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nanocrystals

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Journal Article
Published: 01 May 2013
American Mineralogist (2013) 98 (5-6): 977–985.
...Liberto De Pablo Galan; Mercedes Doval; Angel La Iglesia; Jesus Soriano; Lourdes Chavez Abstract Cristobalite-tridymite blade nanocrystals cemented by SiO 2 -glass and tridymite nanocrystals fill separately SiO 2 -glass spherules released by explosive volcanism, in rhyolitic tuffs from the Province...
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Journal Article
Published: 01 April 2013
American Mineralogist (2013) 98 (4): 582–587.
... and the formation of new continental crust between 2.51 to 2.45 Ga. Here we report unique mineral evidence for momentary subaerial volcanism recorded in hematite-rich layers of the 2.48 Ga BIF from Dales Gorge, Hamersley of Western Australia. The BIF contains euhedral quartz nanocrystals (QNC), which only occur...
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Journal Article
Published: 01 February 2013
American Mineralogist (2013) 98 (2-3): 518–521.
... of the nanocrystals and SAED patterns simulated using the structure of vorlanite ( Figs. 3a , 3b , and 3c ). Figure 3d shows the cubic oxygen coordination of U 6+ in this mineral. All vorlanite nanocrystals observed correspond to euhedral cubes, 20 to 150 nm large ( Fig. 2a and inset in Fig. 3a ). After...
FIGURES
Journal Article
Published: 01 January 2013
American Mineralogist (2013) 98 (1): 154–162.
...Takuya Echigo; Niven Monsegue; Deborah M. Aruguete; Mitsuhiro Murayama; Michael F. Hochella, Jr. Abstract We report the first characterization of the internal structural features within rhombohedral nanocrystals of hematite (α-Fe 2 O 3 ), specifically nanoscale pores (nanopores) within...
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Journal Article
Published: 01 October 2009
American Mineralogist (2009) 94 (10): 1428–1439.
...}\ {-}\ \mathit{C}_{\mathit{A}})\ \frac{k_{B}\mathit{T}}{\mathit{h}}\ exp\left(\frac{{-}{\Delta}\mathit{g}_{\mathit{D}}^{0}}{k_{B}\mathit{T}}\right)\] \end{document} where Δ g D 0 is the standard free energy of activation of a diffusion step. As our model is meant to be applied to nanocrystals, we...
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Journal Article
Journal: Elements
Published: 01 August 2009
Elements (2009) 5 (4): 235–240.
...Mihály Pósfai; Rafal E. Dunin-Borkowski Abstract Ferrimagnetic nanocrystals are present in virtually every organism. they are used by bacteria, algae, mollusks, insects, and vertebrates either for navigating in the geomagnetic field or for hardening their tissues. advanced transmission electron...
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Journal Article
Published: 01 April 2009
American Mineralogist (2009) 94 (4): 578–593.
... of up to four sets of oriented rod-shaped CaO nanocrystals on each rhombohedral cleavage face of the calcite pseudomorph. The four sets formed on (101̅4) calcite display the following topotactic relationships: (1) (12̅10) calcite //(110) CaO ; (2) (1̅104) calcite ⊥ (110) CaO ; (3) (1̅018) calcite //(110...
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Journal Article
Published: 01 May 2007
European Journal of Mineralogy (2007) 19 (3): 345–351.
...Erica Bittarello; Dino Aquilano Abstract “Silica Biomorphs” are self-assembled nanocrystals of barium carbonate that form in silica-rich environments. Their morphologies are highly reminiscent of the shapes of primitive life (discovered in Archean cherts), but the precipitates are clearly inorganic...
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Journal Article
Published: 01 November 2006
European Journal of Mineralogy (2006) 18 (6): 845–853.
.... Chemical analyses show dominant Fe 2 O 3 (53.5–71.5 wt.%), with minor SiO 2 (3.0–24.7 wt.%) and Al 2 O 3 (0.8–7.1 wt.%). A very high arsenic content characterizes all the samples (with a mean of 5.6 wt.% As 2 O 5 ). Goethite and hematite occur as finely dispersed nanocrystals, respectively 2–10 nm and 10...
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Journal Article
Published: 01 August 2006
American Mineralogist (2006) 91 (8-9): 1216–1229.
..., as well as on the contribution of biogenic greigite to the paleomagnetic signal in sedimentary deposits. Off-axis electron holography is a transmission electron microscopy (TEM) technique that can be used to study the magnetic microstructures of nanocrystals ( Dunin-Borkowski et al. 2004 ). The method...
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Journal Article
Published: 01 January 2001
Reviews in Mineralogy and Geochemistry (2001) 44 (1): 59–72.
... of the kinetics, which depends strongly on the preparation of the sample and its history. The study of first-order phase transitions can be greatly simplified in nanocrystal systems because small crystals can behave as single structural domains and reproducibly cycle through multiple transitions ( Wickham et al...
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Journal Article
Published: 01 November 2001
European Journal of Mineralogy (2001) 13 (6): 1235–1242.
... sizes of single crystallites in the 1 — 50 nm range and agglomerate grain sizes up to 4 μm. The three-dimensional agglomerates are built with different biomineral nanocrystals in three distinct modes of biological self-assembly: 1) ordered magnetite; 2) semi-ordered mixture of magnetite and ϵFe 2 O 3...
FIGURES
Image
High-resolution images of fine covellite nanocrystals and nanorods, focusing on defects within the crystal structure as outlined in yellow. Boundaries of the fine nanocrystals are outlined in black to assist visualization. (a) Twinning and (b–c) stacking faults can be observed within <10 nm nanocrystals across the (100)/(101) or (102) planes. (d–e) Stacking faults and kinks can be observed within nanorods. The morphological variety of fine covellite nanocrystals with different planes exposed are also evident. (Color online.)
Published: 01 May 2019
Figure 7. High-resolution images of fine covellite nanocrystals and nanorods, focusing on defects within the crystal structure as outlined in yellow. Boundaries of the fine nanocrystals are outlined in black to assist visualization. ( a ) Twinning and ( b–c ) stacking faults can be observed
Image
SEM photomicrographs of Prismatic Type I crystals from locality LY-2e. A) Cluster of crystals with strands of EPS on surfaces. White letter B indicates position of Part B. B) Cross-sectional shapes of upper parts of crystals in central part of cluster shown in Part A. White letter C indicates position of Part C. C) General view of crystal formed of perfectly aligned nanocrystals. D–F) Enlarged views of perfectly aligned nanocrystals from crystal shown in Part C. Note that some nanocrystals are perfectly formed with smooth faces whereas others are incompletely formed (arrows on Part D). G) Group of crystals from another cluster (like that shown in Part A) showing mesocrystals formed of aligned nanocrystals. White letter H indicates position of Part H. H) Surface of crystals showing perfectly aligned rhombic nanocrystals. White letter I indicates position of Part I. I) Example of nanocrystal formed of even smaller crystals that are of various sizes (arrows).
Published: 07 November 2017
indicates position of Part C. C) General view of crystal formed of perfectly aligned nanocrystals. D – F) Enlarged views of perfectly aligned nanocrystals from crystal shown in Part C. Note that some nanocrystals are perfectly formed with smooth faces whereas others are incompletely formed (arrows
Image
An open-framework allotrope of silicon Si24 from foil no. 5312. (a) Mosaic grain composed of nanocrystals of Si24. Bright-field image. (b) HAADF image of the mosaic crystal of Si24 showing the individual nanocrystals. The inset image in the upper-right corner displays a higher magnification. Some of the nanocrystals show nano-twin lamellae. (c) High-resolution lattice fringe image of an individual nanocrystal of Si24 from the mosaic crystal. The indexed diffraction pattern is inserted in the upper right corner. (d) TEM dark-field image using the (141) reflection in the diffraction pattern. The brighter patches in the mosaic crystal are individual nanocrystals of Si24 with a perfect zone axis orientation with respect to the electron beam. The alternating bright and dark contrasts at the crystal interfaces are thickness fringes due to an inclined interface.
Published: 01 January 2019
Figure 7. An open-framework allotrope of silicon Si 24 from foil no. 5312. ( a ) Mosaic grain composed of nanocrystals of Si 24 . Bright-field image. ( b ) HAADF image of the mosaic crystal of Si 24 showing the individual nanocrystals. The inset image in the upper-right corner displays a higher
Image
Schematic showing a hysteresis loop for the CdSe nanocrystals with the smearing of the thermodynamic transition pressure caused by the finite nature of the nanocrystal particle. The thermodynamic transition pressure is offset from the hysteresis center to emphasize that in first-order solid-solid transformations, this pressure is unlikely to be precisely centered. The lower plot shows the estimated smearing for CdSe nanocrystals as inversely proportional to the number of atoms in the crystal, at two temperatures, as discussed in the text. Note that nanocrystals are not ordinarily synthesized or studied in sizes smaller than 20 Å in diameter. This figure shows that this thermal smearing is insignificant compared to the large hysteresis width in the CdSe nanocrystals studied (25–130 Å in diameter), such that the transition is bulk-like from this perspective. This means that observed transformations occur at pressures far from equilibrium, where there is little probability of back reaction to the metastable state once a nanocrystal has transformed. In much smaller crystals or with larger temperatures, the smearing could become on the order of the hysteresis width, and the crystals would transform from one structure to the other at thermal equilibrium.
Published: 01 January 2001
Figure 4. Schematic showing a hysteresis loop for the CdSe nanocrystals with the smearing of the thermodynamic transition pressure caused by the finite nature of the nanocrystal particle. The thermodynamic transition pressure is offset from the hysteresis center to emphasize that in first-order
Image
Ru-Rh-Ir-sulfide nanocrystals in pyrrhotite. (A) TEM bright-field image of inhomogeneously distributed nanometer-sized idiomorphic crystals of Ru-Rh-Ir-sulfide in polycrystalline pyrrhotite (white arrows). The dark line contrasts in pyrrhotite are diffraction contrasts that are interrupted or bent at grain boundaries. (B) High-resolution TEM (HREM) lattice fringe image of an individual Ru-Rh- sulfide nanocrystal in a pyrrhotite matrix. (C) Convergent beam electron diffraction pattern from an individual nanocrystal. The diffraction discs could be indexed as Ru-Rh-Ir-sulfide nanocrystals.
Published: 01 February 2013
Fig. 2 Ru-Rh-Ir-sulfide nanocrystals in pyrrhotite. (A) TEM bright-field image of inhomogeneously distributed nanometer-sized idiomorphic crystals of Ru-Rh-Ir-sulfide in polycrystalline pyrrhotite (white arrows). The dark line contrasts in pyrrhotite are diffraction contrasts that are interrupted
Image
Ru-Rh-Ir-sulfide nanocrystals in pyrrhotite. (A) TEM bright-field image of inhomogeneously distributed nanometer-sized idiomorphic crystals of Ru-Rh-Ir-sulfide in polycrystalline pyrrhotite (white arrows). The dark line contrasts in pyrrhotite are diffraction contrasts that are interrupted or bent at grain boundaries. (B) High-resolution TEM (HREM) lattice fringe image of an individual Ru-Rh- sulfide nanocrystal in a pyrrhotite matrix. (C) Convergent beam electron diffraction pattern from an individual nanocrystal. The diffraction discs could be indexed as Ru-Rh-Ir-sulfide nanocrystals.
Published: 01 February 2013
Fig. 2 Ru-Rh-Ir-sulfide nanocrystals in pyrrhotite. (A) TEM bright-field image of inhomogeneously distributed nanometer-sized idiomorphic crystals of Ru-Rh-Ir-sulfide in polycrystalline pyrrhotite (white arrows). The dark line contrasts in pyrrhotite are diffraction contrasts that are interrupted
Image
Ru-Rh-Ir-sulfide nanocrystals in pyrrhotite. (A) TEM bright-field image of inhomogeneously distributed nanometer-sized idiomorphic crystals of Ru-Rh-Ir-sulfide in polycrystalline pyrrhotite (white arrows). The dark line contrasts in pyrrhotite are diffraction contrasts that are interrupted or bent at grain boundaries. (B) High-resolution TEM (HREM) lattice fringe image of an individual Ru-Rh- sulfide nanocrystal in a pyrrhotite matrix. (C) Convergent beam electron diffraction pattern from an individual nanocrystal. The diffraction discs could be indexed as Ru-Rh-Ir-sulfide nanocrystals.
Published: 01 February 2013
Fig. 2 Ru-Rh-Ir-sulfide nanocrystals in pyrrhotite. (A) TEM bright-field image of inhomogeneously distributed nanometer-sized idiomorphic crystals of Ru-Rh-Ir-sulfide in polycrystalline pyrrhotite (white arrows). The dark line contrasts in pyrrhotite are diffraction contrasts that are interrupted
Image
Photomicrographs of rhombic Type III calcite mesocrystals from Stjáni, locality c. A) General view of rhombic Type III crystal. White letters B and C indicate positions of Parts B and C, respectively. B) Surface of crystal showing constituent nanocrystals. C, D) Oblique views of nanocrystals showing wedge-shaped serrated cross-sectional morphology. Each nanocrystal appears to be formed of slightly overlapping rhombic plates. E) Surface of rhombic type III crystal. White letter F indicates position of Part F. F) Enlarged views of surface of rhombic crystal showing perfect alignment of constituent nanocrystals.
Published: 07 November 2017
Fig. 16.— Photomicrographs of rhombic Type III calcite mesocrystals from Stjáni, locality c. A) General view of rhombic Type III crystal. White letters B and C indicate positions of Parts B and C, respectively. B) Surface of crystal showing constituent nanocrystals. C , D) Oblique views