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![Results of K-means Cluster Analysis of a radial aggregate of kipushite–ph...]()
![The bond lengths (Å) of T 1O 4 and T 2O 4 tetrahedra of goldhillite (FM...]()
![BSE image of pseudomalachite (Pm) and <span class="search-highlight">philipsburgite</span> (Phb) showing the dist...]()
![Data measurement and refinement information for <span class="search-highlight">philipsburgite</span> crystals fro...]()
![Chemical data (in wt.%) for <span class="search-highlight">philipsburgite</span> from the Black Pine mine (BP), K...]()
![Raman bands of holotype goldhillite and goldhillite, <span class="search-highlight">philipsburgite</span> and kip...]()
![Selected bond lengths (Å) for <span class="search-highlight">philipsburgite</span> (BP). Cu1–O h 4 ...]()
![Comparison of goldhillite, <span class="search-highlight">philipsburgite</span> and kipushite. Minera...]()
![Raman spectra of the kipushite–<span class="search-highlight">philipsburgite</span> solid solution (samples M2, M...]()
![Summary plot of Cu vs . Zn (a) and P vs . As ( apfu ) in the kipushite–ph...]()
![Plots of correlation between: (a) Raman band positions of arsenate and posp...]()
![The dependences of unit cell parameters of kipushite (KP) from Kipushi mine...]()
![(a) Thin section of a secondary mineral assemblage (Fe-hydroxides, chrysoco...]()
![Examples of samples from Miedzianka investigated in this study: (a) a crust...]()
![(a) Scanning electron microscope (SEM) image of a cellular silica-rich crus...]()
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philipsburgite
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Journal Article
Goldhillite, Cu 5 Zn(AsO 4 ) 2 (OH) 6 ⋅H 2 O, a new mineral species, and redefinition of philipsburgite, Cu 5 Zn[(AsO 4 )(PO 4 )](OH) 6 ⋅H 2 O, as an As–P ordered species
Journal: Mineralogical Magazine
Published: 13 May 2022
Mineralogical Magazine (2022) 86 (3): 436–446.
.... Nash; Paul M. Adams Abstract Philipsburgite has been redefined as the intermediate member of the goldhillite–philipsburgite–kipushite isomorphous series with the ideal formula Cu 5 Zn[(AsO 4 )(PO 4 )](OH) 6 ⋅H 2 O due to the site-selective As–P substitution. The new mineral goldhillite, ideally Cu 5 Zn...
FIGURES
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Journal Article
Pseudomalachite–cornwallite and kipushite–philipsburgite solid solutions: chemical composition and Raman spectroscopy
Journal: European Journal of Mineralogy
Publisher: GeoScienceWorld Journals
Published: 01 June 2016
European Journal of Mineralogy (2016) 28 (3): 555–569.
... arsenate analogue philipsburgite was investigated by electron-probe microanalysis, scanning electron microscopy, powder X-ray diffraction and micro-Raman spectroscopy. A wide range of compositions was found, covering 77.5 mol% and 75 mol% of the cornwallite–pseudomalachite and kipushite–philipsburgite...
FIGURES
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Journal Article
Philipsburgite, a new copper zinc arsenate hydrate related to kipushite, from Montana
Journal: The Canadian Mineralogist
Publisher: Mineralogical Association of Canada
Published: 01 May 1985
The Canadian Mineralogist (1985) 23 (2): 255–258.
Image
Results of K-means Cluster Analysis of a radial aggregate of kipushite–ph...
in Pseudomalachite–cornwallite and kipushite–philipsburgite solid solutions: chemical composition and Raman spectroscopy
> European Journal of Mineralogy
Published: 01 June 2016
Fig. 9 Results of K-means Cluster Analysis of a radial aggregate of kipushite–philipsburgite from Miedzianka. Cluster tree with the root cluster and the first level of the cluster determine a solid-solution between philipsburgite and kipushite. The root cluster on the left and on the right
Image
The bond lengths (Å) of T 1O 4 and T 2O 4 tetrahedra of goldhillite (FM...
in Goldhillite, Cu 5 Zn(AsO 4 ) 2 (OH) 6 ⋅H 2 O, a new mineral species, and redefinition of philipsburgite, Cu 5 Zn[(AsO 4 )(PO 4 )](OH) 6 ⋅H 2 O, as an As–P ordered species
> Mineralogical Magazine
Published: 13 May 2022
Fig. 7. The bond lengths (Å) of T 1O 4 and T 2O 4 tetrahedra of goldhillite (FMM) and philipsburgite (BP). Average values for goldhillite are < T 1–O> ≈ 1.605 Å, < T 2–O> ≈ 1.6875 Å; and for philipsburgite are < T 1–O> ≈ 1.5425 Å and < T 2–O> ≈ 1.685 Å.
Image
BSE image of pseudomalachite (Pm) and philipsburgite (Phb) showing the dist...
in Pseudomalachite–cornwallite and kipushite–philipsburgite solid solutions: chemical composition and Raman spectroscopy
> European Journal of Mineralogy
Published: 01 June 2016
Fig. 4 BSE image of pseudomalachite (Pm) and philipsburgite (Phb) showing the distribution of P, As, Cu, and Zn expressed by their ratios across zoned pseudomalachite and radial aggregates of philipsburgite. The path of electron microprobe analyses is shown by a line of light dots. Numbers refer
Journal Article
New Mineral Names
Journal: American Mineralogist
Publisher: Mineralogical Society of America
Published: 03 October 2022
American Mineralogist (2022) 107 (10): 1982–1984.
... mine, Tooele County, Utah. It was found in the Fersman Mineralogical Museum collection as a sample labeled as philipsburgite. There are currently more than 150 known copper arsenate and copper phosphate minerals combined, but there are only three that are copper arsenate-phosphate minerals...
Image
Data measurement and refinement information for philipsburgite crystals fro...
in Goldhillite, Cu 5 Zn(AsO 4 ) 2 (OH) 6 ⋅H 2 O, a new mineral species, and redefinition of philipsburgite, Cu 5 Zn[(AsO 4 )(PO 4 )](OH) 6 ⋅H 2 O, as an As–P ordered species
> Mineralogical Magazine
Published: 13 May 2022
Table 3. Data measurement and refinement information for philipsburgite crystals from the Black Pine mine (BP), Kamariza mines (KM) and Silver Coin mine (SC) and goldhillite crystal from Gold Hill mine (FMM). BP KM SC FMM Crystal Data T 1 site occupancy* P 0.879(6
Image
Chemical data (in wt.%) for philipsburgite from the Black Pine mine (BP), K...
in Goldhillite, Cu 5 Zn(AsO 4 ) 2 (OH) 6 ⋅H 2 O, a new mineral species, and redefinition of philipsburgite, Cu 5 Zn[(AsO 4 )(PO 4 )](OH) 6 ⋅H 2 O, as an As–P ordered species
> Mineralogical Magazine
Published: 13 May 2022
Table 2. Chemical data (in wt.%) for philipsburgite from the Black Pine mine (BP), Kamariza mines (KM) and Silver Coin mine (SC), and goldhillite from the Gold Hill mine (FMM) and Los Angeles Museum (NHMLA). Constituent BP* KM (10 points on 3 crystals) SC (19 points on 6
Image
Raman bands of holotype goldhillite and goldhillite, philipsburgite and kip...
in Goldhillite, Cu 5 Zn(AsO 4 ) 2 (OH) 6 ⋅H 2 O, a new mineral species, and redefinition of philipsburgite, Cu 5 Zn[(AsO 4 )(PO 4 )](OH) 6 ⋅H 2 O, as an As–P ordered species
> Mineralogical Magazine
Published: 13 May 2022
Table 1. Raman bands of holotype goldhillite and goldhillite, philipsburgite and kipushite by Ciesielczuk et al. ( 2016 ). Range (cm –1 ) This study Ciesielczuk et al. ( 2016 ) Tentative assignment Goldhillite Goldhillite Intermediate member* Kipushite As 1.63
Image
Selected bond lengths (Å) for philipsburgite (BP). Cu1–O h 4 ...
in Goldhillite, Cu 5 Zn(AsO 4 ) 2 (OH) 6 ⋅H 2 O, a new mineral species, and redefinition of philipsburgite, Cu 5 Zn[(AsO 4 )(PO 4 )](OH) 6 ⋅H 2 O, as an As–P ordered species
> Mineralogical Magazine
Published: 13 May 2022
Table 7. Selected bond lengths (Å) for philipsburgite (BP). Cu1–O h 4 1.969(5) Cu2–O h 8 1.992(5) Cu3–O h 10 1.928(5) Cu1–O6 1.968(5) Cu2–O h 1 2.000(5) Cu3–O h 1 1.985(5) Cu1–O h 1 1.973(4) Cu2–O h 4 2.014(5) Cu3–O h 9 2.006(5) Cu1–O h 3 2.028(5) Cu2–O7
Image
Comparison of goldhillite, philipsburgite and kipushite. Minera...
in Goldhillite, Cu 5 Zn(AsO 4 ) 2 (OH) 6 ⋅H 2 O, a new mineral species, and redefinition of philipsburgite, Cu 5 Zn[(AsO 4 )(PO 4 )](OH) 6 ⋅H 2 O, as an As–P ordered species
> Mineralogical Magazine
Published: 13 May 2022
Table 8. Comparison of goldhillite, philipsburgite and kipushite. Mineral Goldhillite Philipsburgite Kipushite Crystal chemical formula Cu 5 Zn(AsO 4 ) 2 (OH) 6 ⋅H 2 O Cu 5 Zn(AsO 4 )(PO 4 )(OH) 6 ⋅H 2 O Cu 5 Zn(PO 4 ) 2 (OH) 6 ⋅H 2 O Symmetry Monoclinic Monoclinic
Image
Raman spectra of the kipushite–philipsburgite solid solution (samples M2, M...
in Pseudomalachite–cornwallite and kipushite–philipsburgite solid solutions: chemical composition and Raman spectroscopy
> European Journal of Mineralogy
Published: 01 June 2016
Fig. 8 Raman spectra of the kipushite–philipsburgite solid solution (samples M2, M7, M8). The hydroxyl region in all spectra was enlarged to better visualize components of the bands. (online version in colour)
Image
Summary plot of Cu vs . Zn (a) and P vs . As ( apfu ) in the kipushite–ph...
in Pseudomalachite–cornwallite and kipushite–philipsburgite solid solutions: chemical composition and Raman spectroscopy
> European Journal of Mineralogy
Published: 01 June 2016
Fig. 6 Summary plot of Cu vs . Zn (a) and P vs . As ( apfu ) in the kipushite–philipsburgite solid solution. Symbols refer to four samples from Miedzianka (266 data points) supplemented by published data. (online version in colour)
Image
Plots of correlation between: (a) Raman band positions of arsenate and posp...
in Pseudomalachite–cornwallite and kipushite–philipsburgite solid solutions: chemical composition and Raman spectroscopy
> European Journal of Mineralogy
Published: 01 June 2016
Fig. 10 Plots of correlation between: (a) Raman band positions of arsenate and posphate ions in spectra of the kipushite–philipsburgite solid solution; (b) FWHM of υ 1 (PO 4 ) 3− bands and position of those bands; (c) FWHM of υ 1 (AsO 4 ) 3− bands and position of those bands.
Image
The dependences of unit cell parameters of kipushite (KP) from Kipushi mine...
in Goldhillite, Cu 5 Zn(AsO 4 ) 2 (OH) 6 ⋅H 2 O, a new mineral species, and redefinition of philipsburgite, Cu 5 Zn[(AsO 4 )(PO 4 )](OH) 6 ⋅H 2 O, as an As–P ordered species
> Mineralogical Magazine
Published: 13 May 2022
Fig. 6. The dependences of unit cell parameters of kipushite (KP) from Kipushi mine, Zaire (Piret et al. , 1985 ), philipsburgite (BP, SC, KM) and goldhillite (FMM, NHMLA, YM), where YM = the sample of goldhillite from Yamato mine, Yamaguchi Prefecture, Japan (Shirose and Uehara, 2011
Image
(a) Thin section of a secondary mineral assemblage (Fe-hydroxides, chrysoco...
in Pseudomalachite–cornwallite and kipushite–philipsburgite solid solutions: chemical composition and Raman spectroscopy
> European Journal of Mineralogy
Published: 01 June 2016
Fig. 7 (a) Thin section of a secondary mineral assemblage (Fe-hydroxides, chrysocolla, pseudomalachite, kipushite–philipsburgite) developed in a quartz-lined cavity within quartz vein in amphibolite. Symbols as in Fig. 1 . BSE image of the boxed area is shown in b. X-ray element distribution
Image
Examples of samples from Miedzianka investigated in this study: (a) a crust...
in Pseudomalachite–cornwallite and kipushite–philipsburgite solid solutions: chemical composition and Raman spectroscopy
> European Journal of Mineralogy
Published: 01 June 2016
Fig. 1 Examples of samples from Miedzianka investigated in this study: (a) a crust of chrysocolla (Ccl) overgrown by pseudomalachite (Pm) and malachite (Mal) in sample M1; (b) radial aggregates of kipushite–philipsburgite (Phb) crystals with pronounced banding, sample M2; (c) highly weathered
Image
(a) Scanning electron microscope (SEM) image of a cellular silica-rich crus...
in Pseudomalachite–cornwallite and kipushite–philipsburgite solid solutions: chemical composition and Raman spectroscopy
> European Journal of Mineralogy
Published: 01 June 2016
Fig. 2 (a) Scanning electron microscope (SEM) image of a cellular silica-rich crust overgrown by pseudomalachite (Pm) and malachite (Mal), sample M5; (b) BSE image of a cross section through botryoidal pseudomalachite (Pm) overgrown by radial aggregates of kipushite–philipsburgite (Phb), sample
Journal Article
Preface: The 8 th European Conference on Mineralogy and Spectroscopy
Journal: European Journal of Mineralogy
Publisher: GeoScienceWorld Journals
Published: 01 June 2016
European Journal of Mineralogy (2016) 28 (3): 511.
... in the pseudomalachite–cornwallite and kipushite–philipsburgite phosphate–arsenate solid solutions. Tempesta et al. present micro-destructive and standardless chemical analyses of red beryls by means of Laser Induced Breakdown Spectroscopy and reveal different mineral species, while the studies by Ertl et al...
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