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stefanweissite

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Journal Article
Published: 01 August 2021
American Mineralogist (2021) 106 (8): 1255–1272.
...+ = Ca + 3 Me 5+ + Me 2+ ), and Stålaker-type mode (0.7 ACT + 0.5 REE + 0.9 Ti + 0.7 Me 3+ + 0.05 Zr = 1.2 Ca + 1.3 Me 5+ + 0.3 Me 2+ + 0.05 Mn). In terms of chemical composition, the studied zirconolite corresponds to recently approved zirconolite-related minerals stefanweissite (for Ca > REE...
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Journal Article
Published: 21 January 2019
Mineralogical Magazine (2019) 83 (4): 607–614.
...Nikita V. Chukanov; Natalia V. Zubkova; Igor V. Pekov; Marina F. Vigasina; Yury S. Polekhovsky; Bernd Ternes; Willi Schüller; Sergey N. Britvin; Dmitry Yu. Pushcharovsky Abstract The new mineral stefanweissite, IMA2018-020, was discovered in sanidinite volcanic ejecta from the Laach Lake (Laacher...
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Ratios of large VIIIM1 cations in orthorhombic zirconolite-type minerals from the Laach Lake volcano: the holotype stefanweissite (black square); other stefanweissite samples (open squares); and nöggerathite-(Ce) (open circles – our data; black circle – analysis 1 from Della Ventura et al., 2000).
Published: 21 January 2019
Fig. 5. Ratios of large VIII M 1 cations in orthorhombic zirconolite-type minerals from the Laach Lake volcano: the holotype stefanweissite (black square); other stefanweissite samples (open squares); and nöggerathite-(Ce) (open circles – our data; black circle – analysis 1 from Della Ventura
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Raman spectrum of stefanweissite.
Published: 21 January 2019
Fig. 2. Raman spectrum of stefanweissite.
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[100] projection of the stefanweissite structure showing sawtooth layers of corner-connected octahedra.
Published: 14 April 2021
Fig. 5. [100] projection of the stefanweissite structure showing sawtooth layers of corner-connected octahedra.
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The crystal structure of stefanweissite: general view. The unit cell is outlined. For legend see Fig. 3.
Published: 21 January 2019
Fig. 4. The crystal structure of stefanweissite: general view. The unit cell is outlined. For legend see Fig. 3 .
Journal Article
Published: 14 April 2021
Mineralogical Magazine (2021) 85 (3): 348–353.
...Fig. 5. [100] projection of the stefanweissite structure showing sawtooth layers of corner-connected octahedra. ...
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Published: 14 April 2021
Table 5. Crystallographic parameters for aldermanite, walentaite and stefanweissite. Aldermanite Walentaite Stefanweissite Formula [Mg(H 2 O) 6 ] [Na(H 2 O) 2 Al 3 (PO 4 ) 2 (OH,F) 6 ]⋅H 2 O [Mn 2+ (H 2 O) 6 ] [ ${\rm As}_3^{3 + }$ O ${\rm Fe}_3^{3 + }$ (PO 4 ) 2 O
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Published: 14 April 2021
Table 5. Crystallographic parameters for aldermanite, walentaite and stefanweissite. Aldermanite Walentaite Stefanweissite Formula [Mg(H 2 O) 6 ] [Na(H 2 O) 2 Al 3 (PO 4 ) 2 (OH,F) 6 ]⋅H 2 O [Mn 2+ (H 2 O) 6 ] [ ${\rm As}_3^{3 + }$ O ${\rm Fe}_3^{3 + }$ (PO 4 ) 2 O
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Published: 14 April 2021
Table 5. Crystallographic parameters for aldermanite, walentaite and stefanweissite. Aldermanite Walentaite Stefanweissite Formula [Mg(H 2 O) 6 ] [Na(H 2 O) 2 Al 3 (PO 4 ) 2 (OH,F) 6 ]⋅H 2 O [Mn 2+ (H 2 O) 6 ] [ ${\rm As}_3^{3 + }$ O ${\rm Fe}_3^{3 + }$ (PO 4 ) 2 O
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Octahedral (a) and large-cation (b) layers and arrangement of Fe-dominant sites M5 and M6 inside the octahedral layer (c) in the structure of stefanweissite.
Published: 21 January 2019
Fig. 3. Octahedral ( a ) and large-cation ( b ) layers and arrangement of Fe-dominant sites M 5 and M 6 inside the octahedral layer ( c ) in the structure of stefanweissite.
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Aggregates of brown lath- and needle-shaped crystals of stefanweissite on sanidine, in association with biotite (a, c) and magnetite (b). Photographer: Stefan Wolfsried. Field of view widths: (a) 1 mm; (b) 1.5 mm; (c) 0.8 mm; and (d) 2 mm.
Published: 21 January 2019
Fig. 1. Aggregates of brown lath- and needle-shaped crystals of stefanweissite on sanidine, in association with biotite ( a , c ) and magnetite ( b ). Photographer: Stefan Wolfsried. Field of view widths: ( a ) 1 mm; ( b ) 1.5 mm; ( c ) 0.8 mm; and ( d ) 2 mm.
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Published: 21 January 2019
Table 1. Reflectance values ( R max / R min ) for stefanweissite. λ (nm) R max R min λ (nm) R max R min 400 16.6 15.5 560 15.4 14.1 420 16.4 15.2 580 15.2 14.0 440 16.2 15.0 589 15.2 13.89 460 16.1 14.8 600 15.1 13.8 470
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Published: 21 January 2019
Table 3. Powder X-ray diffraction data for stefanweissite. I obs I calc * d obs d calc ** h k l 4 2 4.121 4.129 0 2 2 8 12 3.682 3.689 1 3 1 4 2 3.335 3.340 0 4 1 100 100 2.983 2.963 2 0 2 71 93 2.897 2.903 0 4 2
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Published: 21 January 2019
Table 6. Selected interatomic distances (Å) in the structure of stefanweissite. M 1–O3 2.388(3) × 2 M 2–O4 2.092(4) M 3–O1 1.964(3) × 4 M 1–O4 2.440(3) × 2 M 2–O2 2.126(3) × 2 M 3–O4 2.044(5) × 2 M 1–O1 2.490(3) × 2 M 2–O3 2.132(5) < M 3–O> 1.991
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Published: 21 January 2019
Table 7. Comparative data for stefanweissite and related minerals. Mineral Stefanweissite Nöggerathite-(Ce) Zirconolite-3 O Laachite Idealised formula (Ca, REE ) 2 Zr 2 (Nb,Ti) (Ce,Ca) 2 Zr 2 (Nb,Ti) CaZrTi 2 O 7 Ca 2 Zr 2 Nb 2 TiFeO 14 (Ti,Nb) 2 Fe 2+ O 14 (Ti,Nb) 2
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Published: 21 January 2019
Table 2. Chemical composition of stefanweissite. Constituent Wt.% Range S.D. Standard CaO 7.63 6.53–8.52 0.69 Wollastonite MnO 2.51 2.07–2.80 0.29 MnTiO 3 FeO 7.86 6.97–8.68 0.57 Fe Al 2 O 3 0.25 0–0.53 0.22 Albite La 2 O 3 2.28 1.85–2.74 0.31
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Compositions of zirconolite from the LPC projected in the ternary plots involving elements assumed to occupy the M[VIII] (a) and M[VI,V,IV] (b) sites, and their comparison with other occurrences worldwide. The Ca vertex represents Ca + [VIII]Mn in the cases of laachite, stefanweissite, nöggerathite, and zirconolite-3T from Laacher See using structural models of Chukanov et al. (2014, 2018, 2019) and Zubkova et al. (2018). (Color online.)
Published: 01 August 2021
, stefanweissite, nöggerathite, and zirconolite-3 T from Laacher See using structural models of Chukanov et al. (2014 , 2018 , 2019 ) and Zubkova et al. (2018) . (Color online.)
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X-ray powder diffraction patterns of thermally annealed zirconolite from the LPC and their Rietveld analyses. (a) Zirconolite annealed at 800 °C. Rietveld refinement is based on the structural model of a cubic ZrO2 (labeled cub; Wyckoff 1963). (b) Zirconolite annealed at 900 °C. Rietveld refinement is based on structural models of stefanweissite (labeled 3O; Chukanov et al. 2019) and zirconolite-3T (labeled 3T; Zubkova et al. 2018). Weight fractions of 0.612(4) and 0.388(5) are obtained for the two phases. (Color online.)
Published: 01 August 2021
. Rietveld refinement is based on structural models of stefanweissite (labeled 3O; Chukanov et al. 2019 ) and zirconolite-3 T (labeled 3 T ; Zubkova et al. 2018 ). Weight fractions of 0.612(4) and 0.388(5) are obtained for the two phases. (Color online.)
Journal Article
Published: 07 August 2018
Mineralogical Magazine (2018) 82 (4): 1015–1021.
... Stefanweissite (Ca, REE ) 2 Zr 2 (Nb,Ti)(Ti,Nb) 2 Fe 2+ O 14 In den Dellen (Zieglowski) pumice quarry, 1.5 km NE of Mendig, Laach Lake (Laacher See) volcano, Eifel region, Rhineland-Palatinate, Germany Nikita V. Chukanov*, Natalia V. Zubkova, Igor V. Pekov, Marina F. Vigasina, Yury S. Polekhovsky...