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pillaite

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Journal Article
Published: 01 April 2012
The Canadian Mineralogist (2012) 50 (2): 219–233.
... on the temperature of deposition, Pb 2 Sb 2 S 5 or halogen-bearing sulfosalts such as dadsonite or iodine-substituted pillaite can be prepared as well. By means of thermodynamic modeling, the chemical vapor-transport reaction of boulangerite is described, and an explanation for the formation of the halogen...
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Journal Article
Published: 01 July 2001
European Journal of Mineralogy (2001) 13 (4): 779–790.
...Alain MEERSCHAUT; Pierre PALVADEAU; Yves MOËLO; Paolo ORLANDI Abstract The crystal structure of pillaite, a recently described Pb-Sb oxy-chloro-sulfosalt from the Buca della Vena mine, Tuscany (Italy), was solved and refined to a residual R of 0.045 in the monoclinic system, with space group C2/m...
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Journal Article
Published: 01 May 2001
European Journal of Mineralogy (2001) 13 (3): 605–610.
...Paolo ORLANDI; Yves MOËLO; Alain MEERSCHAUT; Pierre Palvadeau Abstract The new mineral pillaite, Pb 9 Sb 10 S 23 ClO 0.5 , an oxy-chloro-sulfosalt, has been found at Buca della Vena mine in the Apuan Alps, northern Tuscany, Italy. It crystallized in small fractures of dolomitic lenses in massive...
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Schematically drawn projection of crystal structures of a) dadsonite [ b – ...
Published: 01 April 2012
Fig. 5 Schematically drawn projection of crystal structures of a) dadsonite [ b – c plane], b) iodine-substituted pillaite [ a – c plane]; HRTEM lattices images of a fiber cross-section of: c) dadsonite with B || [100]; the black solid lines mark the chain-like structure fragments; d) iodine
Image
Schematically drawn projection of crystal structures of a) dadsonite [ b – ...
Published: 01 April 2012
Fig. 5 Schematically drawn projection of crystal structures of a) dadsonite [ b – c plane], b) iodine-substituted pillaite [ a – c plane]; HRTEM lattices images of a fiber cross-section of: c) dadsonite with B || [100]; the black solid lines mark the chain-like structure fragments; d) iodine
Image
Schematically drawn projection of crystal structures of a) dadsonite [ b – ...
Published: 01 April 2012
Fig. 5 Schematically drawn projection of crystal structures of a) dadsonite [ b – c plane], b) iodine-substituted pillaite [ a – c plane]; HRTEM lattices images of a fiber cross-section of: c) dadsonite with B || [100]; the black solid lines mark the chain-like structure fragments; d) iodine
Image
Schematically drawn projection of crystal structures of a) dadsonite [ b – ...
Published: 01 April 2012
Fig. 5 Schematically drawn projection of crystal structures of a) dadsonite [ b – c plane], b) iodine-substituted pillaite [ a – c plane]; HRTEM lattices images of a fiber cross-section of: c) dadsonite with B || [100]; the black solid lines mark the chain-like structure fragments; d) iodine
Image
Schematically drawn projection of crystal structures of a) dadsonite [ b – ...
Published: 01 April 2012
Fig. 5 Schematically drawn projection of crystal structures of a) dadsonite [ b – c plane], b) iodine-substituted pillaite [ a – c plane]; HRTEM lattices images of a fiber cross-section of: c) dadsonite with B || [100]; the black solid lines mark the chain-like structure fragments; d) iodine
Image
Schematically drawn projection of crystal structures of a) dadsonite [ b – ...
Published: 01 April 2012
Fig. 5 Schematically drawn projection of crystal structures of a) dadsonite [ b – c plane], b) iodine-substituted pillaite [ a – c plane]; HRTEM lattices images of a fiber cross-section of: c) dadsonite with B || [100]; the black solid lines mark the chain-like structure fragments; d) iodine
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Reflectance curves of <span class="search-highlight">pillaite</span> in air and oil.
Published: 01 May 2001
Fig. 2. Reflectance curves of pillaite in air and oil.
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Crystal and experimental data, and structure refinement for <span class="search-highlight">pillaite</span>.
Published: 01 July 2001
Table 1. Crystal and experimental data, and structure refinement for pillaite.
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Scanning electron microscope image of <span class="search-highlight">pillaite</span> fibers.
Published: 01 May 2001
Fig. 1. Scanning electron microscope image of pillaite fibers.
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X-ray powder diffraction pattern of <span class="search-highlight">pillaite</span>.
Published: 01 May 2001
Table 3. X-ray powder diffraction pattern of pillaite.
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Trigonal prismatic coordination of the chlorine atom with lead in the pilla...
Published: 01 July 2001
Fig. 2. Trigonal prismatic coordination of the chlorine atom with lead in the pillaite structure.
Journal Article
Published: 01 September 2004
European Journal of Mineralogy (2004) 16 (5): 839–844.
...Paolo ORLANDI; Yves MOËLO; Alain MEERSCHAUT; Pierre PALVADEAU; Philippe LEONE Abstract Pellouxite, the second natural oxy-chloro-sulfosalt after pillaite, has been discovered in cavities of calcite veins in the small Fe-Ba deposit of Buca della Vena mine, Apuan Alps (Tuscany, Italy). The new...
FIGURES
Journal Article
Published: 01 September 2004
European Journal of Mineralogy (2004) 16 (5): 845–855.
.... The isolated oxygen is strongly bonded to two Sb atoms, like in scainiite and pillaite. The Cl/S pair is situated in a triangular prismatic coordination (4 Pb + 2 Sb). Following the principles of modular analysis, the whole structure is described in two ways: 1 - a combination of three types of 1 D and 2D...
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Anisotropic displacement parameters (in Å 2  × 10 3 ) for cations in the c...
Published: 01 July 2001
Table 3. Anisotropic displacement parameters (in Å 2 × 10 3 ) for cations in the crystal structure of pillaite.
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Atomic coordinates (x 10 4 ) and equivalent isotropic displacement paramete...
Published: 01 July 2001
Table 2. Atomic coordinates (x 10 4 ) and equivalent isotropic displacement parameters in the crystal structure of pillaite.
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Reflectance (%) of <span class="search-highlight">pillaite</span> (sub-isotropic basal section) from 400 to 800 n...
Published: 01 May 2001
Table 1. Reflectance (%) of pillaite (sub-isotropic basal section) from 400 to 800 nm in air and oil.
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The crystal structure of <span class="search-highlight">pillaite</span> ( Meerschaut  et al.  2001 ). For convent...
Published: 01 February 2009
F ig . 5. The crystal structure of pillaite ( Meerschaut et al. 2001 ). For conventions, see Figure 2 . Rods of the walls (vertical) are terminated by “kermesite-like configurations”, and box-fill rods are completed by chlorine atoms (yellow).