently, there have been detailed in situ experiments designed to understand how bentonite performs under natural conditions. One such experiment is the Buffer–Rock Interaction Experiment (BRIE), performed at the Äspö Hard Rock Laboratory near Oskarshamn in the SE of Sweden. This experiment is designed to further understand the wetting of bentonite from the groundwater flow in a fractured granite host rock. In this paper, the observations from the BRIE are explained using an integrated model that is able to describe the saturation of bentonite emplaced in a heterogeneous fractured rock. It provides a framework to understand the key processes in both the rock and bentonite. The predictive capability of these models was investigated within the context of uncertainties in the data and the consequence for predictions of the wetting of emplaced bentonite. For example, to predict the wetting of emplaced bentonite requires an understanding of the distribution of fracture transmissivity intersecting the bentonite. A consequence of these findings is that the characterization of the fractured rock local to the bentonite is critical to understanding the subsequent wetting profiles. In particular, prediction of the time taken to achieve full saturation of bentonite using a simplified equivalent homogeneous description of the fractured host rock will tend to be too short.
Abstract Geological disposal is the most realistic option for high-level radioactive waste in Japan. In considering long-term stability for geological disposal, several types of materials have been studied as engineered barriers with a host rock. We focused our study on metal and bentonite as engineered barrier materials and investigated the long-term corrosion tendency of the metal exposed to bentonite. An electrochemical method for inducing accelerated corrosion was studied in a laboratory, and we analysed some field samples from a FEBEX dismantling project (FEBEX-DP) in Switzerland for comparison with our experimental results.
Abstract A safety concept and a safety demonstration concept for the disposal of high-level radioactive waste in German clay formations have been developed. The main safety objective is to retain the radionuclides inside a ‘Containment Providing Rock Zone’. Thus, the radionuclide transport should be restrained by adequate safety functions of the geological and geotechnical barriers. The compliance with legal dose constraints has to be demonstrated for probable evolutions and less probable evolutions. As a basis for system analysis, generic geological reference models, disposal concepts and repository designs have been developed for northern and southern Germany. All data relevant for future system evolution were compiled in two FEP (features, events and processes) catalogues. They provide information on FEP characteristics, their probabilities of occurrence, their interactions and identify ‘initial FEP’ that impair the safety functions of relevant barriers. A probable reference scenario has been deduced systematically from the probable ‘initial FEP’, and from probable processes relevant for radionuclide mobilization and transport. Four different starting points to develop alternative scenarios (i.e. less probable evolutions) were identified. The scenario development methodology is applicable to different kinds of host rock and therefore may be a basis for the preliminary safety analyses necessary in the future site selection process in Germany.