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1-20 OF 75 RESULTS FOR
trisilicates
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Journal Article
Synthesis and structural study of five new trisilicates, BaREE 2 Si 3 O 10 (REE = Gd, Er, Yb, Sc) and SrY 2 Si 3 O 10 , including a review on the geometry of the Si 3 O 10 unit
Journal: European Journal of Mineralogy
Published: 01 March 2010
European Journal of Mineralogy (2010) 22 (2): 245–258.
...Maria Wierzbicka-Wieczorek; Uwe Kolitsch; Ekkehart Tillmanns Abstract Five new mixed-framework trisilicates were synthesised using a high-temperature flux growth technique. Colourless, glassy plates of SrY 2 Si 3 O 10 crystallise in space group P 1̅, with a = 6.757(1), b = 6.885(1), c = 9.273(2) Å...
Image
Comparison of Si 3 O 10 arrangements in other selected trisilicates: a) Na...
in Synthesis and structural study of five new trisilicates, BaREE 2 Si 3 O 10 (REE = Gd, Er, Yb, Sc) and SrY 2 Si 3 O 10 , including a review on the geometry of the Si 3 O 10 unit
> European Journal of Mineralogy
Published: 01 March 2010
Fig. 9. Comparison of Si 3 O 10 arrangements in other selected trisilicates: a) Na 2 Ca 3 (Si 3 O 10 ), b) SrY 2 (Si 3 O 10 ), c) Na 4 Cd 2 (Si 3 O 10 ), d) kilchoanite, Ca 6 (Si 3 O 10 )(SiO 4 ), e) BaGd 2 (Si 3 O 10 ), f) SrYb 4 (Si 2 O 7 )(Si 3 O 10 ), g) kinoite, Cu 2 Ca 2 Si 3 O 10 (H 2 O
Journal Article
Rosenhahnite, Ca 3 Si 3 O 8 (OH) 2 ; crystal structure and the stereochemical configuration of the hydroxylated trisilicate group, [Si 3 O 8 (OH) 2 ]
Journal: American Mineralogist
Publisher: Mineralogical Society of America
Published: 01 June 1977
American Mineralogist (1977) 62 (5-6): 503–512.
...–O bond lengths is 0.002A. The crystal structure of rosenhahnite consists of Ca(1)O 7 , Ca(2)O 6 , and Ca(3)O 7 polyhedra and insular [Si 3 O 8 (OH) 2 ] groups. The trisilicate group with point symmetry 1 consists of a central SiO 4 tetrahedron sharing corners with two adjacent SiO 3 (OH) tetrahedra...
Image
Detail of the local environments of the triple silicate groups in demagistr...
in Demagistrisite, the Missing Link in a Polysomatic Series from Lawsonite to Orientite
> The Canadian Mineralogist
Published: 08 January 2021
Fig. 6. Detail of the local environments of the triple silicate groups in demagistrisite. Approximately 7% of the trisilicate groups are substituted by a local “ardennite-like” structure with a further tetrahedra (in cyan) outside of the trisilicate group and the Si3 tetrahedron substituted
Journal Article
K 2 Ca 3 Si 3 O 10 , a novel trisilicate: high-pressure synthesis, structural, spectroscopic and computational studies
Journal: European Journal of Mineralogy
Published: 01 June 2011
European Journal of Mineralogy (2011) 23 (3): 425–435.
... pressure experiments. Am. Mineral. , 75 , 1020 –1028. Wierzbicka-Wieczorek, M., Kolitsch, U., Tillmanns, E. ( 2010 ): Synthesis and structural study of five new trisilicates, BaREE 2 Si 3 O 10 (REE = Gd, Er, Yb, Sc) and SrY 2 Si 3 O 10 , including a review on the geometry of the Si 3 O 10 unit...
Image
The crystal structure of a new sodium trisilicate.
Published: 01 January 2000
Figure 12. The crystal structure of a new sodium trisilicate.
Journal Article
Pavlovskyite Ca 8 (SiO 4 ) 2 (Si 3 O 10 ): A new mineral of altered silicate-carbonate xenoliths from the two Russian type localities, Birkhin massif, Baikal Lake area and Upper Chegem caldera, North Caucasus
Evgeny V. Galuskin, Frank Gfeller, Valentina B. Savelyeva, Thomas Armbruster, Biljana Lazic, Irina O. Galuskina, Daniel M. Többens, Aleksandr E. Zadov, Piotr Dzierżanowski, Nikolai N. Pertsev, Viktor M. Gazeev
Journal: American Mineralogist
Publisher: Mineralogical Society of America
Published: 01 April 2012
American Mineralogist (2012) 97 (4): 503–512.
...%. Pavlovskyite represents a 1:1 member of a polysomatic series with calcio-olivine γ-Ca 2 SiO 4 and kilchoanite Ca 6 (SiO 4 )(Si 3 O 10 ) as end-member modules. The structure is characterized by strongly folded trisilicate units (Si 3 O 10 ) interwoven with a framework of CaO 6 and CaO 8 polyhedra. Olivine-like...
Includes: Supplemental Content
Journal Article
STRUCTURAL ENVIRONMENTS AROUND MOLYBDENUM IN SILICATE GLASSES AND MELTS. I. INFLUENCE OF COMPOSITION AND OXYGEN FUGACITY ON THE LOCAL STRUCTURE OF MOLYBDENUM
Journal: The Canadian Mineralogist
Publisher: Mineralogical Association of Canada
Published: 01 June 2006
The Canadian Mineralogist (2006) 44 (3): 731–753.
...François Farges; Ralf Siewert; Gordon E. Brown, Jr.; Anne Guesdon; Guillaume Morin Abstract The coordination chemistry of molybdenum was investigated in nine series of synthetic silicate glasses, including sodium disilicate (NS2), sodium trisilicate (NS3), albite (Ab), anorthite (An), Ab 50 An 50...
Journal Article
Water in Zr-bearing synthetic and natural glasses
Journal: European Journal of Mineralogy
Published: 01 November 2000
European Journal of Mineralogy (2000) 12 (6): 1093–1107.
...François FARGES; Stéphanie ROSSANO Abstract The local environment of ∼ 1400 ppm Zr in hydrous synthetic glasses (sodium trisilicate and albitic) has been probed at the Zr K-edge by X-ray Absorption Fine Structure (XAFS) spectroscopy and compared to that for natural glasses (volcanic and tektites...
Image
View of zigzag chains and horseshoe-shaped trisilicate (Si 3 O 10 ) unit in...
in Synthesis and structural study of five new trisilicates, BaREE 2 Si 3 O 10 (REE = Gd, Er, Yb, Sc) and SrY 2 Si 3 O 10 , including a review on the geometry of the Si 3 O 10 unit
> European Journal of Mineralogy
Published: 01 March 2010
Fig. 3. View of zigzag chains and horseshoe-shaped trisilicate (Si 3 O 10 ) unit in BaREE 2 (Si 3 O 10 ) (REE = Gd, Y, Er, Yb, Sc) along [100].
Image
View of BaYb 6 (Si 2 O 7 ) 2 (Si 3 O 10 ) along [100], showing the zigzag c...
in BaYb 6 (Si 2 O 7 ) 2 (Si 3 O 10 ) – the first silicate containing both Si 2 O 7 and Si 3 O 10 groups: synthesis, crystal chemistry and topology
> European Journal of Mineralogy
Published: 01 December 2013
Fig. 2 View of BaYb 6 (Si 2 O 7 ) 2 (Si 3 O 10 ) along [100], showing the zigzag chains and the di- and trisilicate groups in the ratio 2:1. The unit cell is outlined, c * = c sinβ.
Image
Crystal structure of BaY 4 (Si 2 O 7 )(Si 3 O 10 ) ( Wierzbicka-Wieczorek, ...
in BaYb 6 (Si 2 O 7 ) 2 (Si 3 O 10 ) – the first silicate containing both Si 2 O 7 and Si 3 O 10 groups: synthesis, crystal chemistry and topology
> European Journal of Mineralogy
Published: 01 December 2013
Fig. 4 Crystal structure of BaY 4 (Si 2 O 7 )(Si 3 O 10 ) ( Wierzbicka-Wieczorek, 2007 ) along [100], showing the zigzag chains and the di- and trisilicate groups in the ratio 1:1, c * = c sinβ. Compare Fig. 2 .
Journal Article
Demagistrisite, the Missing Link in a Polysomatic Series from Lawsonite to Orientite
Fernando Cámara, Anthony R. Kampf, Fabrizio Nestola, Marco E. Ciriotti, Deborah Spartá, Corrado Balestra
Journal: The Canadian Mineralogist
Publisher: Mineralogical Association of Canada
Published: 08 January 2021
The Canadian Mineralogist (2021) 59 (1): 91–105.
...Fig. 6. Detail of the local environments of the triple silicate groups in demagistrisite. Approximately 7% of the trisilicate groups are substituted by a local “ardennite-like” structure with a further tetrahedra (in cyan) outside of the trisilicate group and the Si3 tetrahedron substituted...
Image
Molybdenum K-edge XANES spectra for dry and H 2 O-bearing densified felsdpa...
in STRUCTURAL ENVIRONMENTS AROUND MOLYBDENUM IN SILICATE GLASSES AND MELTS. II. EFFECT OF TEMPERATURE, PRESSURE, H 2 O, HALOGENS AND SULFUR
> The Canadian Mineralogist
Published: 01 June 2006
F ig . 4. Molybdenum K-edge XANES spectra for dry and H 2 O-bearing densified felsdpathic glasses (a) and sodium trisilicate glasses (b). Changes in the pre-edge feature (A) are observed only in NS3 glasses and are attributed to the presence of Mo(IV) moieties.
Image
Molybdenum K-edge-normalized, k 3 -weighted EXAFS spectra (a) (solid: exper...
in STRUCTURAL ENVIRONMENTS AROUND MOLYBDENUM IN SILICATE GLASSES AND MELTS. II. EFFECT OF TEMPERATURE, PRESSURE, H 2 O, HALOGENS AND SULFUR
> The Canadian Mineralogist
Published: 01 June 2006
F ig . 5. Molybdenum K-edge-normalized, k 3 -weighted EXAFS spectra (a) (solid: experimental; dotted: calculated model) and their corresponding Fourier-transforms (b) for various dry and hydrous densified feldpathoidal and sodium trisilicate glasses. No splitting of features in the FT
Journal Article
BaYb 6 (Si 2 O 7 ) 2 (Si 3 O 10 ) – the first silicate containing both Si 2 O 7 and Si 3 O 10 groups: synthesis, crystal chemistry and topology
Journal: European Journal of Mineralogy
Published: 01 December 2013
European Journal of Mineralogy (2013) 25 (4): 509–517.
...Fig. 2 View of BaYb 6 (Si 2 O 7 ) 2 (Si 3 O 10 ) along [100], showing the zigzag chains and the di- and trisilicate groups in the ratio 2:1. The unit cell is outlined, c * = c sinβ. ...
Journal Article
A new rare earth disilicate (REE 2 Si 2 O 7 ; REE = Dy, Tm, Lu; type-L): Evidence for non-quenchable 10 GPa polymorph with silicon in fivefold trigonal bipyramidal coordination?
Journal: American Mineralogist
Publisher: Mineralogical Society of America
Published: 01 February 2004
American Mineralogist (2004) 89 (2-3): 396–404.
... = 83.977(2), β = 88.074(2), γ = 87.846(2)°, V = 755.8 Å 3 , and D x = 6.830 g/cm 3 . The type-L structure comprises linear trisilicate [Si 3 O 10 ] 8− and orthosilicate [SiO 4 ] 4− ions cross linked by REE 3+ in one sevenfold and five eightfold coordinated positions (to 3.0 Å), and is assembled from...
Journal Article
Continuous Cauchy wavelet transform analyses of EXAFS spectra: A qualitative approach
Journal: American Mineralogist
Publisher: Mineralogical Society of America
Published: 01 April 2003
American Mineralogist (2003) 88 (4): 694–700.
... and environmental interest, including sodium trisilicate glass and an aqueous chloride solution, at the Mo K and Au L III edges, respectively. Further studies based on CCWT phase terms are underway, in order to quantitatively characterize anharmonic information from EXAFS contributions. * E-mail: munoz...
Journal Article
Tiragalloite, Mn 4 [AsSi 3 O 12 (OH)], a new mineral and the first example of arsenatotrisilicate
Journal: American Mineralogist
Publisher: Mineralogical Society of America
Published: 01 October 1980
American Mineralogist (1980) 65 (9-10): 947–952.
... feature is the presence of an arsenatotrisilicate ion (AsSi 3 O 12 OH) 8− , comprising four tetrahedra linked together to form a chain fragment. This new ion is an extension of the trisilicate (Si 3 O 10 ) 8− ion with an additional As-centered tetrahedron linked to it. This example is the first of a new...
Image
Total sulfur in the melt as a function of oxygen fugacity (relative to the ...
in Experimental Studies on Sulfur Solubility in Silicate Melts at Near-Atmospheric Pressure
> Reviews in Mineralogy and Geochemistry
Published: 01 January 2011
(log S )/ d (log f O 2 )) = −3/2, respectively. Data: 39.4 SiO 2 -43.3 CaO-17.3 Al 2 O 3 -melts: Black full symbols, square = 1425 °C, circle = 1500 °C, triangle = 1550 °C, Fincham and Richardson (1954) ; SiO 2 -Na 2 O-melts at 1200 °C: Half-filled symbols, circle = trisilicate, square = disilicate