ABSTRACT Under fast-moving oceanic plates, the asthenosphere seismic B″ region becomes isolated from the convecting mantle by plate drag and acts as an advecting layer, which can serve as a long-lived source for intraplate volcanism. Geochemical enrichment of B″ can occur via infiltration by melts generated from the breakdown of serpentinite at ~200 km depth in subducting slabs. Ocean-island chains arise when melts generated within metasomatized B″ by shear melting and localized convection are released along lithospheric fractures controlled by the stress field of the plate. Intersection of metasomatized B″ with ocean-ridge systems produces oceanic plateaus. A strong anisotropy anomaly (V SH /V SV >1) at depths of ~150 km in the Pacific asthenosphere marks a metasomatized B″ domain that originated in the western paleo-Pacific basin in the Carboniferous, and that is now associated with Hawaiian volcanism. Metasomatized B″ can be trapped beneath orogenic belts during continental aggregation and tapped by edge-driven convection upon rifting to produce the correlation between intraplate volcanism and the fabric of sutures in opening ocean basins such as the Atlantic Ocean basin.