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rhombohedral system

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Journal Article
Published: 01 April 1987
American Mineralogist (1987) 72 (3-4): 329–336.
...Benjamin P. Burton Abstract A three-parameter version of the tetrahedron approximation in the cluster-variation method is used to model cation ordering in rhombohedral carbonate systems. The model is sufficient to calculate theoretical phase diagrams that are in complete qualitative agreement...
Journal Article
Published: 01 March 2023
American Mineralogist (2023) 108 (3): 584–594.
... the potential to preserve elemental and isotopic biomarkers relevant to the search for life in the solar system. The crystal structures and chemistry of jarosite minerals affect their stability and reactivity and thus the roles they play in natural and engineered systems. Rhombohedral symmetry has been...
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Example compositional trends in crystals of congolite from the Kłodawa Salt Mine, presented in the system Fe3B7O13Cl–Mg3B7O13Cl–Mn3B7O13Cl. (a) Crystals with rhombohedral cores (45c). (b) Crystals without rhombohedral cores (7b). Symbols: ‘R’ and an orange arrow – compositions corresponding to rhombohedral morphology; ‘O’ and green arrows – compositions corresponding to orthorhombic morphology; ‘C’ and violet arrows – compositions corresponding to cubic morphology; ‘C1’ and ‘C2’, and blue and pale green arrows – compositions from additional zones of cubic morphology. Empty circles (o) and crosses (+) represent data points from two independent microprobe sessions.
Published: 01 October 2012
Fig. 6 Example compositional trends in crystals of congolite from the Kłodawa Salt Mine, presented in the system Fe 3 B 7 O 13 Cl–Mg 3 B 7 O 13 Cl–Mn 3 B 7 O 13 Cl. (a) Crystals with rhombohedral cores (45c). (b) Crystals without rhombohedral cores (7b). Symbols: ‘R’ and an orange arrow
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Plot of ilmenite mole fraction (Xil) in rhombohedral oxide versus ülvospinel mole fraction (X uv) in coexisting cubic oxide, contoured for temperature (°C) and fO2 (log10 units relative to NNO buffer) in the system Fe-Ti-O. The dashed lines denote the miscibility gap in the rhombohedral oxide phase; the presence of minor components profoundly affects the size and shape of this gap. Figure from Ghiorso and Evans (2008) kindly supplied by M. Ghiorso.
Published: 01 January 2008
Figure 11. Plot of ilmenite mole fraction ( X il ) in rhombohedral oxide versus ülvospinel mole fraction (X uv ) in coexisting cubic oxide, contoured for temperature (°C) and f O 2 (log 10 units relative to NNO buffer) in the system Fe-Ti-O. The dashed lines denote the miscibility gap
Journal Article
Published: 01 May 1938
American Mineralogist (1938) 23 (5): 314–328.
...M. A. Peacock; M. C. Bandy Abstract Ungemachite . System and lattice, hexagonal— R; class, rhombohedral— 3 ; a : c = 1:2.2966; α=62°5½′; 32 forms. Habit, thick tabular {0003}{111}. Space group C 3i 2 — R 3 . Hexagonal cell dimensions: a 0 = 10.84 ± 0.02 Å, c 0 = 24.82±0.05 Å; a 0 : c 0 = 1:2.290...
Journal Article
Published: 01 December 1980
American Mineralogist (1980) 65 (11-12): 1252–1262.
... that the small amounts of Sr in natural metamorphic aragonite extend the field of its stabihty to slightly lower pressures than in the unary CaCO 3 system. The phase equilibrium data also provide evidence for the existence of two structurally distinct rhombohedral carbonates at elevated pressures in the binary...
Journal Article
Published: 01 December 1937
American Mineralogist (1937) 22 (12): 1139–1150.
... system are also discussed. These are vital to an accurate unit cell determination and have not previously been discussed in this connection. Two previous investigations have assigned tourmaline to space groups based upon a hexagonal lattice. This equi-inclination study plainly shows that it is based...
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Phase diagram for the PZT (PbTiO3 – PbZrO3) system. Tetragonal and rhombohedral phase fields are separated by a nearly vertical morphotropic phase boundary (MPB). Adapted from Figure 1 in Oh and Jang (1999).
Published: 01 January 2000
Figure 14. Phase diagram for the PZT (PbTiO 3 – PbZrO 3 ) system. Tetragonal and rhombohedral phase fields are separated by a nearly vertical morphotropic phase boundary (MPB). Adapted from Figure 1 in Oh and Jang (1999) .
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Primary moissanite in the Dongjiashan serpentinite, natural light. (a) Free crystal, hexagonal, colourless, uniaxial (+), sample #23, (b) free crystal, hexagonal, blue, biaxial (+), sample #17, (c) free crystal, hexagonal, light blue, biaxial (+), sample #56, (d) free crystal, hexagonal, blue, biaxial (+) with global inclusion, sample #19, (e) free crystal, rhombohedral, yellow, biaxial (+), with {110} and needle-shaped native Si, sample #21, (f) aggregate, rhombohedral, light-blue, uniaxial (+), sample #3, (g) moissanite in thin section 04121, hexagonal, colorless, biaxial (+), (h) moissanite in thin section 04122, various colours, biaxial (+), crystal system uncertain, (i) moissanite in thin section 04124, colourless, biaxial (+), crystal system uncertain. Explanations are given in text. Si: metal silicon, Fe: native Fe, Ru: rutile, M: moissanite. Scale bar is 100 μm, inset in b, d, g and i is the biaxial interference figure of moissanite.
Published: 01 August 2008
, hexagonal, blue, biaxial (+) with global inclusion, sample #19, ( e ) free crystal, rhombohedral, yellow, biaxial (+), with {110} and needle-shaped native Si, sample #21, ( f ) aggregate, rhombohedral, light-blue, uniaxial (+), sample #3, ( g ) moissanite in thin section 04121, hexagonal, colorless, biaxial
Journal Article
Published: 01 January 1990
Reviews in Mineralogy and Geochemistry (1990) 24 (1): 191–212.
... redox state of the residual liquid, so that it may resemble a buffered path. Addition or subtraction of oxygen to the system (liquid plus solids) at constant temperature will initially change the proportions of the solids. But should the oxygen fugacity change, then the iron redox ratio...
Series: SEPM Gulf Coast Section Publications
Published: 01 December 2010
DOI: 10.5724/gcs.10.30.0115
EISBN: 978-0-9836096-0-5
... associated with downwind sediment flux in a wind-dominated depositional system. Sediment flux in the interpreted east-west current dominant setting has produced east-west elongate platforms while rhombic-shaped platforms have evolved from elliptical platforms and later expanded in a direction perpendicular...
Journal Article
Published: 01 October 2010
Mineralogical Magazine (2010) 74 (5): 841–848.
.... This suggestion is in general agreement with the previous observations which demonstrated, for the Mg-Al system, a higher-temperature regime of formation of the hexagonal (or pseudo-hexagonal in the case of quintinite-2 H -3 c ) 2 H polytype in comparison to the rhombohedral (or pseudo-rhombohedral in the case...
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Published: 01 January 2007
DOI: 10.1130/2007.2421(04)
... system. A complete single-crystal elasticity tensor of FeO was determined up to 10 GPa, and only minor changes of elastic moduli were detected at the magnetic transition pressure, indicating relatively weak magnetoelastic coupling in FeO at high pressures. The existence of a rhombohedral distortion...
Journal Article
Published: 01 September 2000
Journal of Sedimentary Research (2000) 70 (5): 1152–1159.
... in a rock-buffered diagenetic system, where the fluid contained significant amounts of dissolved constituents from the aragonite. Examples of spheroidal to quasi-rhombohedral dolomite and Mg-calcite in the literature include a diverse array of crystal morphology and internal microfabric. Quasi...
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Journal Article
Published: 01 February 1955
American Mineralogist (1955) 40 (1-2): 94–106.
...Lester W. Strock; Vincent A. Brophy Abstract Polytype crystals of ZnS or SiC consist of structures based on unit cells whose [ c ] axis spacing is some multiple of the number of layers on one atom sort contained in the simple hexagonal (2-layer) or rhombohedral (3-layer) polymorph prototypes. Known...
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Schematic model for the effect of magnesium on calcite morphology shows the transition from (a) the rhombohedral form of the pure system to a situation where strain at the intersection of the ± directions leads to (b) a new step direction and development of a new “face” (b, c, d). The result of this transition is the development of an elongated structure with a roughened (rounded at macroscopic scale) and elongated form.
Published: 01 May 2004
F igure 5. Schematic model for the effect of magnesium on calcite morphology shows the transition from ( a ) the rhombohedral form of the pure system to a situation where strain at the intersection of the ± directions leads to ( b ) a new step direction and development of a new “face” ( b , c
Journal Article
Published: 01 May 2012
American Mineralogist (2012) 97 (5-6): 807–815.
.... However, the chemical composition and crystal structure were well constrained by extensive quantitative energy-dispersive X-ray analysis and electron diffraction using transmission electron microscopy (TEM). The crystal system for wassonite is rhombohedral ( a = 3.42 ± 0.07, c = 26.50 ± 0.53 Å) with space...
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Journal Article
Published: 01 January 2015
American Mineralogist (2015) 100 (1): 130–137.
...Anton Shatskiy; Sergey V. Rashchenko; Eiji Ohtani; Konstantin D. Litasov; Mikhail V. Khlestov; Yuri M. Borzdov; Igor N. Kupriyanov; Igor S. Sharygin; Yuri N. Palyanov Abstract The phase relations in the Na 2 CO 3 -(Fe 0.87 Mn 0.06 Mg 0.07 )CO 3 system have been studied in Kawai-type multi-anvil...
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Journal Article
Published: 01 December 1973
American Mineralogist (1973) 58 (11-12): 979–985.
... (MgBa(CO 3 ) 2 ), MgSr(CO 3 ) 2 and two forms of CaBa(CO 3 ) 2 , a monoclinic barytocalcite and a rhombohedral form with disordered calcite structure. In the system MgCO 3 -CaCO 3 -BaCO 3 , both norsethite and disordered calcite have detectable ranges of solid solution at 650°C and 5 kbar, and six two...
Journal Article
Published: 01 February 2008
The Canadian Mineralogist (2008) 46 (1): 111–124.
... with the adjacent amethyst. Analysis of different colors on major ( r = {101̅1}) and minor ( z = {011̅1}) rhombohedral sectors within the quartz indicates that changes in the growth rate also have influenced color development. As the system evolved, two factors contributed to the color changes. A minor ferric...
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