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kirkiite

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Journal Article

First occurrence of close-to-ideal kirkiite at Vulcano (Aeolian Islands, Italy) : chemical data and single-crystal X-ray study Available to Purchase

Daniela PINTO, Tonci BALIĆ-ŽUNIĆ, Anna GARAVELLI, Carlo GARBARINO, Emil MAKOVICKY, Filippo VURRO
Published: 01 May 2006
European Journal of Mineralogy (2006) 18 (3): 393–401.
DOI: https://doi.org/10.1127/0935-1221/2006/0018-0393
...Daniela PINTO; Tonci BALIĆ-ŽUNIĆ; Anna GARAVELLI; Carlo GARBARINO; Emil MAKOVICKY; Filippo VURRO Abstract Samples of kirkiite from the high temperature fumaroles of La Fossa crater of Vulcano (Aeolian islands, Italy) were chemically and structurally investigated in this work. Associated minerals...
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View PDF for article title, First occurrence of close-to-ideal <span class="search-highlight">kirkiite</span> at Vulcano (Aeolian Islands, Italy) : chemical data and single-crystal X-ray study
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Journal Article

THE CRYSTAL STRUCTURE OF KIRKIITE, Pb 10 Bi 3 As 3 S 19 Available to Purchase

Emil Makovicky, Tonči Balić-Žunić, Ljiljana Karanović, Dejan Poleti
Published: 01 February 2006
The Canadian Mineralogist (2006) 44 (1): 177–188.
DOI: https://doi.org/10.2113/gscanmin.44.1.177
...Emil Makovicky; Tonči Balić-Žunić; Ljiljana Karanović; Dejan Poleti Abstract The crystal structure of kirkiite has been solved using single-crystal data (Mo K α X-ray diffraction, CCD area detector) to the conventional R -factor R 1 = 0.069. It crystallizes in space group P 2 1 / m...
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View PDF for article title, THE CRYSTAL STRUCTURE OF <span class="search-highlight">KIRKIITE</span>, Pb 10 Bi 3 As 3 S 19
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Journal Article

Rare sulfosalts from Vulcano, Aeolian Islands, Italy; I, Se-bearing kirkiite, Pb 10 (Bi,As) 6 (S,Se) 19 Available to Purchase

Yuri S. Borodaev, Anna Garavelli, Olga V. Kuzmina, Nadezhda N. Mozgova, Natalia I. Organova, Nikolay V. Trubkin, Filippo Vurro
Published: 01 August 1998
The Canadian Mineralogist (1998) 36 (4): 1105–1114.
View PDF for article title, Rare sulfosalts from Vulcano, Aeolian Islands, Italy; I, Se-bearing <span class="search-highlight">kirkiite</span>, Pb 10 (Bi,As) 6 (S,Se) 19
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Unit-cell parameters of close-to-ideal kirkiite and type kirkiite. Available to Purchase

Published: 01 May 2006
Table 6. Unit-cell parameters of close-to-ideal kirkiite and type kirkiite.
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Coordination parameters * for cation positions in the structure of close-t... Available to Purchase

Published: 01 May 2006
Table 5. Coordination parameters * for cation positions in the structure of close-to-ideal kirkiite and of type kirkiite.
Journal Article

RARE SULFOSALTS FROM VULCANO, AEOLIAN ISLANDS, ITALY. VI. VURROITE, Pb 20 Sn 2 (Bi,As) 22 S 54 Cl 6 , A NEW MINERAL SPECIES Available to Purchase

Anna Garavelli, Nadezhda N. Mozgova, Paolo Orlandi, Elena Bonaccorsi, Daniela Pinto, Yves MoëLo, Yuri S. Borodaev
Published: 01 April 2005
The Canadian Mineralogist (2005) 43 (2): 703–711.
DOI: https://doi.org/10.2113/gscanmin.43.2.703
... mm, généralement en aggrégats fibreux. Lui sont associés bismuthinite, lillianite, kirkiite, heyrovskýite, galène, ainsi que des chlorosulfures de Pb(Bi) moins bien caractérisés, dont certains contiennent des traces de Tl, Sn ou As. La vurroïte est gris-argent, avec un éclat métallique. En...
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View PDF for article title, RARE SULFOSALTS FROM VULCANO, AEOLIAN ISLANDS, ITALY. VI. VURROITE, Pb 20 Sn 2 (Bi,As) 22 S 54 Cl 6 , A NEW MINERAL SPECIES
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Comparison between the crystal structure of vurroite (a) and that of kirkiite (Makovicky et al. 2006) (b). Cross-hatched are the similar portions in the two crystal structures. Hatched portion in vurroite represents a restricted kirkiite-like motif.

Comparison between the crystal structure of vurroite ( a ) and that of kirk... Available to Purchase

Published: 01 May 2008
F igure 13. Comparison between the crystal structure of vurroite ( a ) and that of kirkiite ( Makovicky et al. 2006 ) ( b ). Cross-hatched are the similar portions in the two crystal structures. Hatched portion in vurroite represents a restricted kirkiite-like motif.
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Projection on the pseudoternary system Pb(S,Se,Cl)-As2(S,Se,Cl)3-(Bi,Sb)2(S,Se,Cl)3 showing chemical compositions (in mol%) of kirkiite occurrences and synthetic phases. Increment: 10 mol %. 1–2 kirkiite from Vulcano: 1 this study, average composition from twenty analyses, 2 Borodaev et al., (1998); 3 type kirkiite from Aghios Philippos (Moëlo et al., 1985); 4–5 terminal members of the compositional field of synthetic Phase A (Walia &amp; Chang, 1973); 6 ideal composition.

Projection on the pseudoternary system Pb(S,Se,Cl)-As 2 (S,Se,Cl) 3 -(Bi,Sb... Available to Purchase

Published: 01 May 2006
Fig. 2. Projection on the pseudoternary system Pb(S,Se,Cl)-As 2 (S,Se,Cl) 3 -(Bi,Sb) 2 (S,Se,Cl) 3 showing chemical compositions (in mol%) of kirkiite occurrences and synthetic phases. Increment: 10 mol %. 1–2 kirkiite from Vulcano: 1 this study, average composition from twenty analyses, 2
Journal Article

RARE SULFOSALTS FROM VULCANO, AEOLIAN ISLANDS, ITALY. VII. Cl-BEARING GALENOBISMUTITE Available to Purchase

Daniela Pinto, Tonci Balić-Žunić, Elena Bonaccorsi, Yuri S. Borodaev, Anna Garavelli, Carlo Garbarino, Emil Makovicky, Nadezhda N. Mozgova, Filippo Vurro
Published: 01 April 2006
The Canadian Mineralogist (2006) 44 (2): 443–457.
DOI: https://doi.org/10.2113/gscanmin.44.2.443
... Fossa” crater, Island of Vulcano, Italy, has been chemically and structurally investigated. The mineral is commonly associated with bismuthinite, cannizzarite, lillianite, heyrovskýite and galena, and rarely with kirkiite, vurroite and other less well characterized Pb(Bi)-sulfochlorides. Electron...
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View PDF for article title, RARE SULFOSALTS FROM VULCANO, AEOLIAN ISLANDS, ITALY. VII. Cl-BEARING GALENOBISMUTITE
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RARE SULFOSALTS FROM VULCANO, AEOLIAN ISLANDS, ITALY. III. WITTITE AND CANNIZZARITE Available to Purchase

Yuri S. Borodaev, Anna Garavelli, Carlo Garbarino, Silvana M. Grillo, Nadezhda N. Mozgova, Natalia I. Organova, Nikolay V. Trubkin, Filippo Vurro
Published: 01 February 2000
The Canadian Mineralogist (2000) 38 (1): 23–34.
DOI: https://doi.org/10.2113/gscanmin.38.1.23
... distinctes ou non. Nous avons prélevé la cannizzarite entre 1990 et 1995, associée surtout à bismuthinite et galénobismutite, avec dans quelques cas lillianite, heyrovskiite, galène sélénifère, kirkiite, et la nouvelle espèce mozgovaïte. La wittite est présente seulement dans des échantillons...
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View PDF for article title, RARE SULFOSALTS FROM VULCANO, AEOLIAN ISLANDS, ITALY. III. WITTITE AND CANNIZZARITE
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Projection in the As-Sb-Bi sub-system of various metalloid ratios within the jordanite homologous series. Homologues: N = 3, pink squares (kirkiite); N = 4, yellow triangles (jordanite and geocronite); N = 3.5, lozenges (marcobaldiite and arsenmarcobaldiite). EPMA: microprobe analysis (light blue lozenges); STR: crystal structure (dark blue lozenges), with L3: composition of the kirkiite module (= L3 layer + intermediate slab), and L4: composition of the geocronite module. Brown circles represent ideal compositions of marcobaldiite and arsenmarcobaldiite.

Projection in the As-Sb-Bi sub-system of various metalloid ratios within th... Available to Purchase

Published: 01 May 2018
Fig. 5 Projection in the As-Sb-Bi sub-system of various metalloid ratios within the jordanite homologous series. Homologues: N  = 3, pink squares (kirkiite); N  = 4, yellow triangles (jordanite and geocronite); N  = 3.5, lozenges (marcobaldiite and arsenmarcobaldiite). EPMA: microprobe
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THE STATE OF COORDINATION OF CATIONS IN KIRKIITE Available to Purchase

Published: 01 February 2006
TABLE 4. THE STATE OF COORDINATION OF CATIONS IN KIRKIITE
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THE STATE OF COORDINATION OF CATIONS IN KIRKIITE Available to Purchase

Published: 01 February 2006
TABLE 4. THE STATE OF COORDINATION OF CATIONS IN KIRKIITE
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Experimental details for close-to-ideal kirkiite. Available to Purchase

Published: 01 May 2006
Table 2. Experimental details for close-to-ideal kirkiite.
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CRYSTAL DATA AND DETAILS OF THE STRUCTURE REFINEMENT OF KIRKIITE Available to Purchase

Published: 01 February 2006
TABLE 1. CRYSTAL DATA AND DETAILS OF THE STRUCTURE REFINEMENT OF KIRKIITE
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Fractional coordinates and displacement parameters of atoms for close-to-id... Available to Purchase

Published: 01 May 2006
Table 3. Fractional coordinates and displacement parameters of atoms for close-to-ideal kirkiite.
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Selected bond distances (Å) and angles (°) for close-to-ideal kirkiite. Available to Purchase

Published: 01 May 2006
Table 4. Selected bond distances (Å) and angles (°) for close-to-ideal kirkiite.
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FRACTIONAL COORDINATES, EQUIVALENT DISPLACEMENT AND OCCUPATION PARAMETERS O... Available to Purchase

Published: 01 February 2006
TABLE 2. FRACTIONAL COORDINATES, EQUIVALENT DISPLACEMENT AND OCCUPATION PARAMETERS OF ATOMS IN KIRKIITE
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ANISOTROPIC DISPLACEMENT PARAMETERS, U ij (Å 2 ), FOR KIRKIITE Available to Purchase

Published: 01 February 2006
TABLE 3. ANISOTROPIC DISPLACEMENT PARAMETERS, U ij (Å 2 ), FOR KIRKIITE
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Kirkiite from Vulcano and from additional natural occurrences: chemical dat... Available to Purchase

Published: 01 May 2006
Table 1. Kirkiite from Vulcano and from additional natural occurrences: chemical data, Nc values and chemical formulae.