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kosnarite

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Journal Article
Published: 24 November 2020
The Canadian Mineralogist (2020) 58 (5): 637–652.
...Paula C. Piilonen; Henrik Friis; Ralph Rowe; Glenn Poirier ABSTRACT The crystal structure of a natural kosnarite, KZr 2 (PO 4 ) 3 from the Mario Pinto Mine, Jenipapo district, Brazil, has been determined for the first time. Kosnarite and its related synthetic compounds (NZP) are open-framework...
FIGURES | View All (5)
Journal Article
Published: 01 December 1994
Mineralogical Magazine (1994) 58 (4): 635–639.
Journal Article
Published: 01 June 1993
American Mineralogist (1993) 78 (5-6): 653–656.
...Michael E. Brownfield; Eugene E. Foord; Stephen J. Sutley; Theodore Botinelly Abstract Kosnarite, ideally KZr 2 (PO 4 ) 3 , has been identified as part of a late-stage, secondary phosphate mineral assemblage from the Mount Mica pegmatite at Paris, and from the Black Mountain pegmatite, Rumford...
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The crystal structures of metavariscite, variscite and kosnarite: (a) metavariscite projected onto (001); (b) metavariscite projected onto (100); (c) variscite projected onto (001); (d) variscite projected onto (100); (Alϕ6) octahedra are 44-net-shaded; (e) kosnarite projected onto (001); (f) kosnarite projected onto (010); (Zrϕ6) octahedra are square-pattern-shaded.
Published: 01 January 2002
Figure 35. The crystal structures of metavariscite, variscite and kosnarite: (a) metavariscite projected onto (001); (b) metavariscite projected onto (100); (c) variscite projected onto (001); (d) variscite projected onto (100); (Alϕ 6 ) octahedra are 4 4 -net-shaded; (e) kosnarite projected
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(A) The crystal structure of kosnarite viewed down c. Red: PO4 tetrahedra, Blue: ZrO6 octahedra, Purple: K (M′) site. (B) The local environment around the M′ site in kosnarite.
Published: 24 November 2020
Fig. 3. (A) The crystal structure of kosnarite viewed down c . Red: PO 4 tetrahedra, Blue: ZrO 6 octahedra, Purple: K ( M ′) site. (B) The local environment around the M ′ site in kosnarite.
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Published: 24 November 2020
TABLE 1. ELECTRON MICROPROBE COMPOSITIONS OF KOSNARITE
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Published: 24 November 2020
TABLE 3. EXPERIMENTAL AND CRYSTAL STRUCTURE DATA FOR KOSNARITE
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Published: 24 November 2020
TABLE 2. COMPARATIVE POWDER X-RAY DIFFRACTION DATA FOR KOSNARITE
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Published: 24 November 2020
TABLE 5. SELECT BOND LENGTHS (Å) AND DISTORTION PARAMETERS FOR KOSNARITE AND RELATED SYNTHETICS
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Yellowish-beige psueodocubic kosnarite from the Mario Pinto Mine, Jenipapo, Brazil (3 × 5 cm). Photo by M. Bainbridge.
Published: 24 November 2020
Fig. 1. Yellowish-beige psueodocubic kosnarite from the Mario Pinto Mine, Jenipapo, Brazil (3 × 5 cm). Photo by M. Bainbridge.
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Back-scattered (top) and cathodoluminescence (middle) images of kosnarite showing oscillatory zoning. Electron microprobe analyses from rim to core (bottom) show increasing Na, Hf, and Si in the cores of both crystals.
Published: 24 November 2020
Fig. 2. Back-scattered (top) and cathodoluminescence (middle) images of kosnarite showing oscillatory zoning. Electron microprobe analyses from rim to core (bottom) show increasing Na, Hf, and Si in the cores of both crystals.
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Unit cell parameters, a versus c (Å), for kosnarite and other NZP. With increasing ionic radius of the M-site cation, there is a negative correlation between the lengths of the a and c axes. With increasing ionic radius of the L-site cation, there is a deviation from the main trend with increases in both the a and c parameters.
Published: 24 November 2020
Fig. 4. Unit cell parameters, a versus c (Å), for kosnarite and other NZP. With increasing ionic radius of the M -site cation, there is a negative correlation between the lengths of the a and c axes. With increasing ionic radius of the L -site cation, there is a deviation from the main
Journal Article
Published: 08 April 2021
The Canadian Mineralogist (2020) 58 (6): 867–869.
... kosnarite, 643, phosphohedyphane, 356 aphthitalite-like structures, 168, Be calculation in helvine-group minerals, 376, carbonate-bearing phosphohedyphane, 359, chemical analysis from crystal structure, 19, 126, 140, 668, 816, decavanadate polyanion, 125, eudialyte group nomenclature, 422...
Journal Article
Published: 01 November 2003
European Journal of Mineralogy (2003) 15 (6): 1029–1034.
... ( e.g. , kosnarite -KZr 2 (PO 4 ) 3 ; selwynite - NaK(Be,Al)Zr 2 (PO 4 ) 4 ·2H 2 O; mahlmoodite - FeZr(PO 4 ) 2 -4H 2 O; synthetic α-Zr(HPO 4 ) 2 -H 2 O, ZrKH(PO 4 ) 2 and Zr 2 (NaPO 4 ) 4 ·6H 2 O) demonstrates that a heteropolyhedral layer composed of corner-linked PO 4 tetrahedra and ZrO 6 octahedra...
FIGURES
Journal Article
Published: 01 February 1995
The Canadian Mineralogist (1995) 33 (1): 55–58.
... radiating crystals and as granular aggregates filling cavities up to 8 mm across in the quartz - orthoclase - albite - muscovite - schorl-bearing pegmatite. Accompanying minerals include two other Zr-bearing phosphates, kosnarite and the new species wycheproofite, as well as wardite, eosphorite, cyrilovite...
Journal Article
Published: 01 July 2016
The Canadian Mineralogist (2016) 54 (4): 1053–1070.
..., hydroxylherderite, cassiterite, pollucite, and kosnarite have been recovered. Approximately 50 mg of powder from sample 45b was fused to a glass bead on a platinum strip attached to the electrodes of the carbon coater in a vacuum of 1 × 10 –5 torr. The powder was flash-melted on the strip by applying...
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Journal Article
Published: 01 June 2009
Mineralogical Magazine (2009) 73 (3): 415–420.
... for the crystallization of zigrasite resulted from corrosion of zircon. It seems likely that Zr was present as aqueous coordination complexes at the last stages of pegmatite formation, as was also probably the case in Mount Mica where the pegmatite contains both zircon and the zirconium phosphate minerals kosnarite...
FIGURES
Journal Article
Published: 01 June 2010
Mineralogical Magazine (2010) 74 (3): 567–575.
... , plus Mg(1) octahedra: yellow; Mg(2) octahedra: purple; H atoms: small black circles; red lines: O–H bonds. Currently known Zr-phosphate minerals are malhmoodite: Fe 2+ Zr(PO 4 ) 2 (H 2 O) 4 , Milton et al . ( 1993 ); kosnarite: KZr 2 (PO 4 ) 2 , Brownfield et al . ( 1993 ); wycheproofite...
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Journal Article
Published: 08 April 2021
The Canadian Mineralogist (2020) 58 (6): 863–866.
... Pekov, I.V. with Shchipalkina, N.V., 167 Persson, P. with Allaz, J.M., 829 Pesquera, A. with Garate-Olave, I., 747 Pieczka, A. with Gadas, P., 785 Piilonen, P.C., Friis, H., Rowe, R., & Poirier, G., Crystal structure determination of kosnarite, KZr 2 (PO 4 ) 3 , from the Mario Pinto...
Journal Article
Published: 01 November 2017
American Mineralogist (2017) 102 (11): 2170–2179.
... is NaZr 2 (PO 4 ) 3 (NZP) ( Alamo 1993 ). The rare natural mineral kosnarite, KZr 2 (PO 4 ) 3 ( Šljukić et al. 1969 ; Brownfield et al. 1993 ), found as a late-stage hydrothermal mineral in some pegmatites, also belongs to this structural group. Related naturally occurring alkali zirconium beryllium...
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