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uramarsite

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Journal Article
Published: 01 February 2025
American Mineralogist (2025) 110 (2): 319–327.
... is explained here by the resonance splitting of a group of NH 4 + cations occurring around the fourfold axis at close distances from each other. Uramphite is related to uramarsite, (NH 4 )(UO 2 )(AsO 4 )·3H 2 O. The two minerals have similar crystal structures and IR spectra. However...
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Image
IR absorption spectra of (a) uramphite from Beshtau and (b) uramarsite holotype sample, [(NH4)1.15(H3O)0.72Na0.09]Σ1.96(UO2)2.02[(AsO4)1.22(PO4)0.78]Σ2.00·6.09H2O, from the Bota-Burum uranium deposit, Kazakhstan (Sidorenko et al. 2007).
Published: 01 February 2025
Figure 3. IR absorption spectra of ( a ) uramphite from Beshtau and ( b ) uramarsite holotype sample, [(NH 4 ) 1.15 (H 3 O) 0.72 Na 0.09 ] Σ1.96 (UO 2 ) 2.02 [(AsO 4 ) 1.22 (PO 4 ) 0.78 ] Σ2.00 ·6.09H 2 O, from the Bota-Burum uranium deposit, Kazakhstan ( Sidorenko et al. 2007 ).
Image
Crystal structure of uramarsite: (a) the structure projected along the [010]; (b) an arrangement of H2O, H3O+ (red spheres) and NH4+ (blue spheres) molecules in the interlayer space superimposed on the uranyl phosphate-arsenate layer. Legend: see Figure 5; As tetrahedra = dark-gray. (Color online.)
Published: 01 February 2025
Figure 6. Crystal structure of uramarsite: ( a ) the structure projected along the [010]; ( b ) an arrangement of H 2 O, H 3 O + (red spheres) and NH 4 + (blue spheres) molecules in the interlayer space superimposed on the uranyl phosphate-arsenate layer. Legend: see Figure 5
Journal Article
Published: 01 February 2009
American Mineralogist (2009) 94 (2-3): 399–408.
... Stereochimica Inorganica of Università degli Studi di Milano (2007–2). G.P. G.A. Sidorenko, N.V. Chukanov, N.I. Chistyakova, G.I. Bebeshko, A.E. Zadov, and I.S. Naumova (2007) Uramarsite (NH 4 ,H 3 O) 2 (UO 2 ) 2 (AsO 4 ,PO 4 ) 2 ·6H 2 O: a new mineral of the metaautunite group. Dokl. Akad. Nauk 415...
Journal Article
Published: 01 October 2018
Mineralogical Magazine (2018) 82 (5): 1089–1100.
..., mahnertite, malachite, marécottite, melanterite, metakahlerite, metasideronatrite, natrojarosite, plášilite, posnjakite, pseudojohannite, redcanyonite, römerite, sabugalite, schröckingerite, sideronatrite, sulfur, thénardite, thérèsemagnanite, uramarsite, uranospathite, wetherillite, zippeite and other...
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Journal Article
Published: 01 December 2023
American Mineralogist (2023) 108 (12): 2219–2233.
... ·8H 2 O] ( Locock and Burns 2003 ), uramarsite [(NH 4 ,H 3 O) 2 (UO 2 ) 2 (AsO 4 ,PO 4 ) 2 ·6H 2 O] ( Chukanov 2013 ; Sidorenko et al. 2007 ), and walpurgite [(BiO) 4 (UO 2 )(AsO 4 ) 2 ·2H 2 O] ( Frost et al. 2006f ; Mereiter 1982b ) make up the calculated average uranyl arsenate spectrum. Less...
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Journal Article
Published: 01 May 2019
American Mineralogist (2019) 104 (5): 779–784.
..., natrojarosite, plášilite, posnjakite, pseudojohannite, redcanyonite, römerite, sabugalite, schröckingerite, sideronatrite, sulfur, thénardite, thérèsemagnanite, uramarsite, uranospathite, wetherillite, zippeite, and other potentially new minerals (under investigation). Markeyite forms pale yellowish-green...
Journal Article
Published: 28 May 2018
Mineralogical Magazine (2019) 83 (3): 349–360.
..., metakahlerite, nováčekite-II, uramarsite and at least one additional potentially new Mg uranyl sulfate. At the Green Lizard mine, straβmannite is found on matrix comprised of mainly subhedral to euhedral, equant quartz crystals that are recrystallised counterparts of the original grains of the sandstone; some...
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Journal Article
Published: 01 January 2014
Reviews in Mineralogy and Geochemistry (2014) 79 (1): 17–184.
...  uramarsite (NH 4 ,H 3 O) 2 (UO 2 ) 2 [(As,P)O 4 ] 2 ·6H 2 O  uranospinite Ca(UO 2 ) 2 (AsO 4 ) 2 ·10H 2 O  zeunerite Cu(UO 2 ) 2 (AsO 4 ) 2 ·12H 2 O  walpurgite Bi 4 O 4 (UO 2 )(AsO 4 ) 2 ·2H 2 O Arsenites-arsenates  seelite Mg[(UO 2 )(AsO 3 ) 0.7 (AsO 4 ) 0.3 ] 2 >7H 2 O...
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Journal Article
Published: 01 January 2016
The Canadian Mineralogist (2016) 54 (1): 177–283.
... of uramarsite . Crystallography Reports 53 , 771 – 774 . Reis, A.H., Hoekstra, H.R., Gebert, E., & Peterson, S.W. (1976...
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Series: Short Courses
Published: 01 January 2013
DOI: 10.3749/9780921294689.ch03
EISBN: 978-0-921294-68-9
... 17.64 / 90 5 NH 4 [(UO 2 )(AsO 4 )](H 2 O) 3 uramarsite Q 7.19 / 90 7.19 / 90 9.15 / 90 6 Uranyl phosphates with large divalent cations Ca[(UO 2 )(PO 4 )] 2 (H 2 O) 6.5(?) meta-autunite P 4/ nmm 6.99 / 90 6.99 / 90 8.43 / 90 7 Ca[(UO 2 )(PO 4 )] 2 (H 2 O) 11 Autunite...
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