A ~220,000-year record recovered in a 120-m-long sediment core from Bear Lake, Utah and Idaho, provides an opportunity to reconstruct climate change in the Great Basin and compare it with global climate records. Paleomagnetic data exhibit a geomagnetic feature that possibly occurred during the Laschamp excursion (ca. 40 ka). Although the feature does not exhibit excursional behavior (≥40° departure from the expected value), it might provide an additional age constraint for the sequence. Temporal changes in salinity, which are likely related to changes in freshwater input (mainly through the Bear River) or evaporation, are indicated by variations in mineral magnetic properties. These changes are represented by intervals with preserved detrital Fe-oxide minerals and with varying degrees of diagenetic alteration, including sulfidization. On the basis of these changes, the Bear Lake sequence is divided into seven mineral magnetic zones. The differing magnetic mineralogies among these zones reflect changes in deposition, preservation, and formation of magnetic phases related to factors such as lake level, river input, and water chemistry. The occurrence of greigite and pyrite in the lake sediments corresponds to periods of higher salinity. Pyrite is most abundant in intervals of highest salinity, suggesting that the extent of sulfidization is limited by the availability of SO 4 2‒ . During MIS 2 (zone II), Bear Lake transgressed to capture the Bear River, resulting in deposition of glacially derived hematite-rich detritus from the Uinta Mountains. Millennial-scale variations in the hematite content of Bear Lake sediments during the last glacial maximum (zone II) resemble Dansgaard-Oeschger (D-O) oscillations and Heinrich events (within dating uncertainties), suggesting that the influence of millennial-scale climate oscillations can extend beyond the North Atlantic and influence climate of the Great Basin. The magnetic mineralogy of zones IV–VII (MIS 5, 6, and 7) indicates varying degrees of post-depositional alteration between cold and warm substages, with greigite forming in fresher conditions and pyrite in the more saline conditions.

The tension between CO 2 dissolved at relatively high atmospheric pressure in the Hadean ocean, and H 2 generated as ocean water oxidized ferrous iron during convection in the oceanic crust, was resolved by the onset of life. We suggest that this chemosynthetic life emerged within hydrothermal mounds produced by alkaline solutions of moderate temperature in the relative safety of the deep ocean floor. Exothermic reaction between hydrothermal H 2 , HCOO − and CH 3 S − with CO 2 was catalyzed in inorganic membranes near the mound's surface by mackinawite (FeS) nanocrysts and “ready-made” clusters corresponding to the greigite (Fe 5 NiS 8 ) structure. Such clusters were precursors to the active centers (e.g., the C-cluster, Fe 4 NiS 5 ) of a metalloenzyme that today catalyzes acetate synthesis, viz., the bifunctional dehydrogenase enzyme (ACS/CODH). The water, and some of the acetate (H 3 C.COO − ), produced in this way were exhaled into the ocean together as fluid waste. Glycine ( + H 3 N.CH 2 .COO − ) and other amino acids, as well as tiny quantities of RNA, generated in the same milieu were trapped within tiny iron sulfide cavities. Energy from the acetate reaction, augmented by a proton gradient operating through the membrane, was spent polymerizing glycine and other amino acids into short peptides upon the phosphorylated mineral surface. In turn these peptides sequestered, and thereby protected, the catalytically and electrochemically active pyrophosphate and iron/nickel sulfide clusters, from dissolution or crystallization. Intervention of RNA as a polymerizing agent for amino acids also led to an adventitious, though crude, process of regulating metabolism—a process that was also to provide genetic information to offspring. The fluxes of energy and nutrient available in the hydrothermal mound—commensurate with the requirements of life—encouraged differentiation of the first microbes into two separate domains. At the bifurcation the Bacteria were to specialize in acetogenesis and the Archaea into methanogenesis. Representatives of both these domains left the mound by way of the ocean floor and crust to colonize the deep biosphere. Once life had emerged and evolved to the extent of being able to reduce nitrogen for use in peptides and nucleic acids, light could have been used directly as an energy source for biosynthesis. Certain bacteria may have been able to do this, where protected from hard UV by a thin coating of chemical sediment produced at a sub-aerial hot spring operating in an obducted and uplifted portion of the deep biosphere. Embedded in fresh manganiferous exhalites, early photosynthetic bacteria could further protect themselves from radiation by adsorbing manganese on the membrane. Organization of the manganese with calcium, within a membrane protein, happened to result in a CaMn 3 O 4 cluster. In Mn(IV) mode this structure could oxidize two molecules of water, evolve waste oxygen, and gain four electrons and four protons in the process to fix CO 2 for biosynthesis. All these biosynthetic pathways had probably evolved before 3.7 Ga, though the reduced nature of the planet prevented a buildup of free atmospheric oxygen until the early Proterozoic.

We have studied the magnetic properties of wet and dry late Pleistocene Lake Lisan sediments and the Holocene Dead Sea sediments. Our initial prediction was that the properties of both would be quite similar, because they have similar source and lake conditions, unless diagenetic change had occurred. Rock magnetic and paleomagnetic experiments revealed three stages of magnetization acquisition. Our findings suggest two magnetic carriers in the Holocene Dead Sea and wet Lisan sediments: titanomagnetite and greigite. The titanomagnetite grains are detrital and carry a detrital remanent magnetization (DRM), whereas the greigite is diagenetic in origin and carries a chemical remanent magnetization (CRM) that dominates the total natural remanent magnetization (NRM) of Holocene Dead Sea and wet Lisan sediments. The magnetization of dry Lisan sediments is a DRM and resides in multidomain (MD) grains. We propose that magnetic properties of the Lisan Formation and Holocene Dead Sea sediments can be explained by a model that incorporates dissolution, precipitation, and alteration of magnetic carriers. At the time of deposition, titanomagnetite grains of varying size were deposited in Lake Lisan and the Holocene Dead Sea, recording the geomagnetic field via a primary DRM. Sedimentation was followed by partial or complete dissolution of titanomagnetite in anoxic lake bottom conditions. As the kinetics of dissolution depends upon surface area, the single-domain (SD) grains dissolved faster, leaving only the larger pseudo-single domain (PSD) and MD grains. Titanomagnetite dissolution occurred simultaneously with precipitation of greigite in anoxic, sulfate-reducing conditions probably related to bacterial degradation of organic matter. This process added a secondary CRM that overwhelmed the DRM and the primary geomagnetic record. Later, when the level of Lake Lisan dropped, these sediments were exposed to air. At this time, the greigite was oxidized, removing the CRM from the system and leaving only the original detrital PSD and MD titanomagnetite grains as the dominant DRM carriers. Presently, wet Lisan sediments have not been completely altered and therefore contain secondary greigite preserved by the original formation water that carries a secondary CRM. Thus, the magnetization in the Holocene Dead Sea and the wet Lisan magnetic record cannot be considered as an accurate, reliable geomagnetic record, while magnetization of dry Lisan sediments is a primary DRM.