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kipushite

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Journal Article

Pseudomalachite–cornwallite and kipushite–philipsburgite solid solutions: chemical composition and Raman spectroscopy

Justyna Ciesielczuk, Janusz Janeczek, Mateusz Dulski, Tomasz Krzykawski
Published: 01 June 2016
European Journal of Mineralogy (2016) 28 (3): 555–569.
DOI: https://doi.org/10.1127/ejm/2016/0028-2536
...Justyna Ciesielczuk; Janusz Janeczek; Mateusz Dulski; Tomasz Krzykawski Abstract A suite of 60 mineral samples with compositions intermediate between pseudomalachite, Cu 5 (PO 4 ) 2 (OH) 4 , and its arsenate analogue cornwallite, and between kipushite, (Cu,Zn) 6 (PO 4 ) 2 (OH) 6 ·H 2 O, and its...
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Philipsburgite, a new copper zinc arsenate hydrate related to kipushite, from Montana

Donald R. Peacor, Peter J. Dunn, Robert A. Ramik, B. Darko Sturman, Lester G. Zeihen
Published: 01 May 1985
The Canadian Mineralogist (1985) 23 (2): 255–258.
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Occurrence and crystal structure of kipushite, a new copper-zinc phosphate from Kipushi, Zaire

Paul Piret, Michel Deliens, Jacqueline Piret-Meunier
Published: 01 February 1985
The Canadian Mineralogist (1985) 23 (1): 35–42.
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The crystal structures of phosphophyllite, veszelyite and <span class="search-highlight">kipushite</span>: (a) ph...

The crystal structures of phosphophyllite, veszelyite and kipushite: (a) ph...

Published: 01 January 2002
Figure 12. The crystal structures of phosphophyllite, veszelyite and kipushite: (a) phosphophyllite showing (PO 4 ) and (Znϕ 4 ) tetrahedra at the vertices of a 4.8 2 net; (b) phosphophyllite projected onto (010); (Znϕ 4 ) tetrahedra are shadow-shaded, (Znϕ 6 ) octahedra are 4 4 -net-shaded; (c
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Results of K-means Cluster Analysis of a radial aggregate of <span class="search-highlight">kipushite</span>–ph...

Results of K-means Cluster Analysis of a radial aggregate of kipushite–ph...

Published: 01 June 2016
Fig. 9 Results of K-means Cluster Analysis of a radial aggregate of kipushite–philipsburgite from Miedzianka. Cluster tree with the root cluster and the first level of the cluster determine a solid-solution between philipsburgite and kipushite. The root cluster on the left and on the right
Journal Article

Goldhillite, Cu 5 Zn(AsO 4 ) 2 (OH) 6 ⋅H 2 O, a new mineral species, and redefinition of philipsburgite, Cu 5 Zn[(AsO 4 )(PO 4 )](OH) 6 ⋅H 2 O, as an As–P ordered species

Rezeda M. Ismagilova, Branko Rieck, Anthony R. Kampf, Gerald Giester, Elena S. Zhitova, Christian L. Lengauer, Sergey V. Krivovichev, Andrey A. Zolotarev, Justyna Ciesielczuk, Julia A. Mikhailova, Dmitry I. Belakovsky, Vladimir N. Bocharov, Vladimir V. Shilovskikh, Natalia S. Vlasenko, Barbara P. Nash, Paul M. Adams
Published: 13 May 2022
Mineralogical Magazine (2022) 86 (3): 436–446.
DOI: https://doi.org/10.1180/mgm.2022.36
.... Nash; Paul M. Adams Abstract Philipsburgite has been redefined as the intermediate member of the goldhillite–philipsburgite–kipushite isomorphous series with the ideal formula Cu 5 Zn[(AsO 4 )(PO 4 )](OH) 6 ⋅H 2 O due to the site-selective As–P substitution. The new mineral goldhillite, ideally Cu 5 Zn...
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The dependences of unit cell parameters of <span class="search-highlight">kipushite</span> (KP) from Kipushi mine...

The dependences of unit cell parameters of kipushite (KP) from Kipushi mine...

Published: 13 May 2022
Fig. 6. The dependences of unit cell parameters of kipushite (KP) from Kipushi mine, Zaire (Piret et al. , 1985 ), philipsburgite (BP, SC, KM) and goldhillite (FMM, NHMLA, YM), where YM = the sample of goldhillite from Yamato mine, Yamaguchi Prefecture, Japan (Shirose and Uehara, 2011
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Comparison of goldhillite, philipsburgite and <span class="search-highlight">kipushite</span>. Minera...

Comparison of goldhillite, philipsburgite and kipushite. Minera...

Published: 13 May 2022
Table 8. Comparison of goldhillite, philipsburgite and kipushite. Mineral Goldhillite Philipsburgite Kipushite Crystal chemical formula Cu 5 Zn(AsO 4 ) 2 (OH) 6 ⋅H 2 O Cu 5 Zn(AsO 4 )(PO 4 )(OH) 6 ⋅H 2 O Cu 5 Zn(PO 4 ) 2 (OH) 6 ⋅H 2 O Symmetry Monoclinic Monoclinic
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Summary plot of Cu vs . Zn (a) and P vs . As ( apfu ) in the <span class="search-highlight">kipushite</span>–ph...

Summary plot of Cu vs . Zn (a) and P vs . As ( apfu ) in the kipushite–ph...

Published: 01 June 2016
Fig. 6 Summary plot of Cu vs . Zn (a) and P vs . As ( apfu ) in the kipushite–philipsburgite solid solution. Symbols refer to four samples from Miedzianka (266 data points) supplemented by published data. (online version in colour)
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Raman spectra of the <span class="search-highlight">kipushite</span>–philipsburgite solid solution (samples M2, M...

Raman spectra of the kipushite–philipsburgite solid solution (samples M2, M...

Published: 01 June 2016
Fig. 8 Raman spectra of the kipushite–philipsburgite solid solution (samples M2, M7, M8). The hydroxyl region in all spectra was enlarged to better visualize components of the bands. (online version in colour)
Journal Article

In situ dehydration behavior of veszelyite (Cu,Zn) 2 Zn(PO 4 )(OH) 3 ·2H 2 O: A single-crystal X-ray study

Rosa Micaela Danisi, Thomas Armbruster, Biljana Lazic, Predrag Vulić, Reinhard Kaindl, Radovan Dimitrijević, Volker Kahlenberg
Published: 01 July 2013
American Mineralogist (2013) 98 (7): 1261–1269.
DOI: https://doi.org/10.2138/am.2013.4465
...-membered rings. The tetrahedral sheet composed of PO 4 and ZnO 3 (OH) tetrahedra shows strong topological similarities to that of cavansite, gismondine, and kipushite. Diffraction data of a sample from Zdravo Vrelo, near Kreševo (Bosnia and Herzegovina) have been measured in steps of 25 up to 225 °C...
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Plots of correlation between: (a) Raman band positions of arsenate and posp...

Plots of correlation between: (a) Raman band positions of arsenate and posp...

Published: 01 June 2016
Fig. 10 Plots of correlation between: (a) Raman band positions of arsenate and posphate ions in spectra of the kipushite–philipsburgite solid solution; (b) FWHM of υ 1 (PO 4 ) 3− bands and position of those bands; (c) FWHM of υ 1 (AsO 4 ) 3− bands and position of those bands.
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(a) Thin section of a secondary mineral assemblage (Fe-hydroxides, chrysoco...

(a) Thin section of a secondary mineral assemblage (Fe-hydroxides, chrysoco...

Published: 01 June 2016
Fig. 7 (a) Thin section of a secondary mineral assemblage (Fe-hydroxides, chrysocolla, pseudomalachite, kipushite–philipsburgite) developed in a quartz-lined cavity within quartz vein in amphibolite. Symbols as in Fig. 1 . BSE image of the boxed area is shown in b. X-ray element distribution
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Examples of samples from Miedzianka investigated in this study: (a) a crust...

Examples of samples from Miedzianka investigated in this study: (a) a crust...

Published: 01 June 2016
Fig. 1 Examples of samples from Miedzianka investigated in this study: (a) a crust of chrysocolla (Ccl) overgrown by pseudomalachite (Pm) and malachite (Mal) in sample M1; (b) radial aggregates of kipushite–philipsburgite (Phb) crystals with pronounced banding, sample M2; (c) highly weathered
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(a) Scanning electron microscope (SEM) image of a cellular silica-rich crus...

(a) Scanning electron microscope (SEM) image of a cellular silica-rich crus...

Published: 01 June 2016
Fig. 2 (a) Scanning electron microscope (SEM) image of a cellular silica-rich crust overgrown by pseudomalachite (Pm) and malachite (Mal), sample M5; (b) BSE image of a cross section through botryoidal pseudomalachite (Pm) overgrown by radial aggregates of kipushite–philipsburgite (Phb), sample
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Raman bands of holotype goldhillite and goldhillite, philipsburgite and kip...

Raman bands of holotype goldhillite and goldhillite, philipsburgite and kip...

Published: 13 May 2022
Table 1. Raman bands of holotype goldhillite and goldhillite, philipsburgite and kipushite by Ciesielczuk et al. ( 2016 ). Range (cm –1 ) This study Ciesielczuk et al. ( 2016 ) Tentative assignment Goldhillite Goldhillite Intermediate member* Kipushite As 1.63
Journal Article

New Mineral Names

Aaron J. Celestian
Published: 03 October 2022
American Mineralogist (2022) 107 (10): 1982–1984.
DOI: https://doi.org/10.2138/am-2022-NMN1071016
... kipushite, (Cu,Zn) 5 Zn(PO 4 ) 2 (OH) 6 ·H 2 O and the arsenate end-member was not known at the time. This new study redefines the structure and chemical composition of philipsburgite to show that philipsburgite has ordered phosphate-arsenate sites, Cu 5 Zn(AsO 4 )(PO 4 )(OH) 6 ·H 2 O, and defines...
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Preface: The 8 th European Conference on Mineralogy and Spectroscopy

Published: 01 June 2016
European Journal of Mineralogy (2016) 28 (3): 511.
DOI: https://doi.org/10.1127/ejm/2016/0028-2546
... in the pseudomalachite–cornwallite and kipushite–philipsburgite phosphate–arsenate solid solutions. Tempesta et al. present micro-destructive and standardless chemical analyses of red beryls by means of Laser Induced Breakdown Spectroscopy and reveal different mineral species, while the studies by Ertl et al...
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Dongchuanite, a new phosphate mineral with a new structure, from Dongchuan copper mine, Yunnan Province, China

Guowu Li, Ningyue Sun, Hongtao Shen, Yuan Xue, Jinhua Hao, Jeffrey de Fourestier
Published: 24 May 2023
Mineralogical Magazine (2023) 87 (4): 611–618.
DOI: https://doi.org/10.1180/mgm.2023.16
... minerals may have been formed by the weathering of copper, lead and zinc sulfides under the action of surface water. Associated minerals are quartz, theisite, veszelyite, kipushite, tangdanite, tyrolite, arsenoveszelyite, bayldonite, cuprodongchuanite and hemimorphite. Dongchuanite is composed...
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The new mineral cuprozheshengite, Pb 4 CuZn 2 (AsO 4 ) 2 (PO 4 ) 2 (OH) 2 , from Yunnan, China, with site-selective As-P substitution

Ningyue Sun, Ian E. Grey, Guowu Li, Christian Rewitzer, Yuan Xue, William G. Mumme, Hongtao Shen, Jinhua Hao, Colin M. MacRae, Alan Riboldi-Tunnicliffe, Stephanie Boer, Tim Williams, Anthony R. Kampf
Published: 01 July 2024
American Mineralogist (2024) 109 (7): 1248–1257.
DOI: https://doi.org/10.2138/am-2023-8942
... homophase substitutions occur at different structural sites. For example, philipsburgite, Cu 5 Zn[(AsO 4 ) (PO 4 )](OH) 6 ·H 2 O, is an intermediate member with PO 4 /AsO 4 ordering, between kipushite, Cu 5 Zn[(PO 4 )(PO 4 )](OH) 6 ·H 2 O and goldhillite, Cu 5 Zn[(AsO 4 )(AsO 4 )](OH) 6 ·H 2 O ( Ismagilova...
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