Abstract Alkaline igneous rock-related gold deposits, primarily of Mesozoic to Neogene age, are among the largest epithermal gold deposits in the world. These deposits are a subset of low-sulfidation epithermal deposits and are spatially and genetically linked to small stocks or clusters of intrusions possessing high alkali-element contents. Critical-, near-critical, or energy-critical elements associated with these deposits are F, platinum-group elements (PGEs), rare earth elements (REEs), Te, V, and W. Fluorine and tungsten have been locally recovered in the past, and some other elements could be considered as future by-products depending on trends in demand and supply. The Jamestown district in Boulder County, Colorado, historically produced F from large lenticular fluoritebearing breccia bodies and Au-Te veins in and adjacent to the Jamestown monzonite stock. Several hundred thousand metric tons (t) of fluorspar were produced. Some alkalic epithermal gold deposits contain tungstenbearing minerals, such as scheelite, ferberite, or wolframite. Small tungsten orebodies adjacent to and/or overlapping the belt of Au telluride epithermal deposits in Boulder County were mined historically, but it is unclear in all cases how the tungsten mineralization is related genetically to the Au-Te stage. Micron-sized gold within deposits in the Ortiz Mountains in New Mexico contain scheelite but no record of tungsten production from these deposits exists. The most common critical element in alkaline igneous-rock related gold deposits is tellurium, which is enriched (>0.5%) in many deposits and could be considered a future commodity as global demand increases and if developments are made in the processing of Au-Te ores. It occurs as precious metal telluride minerals, although native Te and tetradymite (Bi2Te2S) have been reported in a few localities. Assuming that the Dashigou and adjacent Majiagou deposits in Sichuan province, China, are correctly classified as alkalic-related epithermal gold deposits (exact origin remains unclear), they represent the only primary producers of Te (as tetradymite) from this deposit type. It is worth noting that some epithermal veins (and spatially or genetically related porphyry deposits) contain high contents of Pt or Pd, or both. The Mount Milligan deposit typically contains >100 ppb Pd, and some values exceed 1,000 ppb. However, owing to the presence of other large known PGE resources in deposits in which PGEs are the primary commodities, it is unlikely that alkaline-related epithermal gold deposits will become a major source of PGEs. Similarly, many epithermal gold deposits related to alkaline rocks have high vanadium contents, but are unlikely to be considered vanadium resources in the future. Roscoelite (V-rich mica) is a characteristic mineral of alkalic-related epithermal deposits and is particularly abundant in deposits in Fiji where it occurs with other V-rich minerals, such as karelianite, Ti-free nolanite, vanadium rutile, schreyerite, and an unnamed vanadium silicate. A few alkaline intrusive complexes that contain anomalous concentrations of gold or were prospected for gold in the past are also host to REE occurrences.The best examples are the Bear Lodge Mountains in Wyoming and Cu-REE-F (±Ag, Au) vein deposits in the Gallinas Mountains in New Mexico, which have REE contents ranging up to 5.6% in addition to anomalous Au.

Abstract Carlin, epithermal, and orogenic gold deposits, today mined almost exclusively for their gold content, have similar suites of anomalous trace elements that reflect similar low-salinity ore fluids and thermal conditions of metal transport and deposition. Many of these trace elements are commonly referred to as critical or near-critical elements or metals and have been locally recovered, although typically in small amounts, by historic mining activities. These elements include As, Bi, Hg, In, Sb, Se, Te, Tl, and W. Most of these elements are now solely recovered as by-products from the milling of large-tonnage, base metal-rich ore deposits, such as porphyry and volcanogenic massive sulfide deposits. A combination of dominance of the world market by a single country for a single commodity and a growing demand for many of the critical to near-critical elements could lead to future recovery of such elements from select epithermal, orogenic, or Carlin-type gold deposits. Antimony continues to be recovered from some orogenic gold deposits and tellurium could potentially be a primary commodity from some such deposits. Tellurium and indium in sphalerite-rich ores have been recovered in the past and could be future commodities recovered from epithermal ores. Carlin-type gold deposits in Nevada are enriched in and may be a future source for As, Hg, Sb, and/or Tl. Some of the Devonian carbonaceous host rocks in the Carlin districts are sufficiently enriched in many trace elements, including Hg, Se, and V, such that they also could become resources. Thallium may be locally enriched to economic levels in Carlin-type deposits and it has been produced from Carlin-like deposits elsewhere in the world (e.g., Alsar, southern Macedonia; Lanmuchang, Guizhou province, China). Mercury continues to be recovered from shallow-level epithermal deposits, as well as a by-product of many Carlin-type deposits where refractory ore is roasted to oxidize carbon and pyrite, and mercury is then captured in air pollution control devices.