ABSTRACT The Washita Prairie segment of the Edwards (Balcones Fault Zone) Aquifer is a shallow unconfined aquifer that supports several historical springs, perennial streamflow to Lake Waco, and water for rural households and livestock. Secondary porosity in the aquifer is from neotectonic fractures and epikarst in the Georgetown and Edwards Formations. The fractures produce an “effective” porosity of ~1%. Thin soils allow rapid recharge, as indicated by water-level responses in wells within 24 h of rainfall events. Discharge is generally along second-order streams; topography is the dominant influence on groundwater flow direction. The interbedded clays in the Georgetown Formation create a preferred horizontal to vertical anisotropy. The fractured nature of the aquifer produces local heterogeneity, but regionally, the aquifer acts as a diffuse rather than conduit flow system. Weathering results in a layered flow system with greater effective porosity and permeability in an upper zone compared to the deeper zone. Washita Prairie springs are perennial, with discharges generally <0.05 m 3 /s. The groundwater is calcium bicarbonate facies with total dissolved solids (TDS) <500 mg/L in most springs and shallow-zone wells. Water quality in deeper wells is more variable, as these encounter the deeper flow system with slower circulation and higher TDS. The shallow water table and rapid recharge through fractures allow surface activities to impact water quality, and nitrate levels appear to be elevated above average background values in places. The Washita Prairie segment of the Edwards (Balcones Fault Zone) Aquifer may be able to supply over 50,000,000 m 3 of sustainable water on an annual basis with continued study and proper management.

ABSTRACT The Edwards Aquifer along the Balcones fault zone is in a rapidly growing, urbanizing area. Urbanization creates major hydrogeological impacts, generally increasing impervious cover and flooding intensity, water demands, groundwater recharge, and temperatures both above and below the land surface; covering springs and small streams; altering the porosity and permeability fields; and contaminating groundwater, surface water, and soils. Urbanization also alters topography, natural flora, and the local climate. Several of these effects have either been documented or predicted for the Edwards Aquifer. Groundwater recharge from leaky utility systems and irrigation return flow is significant, particularly during times of low rainfall. The hydraulic properties of the epikarst, particularly the permeability field, can be highly modified. Aquifer water quality remains excellent, but increased anthropogenic chemical nitrate and chloride concentrations, and occasional bacteriological contamination have been observed. The eventual effects of these changes on the aquifers’ unique ecosystems is not known. Urbanization and urban sprawl are projected to increase, which will continue to alter the Edwards Aquifer system physically, chemically, and biologically. Understanding of these changes, their causes, and their effects is necessary to addressing the critical and growing environmental and water-resources issues of urban areas in the coming century.

ABSTRACT The Mitchell Plateau of south-central Indiana is one of the iconic karst landscapes of the United States. The sinkhole-dimpled forests, fields, and farms; the extensive cave systems; and the deep windows into the groundwater system have fostered curiosity, exploration, and publication since the mid-1800s. This paper is designed to complement a field excursion to the classic features of this landscape. Included are literature reviews focused on three karst basins of the Mitchell Plateau: Mill Creek–Mosquito Creek, Bluespring Caverns, and Lost River. Geomorphic, hydrologic, and geochemical data are synthesized in the modern context of our understanding of epigenetic karst. Revealed are three styles of karst basin: (1) small, shallow karst aquifers strongly controlled by meteoric recharge and epikarst percolation; (2) intermediate-size karst aquifers with significant base flow and surface-water–groundwater interaction; and (3) regional aquifer systems with outcrop belt recharge, downdip transport into confinement with long water-rock interaction times, and artesian flow or entrainment of mineralized waters through fractures into springs or surface waters. Quaternary glaciation has greatly influenced the vertical position of base level through river incision and sediment aggradation; conduit development is controlled by proximity to the major rivers and the stratigraphic position of conduits.

Karst systems continually evolve in response to complex hydrological and geochemical processes. A factor not previously considered is the role played by wavy free-surface fluid films in the geochemical erosion of microfractures. Films seeping down nearly vertical walls naturally evolve into wavy films, with some waves growing into solitons. Solitons that continue to grow eventually contact the opposite fracture wall, developing into capillary droplets that persist. The combination of capillary droplets surrounded by free-surface films creates a dissolve-and-sweep mechanism for soluble rocks such as limestone, dolomite, and gypsum. While films participate in calcite transfer from the matrix by diffusive processes, the pressure gradient imposed by a capillary droplet can extract pore solution from within the matrix, chemically leaching the matrix to a deeper depth than film flow. This chapter presents experimental evidence of the formation of droplets and provides a first-order analysis of their solute transfer and transport potential.

Weekly water samples collected in the spring and summer of 2012 demonstrate the dynamic geochemistry within the epikarst of an alpine karst aquifer in Timpanogos Cave National Monument in the Wasatch Mountains near Salt Lake City, Utah, USA. The results of chemical analysis of water from four cave pools, supplemented with concurrent samples from the American Fork River, suggest three modes of recharge: (1) diffuse recharge through the permeable matrix of the carbonate rock, (2) rapid recharge through open fractures in the epikarst, and (3) rapid recharge via piston flow through fractures occluded with colluvium. Water levels in the cave pools recharged by diffuse flow were very stable during the study period. Elevated dissolved solids characterized the geochemistry, including solutes associated with hydrothermal activity in this region (e.g., SO 4 2− and F − ). Isotopes of sulfur and carbon, along with cation-anion ratios suggest that sulfide oxidation may play some role in modern dissolution of the carbonate bedrock. In situ geochemical reactions influence the concentration of some solutes (e.g., HCO 3 − , Ca 2+ , F − ) and may cause a shift in the isotopes of dissolved inorganic carbon. Water levels in the cave pools characterized by rapid recharge, in comparison, were highly variable. When the flow path was direct, the geochemistry of the pool was strongly influenced by the timing and rate of recharge. During times of limited recharge, the geochemistry of these pools evolved toward the values of pools dominated by diffuse flow. On the other hand, when the flow path was impeded by colluvium, recharge was stored, and the geochemical signal was homogenized. In both cases, the source of recharge may be from elevations substantially above the cave pool.

The epikarst, which consists of highly weathered rock in the upper vadose zone of exposed karst systems, plays a critical role in determining the hydrologic and geochemical characteristics of recharge to an underlying karst aquifer. This study utilized time series (2007–2014) of hydrologic and geochemical data of drip water collected within James Cave, Virginia, to examine the influence of epikarst on the quantity and quality of recharge in a mature, doline-dominated karst terrain. Results show a strong seasonality of both hydrology and geochemistry of recharge, which has implications for management of karst aquifers in temperate climatic zones. First, recharge (discharge from the epikarst to the underlying aquifer) reaches a maximum between late winter and early spring, with the onset of the recharge season ranging from as early as December to as late as March during the study period. The timing and duration of the recharge season were found to be a function of precipitation in excess of evapotranspiration on a seasonal time scale. Secondly, seasonally variable residence times for water in the epikarst influence rock-water interaction and, hence, the geochemical characteristics of recharge. Overall, results highlight the strong and complex influence that the epikarst has on karst recharge, which requires long-term and high-resolution data sets to accurately understand and quantify.