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metaschoepite

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Journal Article
Published: 01 April 2007
American Mineralogist (2007) 92 (4): 662–669.
... oxide hydrate minerals, metaschoepite [(UO 2 ) 4 O(OH) 6 ](H 2 O) 5 , contains sheets of uranyl polyhedra with H 2 O groups located in the interlayer. Several crystals along the series from metaschoepite to Na-substituted metaschoepite (Na-MS), approximate formula Na[(UO 2 ) 4 O 2 (OH) 5 ](H 2 O) 5...
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Journal Article
Published: 01 June 1998
The Canadian Mineralogist (1998) 36 (3): 831–845.
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Geometry of the uranyl layers in schoepite, <span class="search-highlight">metaschoepite</span>, and α-UO 2 (OH) ...
Published: 01 February 2011
F igure 1. Geometry of the uranyl layers in schoepite, metaschoepite, and α-UO 2 (OH) 2 . Spheres represent uranium atoms, rods are U-O bonds. The darker spheres represent U1,U2,U5,U6 and U2,U3 in schoepite ( Finch et al. 1996 ) and metaschoepite ( Weller et al. 2000 ), respectively, while
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Scanning electron microscope (SEM) images of <span class="search-highlight">metaschoepite</span> crystals from th...
Published: 01 February 2011
F igure 3. Scanning electron microscope (SEM) images of metaschoepite crystals from the Number 2 Workings, Radium Ridge, South Australia, replaced by paulscherrerite. ( a ) Overview of the replaced orthorhombic metaschoepite crystal. ( b ) Close-up showing the porous nature of the replaced
Journal Article
Published: 01 February 2011
American Mineralogist (2011) 96 (2-3): 229–240.
...F igure 1. Geometry of the uranyl layers in schoepite, metaschoepite, and α-UO 2 (OH) 2 . Spheres represent uranium atoms, rods are U-O bonds. The darker spheres represent U1,U2,U5,U6 and U2,U3 in schoepite ( Finch et al. 1996 ) and metaschoepite ( Weller et al. 2000 ), respectively, while...
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Journal Article
Published: 01 July 2024
American Mineralogist (2024) 109 (7): 1266–1274.
... product of uraninite on asphaltite matrix in intimate association with gypsum, natrozippeite, metaschoepite, and uranopilite. Bobfinchite crystals are transparent to translucent, yellow, lozenge-shaped disks up to 0.3 mm wide. Crystals are flattened on [100] and exhibit the forms {100}, {011}, {021}, {0 2...
FIGURES | View All (8)
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Reactions among schoepite, <span class="search-highlight">metaschoepite</span>, “dehydrated schoepite” (including...
Published: 01 February 2011
F igure 8. Reactions among schoepite, metaschoepite, “dehydrated schoepite” (including paulscherrerite), and α-UO 2 (OH) 2 based on natural occurrences and experimental studies (see text). Modified from Finch et al. (1998) . Paulscherrerite at the type locality (Radium Ridge) forms via
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Summary of results for alteration of <span class="search-highlight">metaschoepite</span> to studtite. Note that 0...
Published: 01 January 2011
F igure 4. Summary of results for alteration of metaschoepite to studtite. Note that 0.1644 M H 2 O 2 is needed to convert all of the dehydrated schoepite to studtite, assuming complete reaction.
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Polyhedral representations of the structures of <span class="search-highlight">metaschoepite</span> ( A ), becque...
Published: 01 December 2006
FIGURE 1 Polyhedral representations of the structures of metaschoepite ( A ), becquerelite ( B ), uranophane ( C ), and compreignacite ( D ). Uranyl polyhedra are yellow, Ca polyhedra are blue, silicate tetrahedra are purple, K atoms are shown as blue spheres, and O atoms of selected H 2 O
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Infrared spectra of paulscherrerite and related phases.  Notes . The absorb...
Published: 01 February 2011
F igure 7. Infrared spectra of paulscherrerite and related phases. Notes . The absorbance peak at 1384 cm −1 in synthetic metaschoepite was not reported by Urbanec and Čejka (1979) , and may correspond to contamination by an unknown carbonate. KBr pressed disk; paulscherrerite 1.5 mg; UO 2
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The sheet of uranyl pentagonal bipyramids that occurs in the structures of ...
Published: 01 April 2007
F igure 3. The sheet of uranyl pentagonal bipyramids that occurs in the structures of Na-MS as well as metaschoepite, fourmarierite and schoepite.
Journal Article
Journal: Elements
Published: 01 December 2006
Elements (2006) 2 (6): 351–356.
...FIGURE 1 Polyhedral representations of the structures of metaschoepite ( A ), becquerelite ( B ), uranophane ( C ), and compreignacite ( D ). Uranyl polyhedra are yellow, Ca polyhedra are blue, silicate tetrahedra are purple, K atoms are shown as blue spheres, and O atoms of selected H 2 O...
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Journal Article
Published: 01 January 2018
American Mineralogist (2018) 103 (1): 143–150.
... of several of these minerals are built from the same sheet topology found in schoepite ( Finch et al. 1996b ), and the so-named schoepite family includes schoepite, metaschoepite, [(UO 2 ) 4 O(OH) 6 ]·5H 2 O ( Weller et al. 2000 ), fourmarierite, Pb[(UO 2 ) 4 O 3 (OH) 4 ]·4H 2 O ( Li and Burns 2000...
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Journal Article
Published: 01 April 2006
American Mineralogist (2006) 91 (4): 658–666.
...Karrie-Ann Kubatko; Katheryn Helean; Alexandra Navrotsky; Peter C. Burns Abstract The enthalpies of formation of seven uranyl oxide hydrate phases and one uranate have been determined using high-temperature oxide melt solution calorimetry: [(UO 2 ) 4 O(OH) 6 ](H 2 O) 5 , metaschoepite; β-UO 2 (OH...
FIGURES
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The sheet anion-topology that corresponds to the sheets in Na-MS-CRY, metas...
Published: 01 April 2007
F igure 4. The sheet anion-topology that corresponds to the sheets in Na-MS-CRY, metaschoepite, and fourmarierite with the locations of OH groups indicated by circles. Vertices in the anion topology that do not contain OH correspond to O atoms.
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Laser-ablation ICP-MS data for  237 Np from a crystal of Na-substituted met...
Published: 01 December 2006
FIGURE 4 Laser-ablation ICP-MS data for 237 Np from a crystal of Na-substituted metaschoepite synthesized from a solution containing approximately 500 ppm Np 5+ . The crystal analyzed is shown as an inset, where the ablation track is apparent.
Journal Article
Published: 01 February 2004
American Mineralogist (2004) 89 (2-3): 339–347.
... honors geologist and conservationist Reginald Claude Sprigg (1919–1994), founder of the Arkaroola Tourist Station. Together with beta-uranophane, soddyite, kasolite, Ce-rich francoisite-(Nd), metatorbernite, billietite, Ba-bearing boltwoodite, schoepite, metaschoepite, and weeksite, spriggite results...
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Laser-ablation ICP-MS data for Np-237 from a crystal of Na-substituted meta...
Published: 01 April 2007
F igure 2. Laser-ablation ICP-MS data for Np-237 from a crystal of Na-substituted metaschoepite synthesized from a solution containing approximately 500 ppm Np 5+ . The crystal analyzed is shown as an inset, where the ablation track is apparent. From Burns and Klingensmith (2006) .
Journal Article
Published: 01 January 2011
American Mineralogist (2011) 96 (1): 202–206.
...F igure 4. Summary of results for alteration of metaschoepite to studtite. Note that 0.1644 M H 2 O 2 is needed to convert all of the dehydrated schoepite to studtite, assuming complete reaction. ...
FIGURES | View All (4)
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A comparative view of the anion sheet topologies, (OH) –  distributions, an...
Published: 01 January 2018
to that of the synthetic Na-analog of metaschoepite. Potassium (blue), lead (orange), and sodium (yellow). (Color online.)