Abstract Lava flows form important fluid reservoirs and have been extensively exploited for water aquifers, geothermal energy, hydrocarbon production and, more recently, for carbon storage. Effusive subaerial mafic to intermediate lava flows account for vast rock volumes globally, and form reservoirs with properties dictated by well-known lava flow facies ranging from pāhoehoe through several transitional forms to ‘a’ā lava. These variations in flow type lead to critical differences in the pore structure, distribution, connectivity, strength and fracturing of individual lava flows, which, alongside lava flow package architectures, determine primary reservoir potential. Lava flow margins with vesicular, fracture and often autobreccia-hosted pore structures can have porosities commonly exceeding 40% and matrix permeabilities over 10 −11 m 2 (>10 D) separated by much lower porosity and permeability flow interiors. Secondary post-emplacement physicochemical changes related to fracturing, meteoric, diagenetic and hydrothermal alteration can significantly modify reservoir potential through a complex interplay of mineral transformation, pore-clogging secondary minerals and dissolution, which must be carefully characterized and assessed during exploration and appraisal. Within this contribution, a review of selected global lava flow-hosted reservoir occurrences is presented, followed by a discussion of the factors that influence lava flow reservoir potential.

Abstract The Antrim Lava Group of NE Ireland comprises a volcanic sequence dominated by basaltic lava flows. Including subsidiary sedimentary interlayers and some evolved lavas and intrusions, the overall sequence reaches a cumulative thickness of ∼800 m. The tempo of eruption of the Antrim Lava Group is poorly constrained but can be evaluated via weathering patterns and environmental reconstructions derived from lava-flow interbeds. In this contribution, we present palynology from a newly identified and well-developed 2.0–2.5 m thick sedimentary sequence (interbed) at Ross's Quarry, Ballycastle, Co. Antrim, that helps elucidate the contemporary development of environments in a setting subject to periodic basaltic volcanism. The interbed is subdivided into geologically distinct subunits of cross-bedded and parallel-bedded sandstones and sandy siltstones, all rich in visible organic remains such as rootlets and fragments of wood and bark. A total of 19 samples was collected from the sequence and subsequently analysed for palynological content. The palynomorph data point toward a diversity of inputs ranging from estuaries, chalky soils, dry soils, swamps, lakes, floodplains, sand bars, wet soils, established bogs and fenlands. In contrast to current understanding, the palynological data and their inferred environments collectively reveal the presence of flora that favour a temperate climate rather than the subtropical climate that has previously been inferred from the lateritic interbeds of the Antrim Lava Group. By combining the Ross's Quarry observations with palynological data from other quarry sites and boreholes in Antrim, we provide new insights into the climate, weathering systems and eruptive history of the Antrim Lava Group.