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Journal Article

Isselite, Cu 6 (SO 4 )(OH) 10 (H 2 O) 4 ⋅H 2 O, a new mineral species from Eastern Liguria, Italy Available to Purchase

Cristian Biagioni, Donato Belmonte, Cristina Carbone, Roberto Cabella, Nicola Demitri, Natale Perchiazzi, Anthony R. Kampf, Ferdinando Bosi
Published: 19 June 2020
Mineralogical Magazine (2020) 84 (5): 653–661.
DOI: https://doi.org/10.1180/mgm.2020.50
...Cristian Biagioni; Donato Belmonte; Cristina Carbone; Roberto Cabella; Nicola Demitri; Natale Perchiazzi; Anthony R. Kampf; Ferdinando Bosi Abstract The new mineral isselite, Cu 6 (SO 4 )(OH) 10 (H 2 O) 4 ⋅H 2 O, has been discovered in the Lagoscuro mine, Monte Ramazzo mining complex, Genoa...
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Coordination environments of Cu2+ in the crystal structure of isselite. The colour scheme is the same as in Fig. 3.

Coordination environments of Cu 2+ in the crystal structure of isselite. T... Available to Purchase

Published: 19 June 2020
Fig. 4. Coordination environments of Cu 2+ in the crystal structure of isselite. The colour scheme is the same as in Fig. 3 .
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Raman spectrum of isselite in the range 200–1200 cm–1 (a) and 2700–4000 cm–1 (b).

Raman spectrum of isselite in the range 200–1200 cm –1 ( a ) and 2700–4000... Available to Purchase

Published: 19 June 2020
Fig. 2. Raman spectrum of isselite in the range 200–1200 cm –1 ( a ) and 2700–4000 cm –1 ( b ).
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Comparison between the crystal structure of isselite (a) and those of montetrisaite (b) and redgillite (c). The colour scheme is the same as in Fig. 3.

Comparison between the crystal structure of isselite ( a ) and those of mon... Available to Purchase

Published: 19 June 2020
Fig. 5. Comparison between the crystal structure of isselite ( a ) and those of montetrisaite ( b ) and redgillite ( c ). The colour scheme is the same as in Fig. 3 .
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Isselite, sprays of acicular blue crystals. Field of view: 2 mm. Monte Ramazzo mining complex, Genoa. Photo M. Esposito. The crystal morphology is shown to the right.

Isselite, sprays of acicular blue crystals. Field of view: 2 mm. Monte Rama... Available to Purchase

Published: 19 June 2020
Fig. 1. Isselite, sprays of acicular blue crystals. Field of view: 2 mm. Monte Ramazzo mining complex, Genoa. Photo M. Esposito. The crystal morphology is shown to the right.
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Crystal structure of isselite as seen down b. Symbols: green polyhedra = Cu sites and yellow polyhedra = S site. Circles: red = O2–, blue = OH– and light blue = H2O.

Crystal structure of isselite as seen down b . Symbols: green polyhedra = ... Available to Purchase

Published: 19 June 2020
Fig. 3. Crystal structure of isselite as seen down b . Symbols: green polyhedra = Cu sites and yellow polyhedra = S site. Circles: red = O 2 – , blue = OH – and light blue = H 2 O.
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Selected bond distances (in Å) for isselite. Cu (1)–OH(6) 1.9... Available to Purchase

Published: 19 June 2020
Table 5. Selected bond distances (in Å) for isselite. Cu (1)–OH(6) 1.950(8) ×2 Cu (4)–OH(2) 1.928(5) Cu (1)–OH(5) 1.961(7) ×2 Cu (4)–OH(1) 1.937(5) < Cu (1)–OH> 1.956 Cu (4)–OH(5) 1.950(7) Cu (1)–Ow(12) 2.623(13) Cu (4)–OH(3) 1.963(7) < Cu (4
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Electron microprobe analysis of isselite (average of six spot analyses – in... Available to Purchase

Published: 19 June 2020
Table 1. Electron microprobe analysis of isselite (average of six spot analyses – in wt.%). Oxide Mean Range S.D. SO 3 11.45 11.30–11.73 0.21 MgO 0.31 0.20–0.40 0.07 CoO 1.07 0.89–1.22 0.14 NiO 9.41 8.63–11.01 0.90 CuO 51.29 49.03–52.55 1.26 ZnO
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X-ray powder diffraction ( d in Å) data for isselite * . I ... Available to Purchase

Published: 19 June 2020
Table 2. X-ray powder diffraction ( d in Å) data for isselite * . I obs d obs I calc d calc h k l s 10 . 3 92 10 . 3 0 0 2 m 6 . 4 29 6 . 46 1 0 1 mw 5 . 67 25 5 . 67 0 1 1 w 5.14 11 5.12 0 1 2 vs 4
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Bond-valence sums (BVS – in valence units) for isselite * . ... Available to Purchase

Published: 19 June 2020
Table 6. Bond-valence sums (BVS – in valence units) for isselite * .   Cu (1) Cu (2) Cu (3) Cu (4) Cu (5) S Σanions OH(1) 0.23 2×→ 0.50 1.23 OH(2) 0.22 2×→ 0.51 1.24 OH(3) 0.39 ↓×2 0.46 0.46 ↓×2 1.31 OH(4) 0.43 ↓×2 0.49
Journal Article

New minerals and nomenclature modifications approved in 2019 Available to Purchase

Ritsuro Miyawaki, Frédéric Hatert, Marco Pasero, Stuart J. Mills
Published: 01 April 2019
Mineralogical Magazine (2019) 83 (2): 315–317.
DOI: https://doi.org/10.1180/mgm.2019.23
... No. 48, April 2019, page 316; Mineralogical Magazine , 83 , 315–317. IMA No. 2018-139 Isselite Cu 6 (SO 4 )(OH) 10 ·5H 2 O Lagoscuro mine, Ceranesi, Genoa Province, Liguria, Italy (44°28’35”N, 8°51’35”E) Cristian Biagioni*, Donato Belmonte, Cristina Carbone, Roberto Cabella...
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Journal Article

IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) NEWSLETTER 48 New minerals and nomenclature modifications approved in 2019 Open Access

Ritsuro Miyawaki, Frédéric Hatert, Marco Pasero, Stuart J. Mills
Published: 01 March 2019
European Journal of Mineralogy (2019) 31 (2): 399–402.
DOI: https://doi.org/10.1127/ejm/2019/0031-2852
...., Mihály, J. and Szabó, D. (2019) Kollerite, IMA 2018-131. CNMNC Newsletter No. 48, April 2019, page 399; European Journal of Mineralogy , 31 , 399–402. IMA No. 2018-133 Isselite Cu 6 (SO 4 )(OH) 10 ·5H 2 O Lagoscuro mine, Ceranesi, Genoa Province, Liguria, Italy (44°28′35″N, 8°51′35″E...
View PDF for article title, IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) NEWSLETTER 48 New minerals and nomenclature modifications approved in 2019
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Journal Article

MGM volume 84 issue 5 Cover and Back matter Available to Purchase

Published: 01 October 2020
Mineralogical Magazine (2020) 84 (5): b1–b2.
DOI: https://doi.org/10.1180/mgm.2020.83
..., ANTHONY R. KAMPF and FERDINANDO BOSI: Isselite, Cu6(SO4)(OH)10(H2O)4. H2O, a new mineral species from Eastern Liguria, Italy 653 EMIL AARESTRUP, TAUS R. C. JØRGENSEN, PAUL E.B. ARMITAGE, ALLEN P. NUTMAN, OLE CHRISTIANSEN and KRISTOFFER SZILAS : The Mesoarchean Amikoq Layered Complex of SW Greenland: Part...
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Crystal data and summary of parameters describing data collection and refin... Available to Purchase

Published: 19 June 2020
Table 3. Crystal data and summary of parameters describing data collection and refinement for isselite. Crystal data Crystal size (mm) 0.080 × 0.010 × 0.005 Cell setting, space group Orthorhombic, Pmn 2 1 a (Å) 6.8070(14) b (Å) 5.8970(12) c (Å) 20.653(4
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Sites, Wyckoff positions, atom coordinates and equivalent isotropic displac... Available to Purchase

Published: 19 June 2020
Table 4. Sites, Wyckoff positions, atom coordinates and equivalent isotropic displacement parameters (Å 2 ) for isselite. Site Wyk. x y z U eq Cu (1) 2 a 0 0.0315(3) 0.01412(8) 0.0249(4) Cu (2) 2 a 0 0.5234(3) 0.00062(8) 0.0239(4) Cu (3) 2 b
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Natural Cu sulfates in the system CuO–SO 3 –H 2 O. Minera... Available to Purchase

Published: 19 June 2020
and Giester ( 1988 ) Dolerophanite Cu 2 O(SO 4 ) 9.37 6.32 7.64 90 122.3 90 C 2/ m Effenberger ( 1985 ) Isselite Cu 6 (SO 4 )(OH) 10 (H 2 O) 4 ⋅H 2 O 6.81 5.90 20.65 90 90 90 Pmn 2 1 This work Kobyashevite Cu 5 (SO 4 ) 2 (OH) 6 (H 2 O) 4 6.07 11.06 5.51 102.9 92.3 92.6
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Natural Cu sulfates in the system CuO–SO 3 –H 2 O. Minera... Available to Purchase

Published: 19 June 2020
and Giester ( 1988 ) Dolerophanite Cu 2 O(SO 4 ) 9.37 6.32 7.64 90 122.3 90 C 2/ m Effenberger ( 1985 ) Isselite Cu 6 (SO 4 )(OH) 10 (H 2 O) 4 ⋅H 2 O 6.81 5.90 20.65 90 90 90 Pmn 2 1 This work Kobyashevite Cu 5 (SO 4 ) 2 (OH) 6 (H 2 O) 4 6.07 11.06 5.51 102.9 92.3 92.6
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Natural Cu sulfates in the system CuO–SO 3 –H 2 O. Minera... Available to Purchase

Published: 19 June 2020
and Giester ( 1988 ) Dolerophanite Cu 2 O(SO 4 ) 9.37 6.32 7.64 90 122.3 90 C 2/ m Effenberger ( 1985 ) Isselite Cu 6 (SO 4 )(OH) 10 (H 2 O) 4 ⋅H 2 O 6.81 5.90 20.65 90 90 90 Pmn 2 1 This work Kobyashevite Cu 5 (SO 4 ) 2 (OH) 6 (H 2 O) 4 6.07 11.06 5.51 102.9 92.3 92.6
Image

Natural Cu sulfates in the system CuO–SO 3 –H 2 O. Minera... Available to Purchase

Published: 19 June 2020
and Giester ( 1988 ) Dolerophanite Cu 2 O(SO 4 ) 9.37 6.32 7.64 90 122.3 90 C 2/ m Effenberger ( 1985 ) Isselite Cu 6 (SO 4 )(OH) 10 (H 2 O) 4 ⋅H 2 O 6.81 5.90 20.65 90 90 90 Pmn 2 1 This work Kobyashevite Cu 5 (SO 4 ) 2 (OH) 6 (H 2 O) 4 6.07 11.06 5.51 102.9 92.3 92.6