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interdiffusion

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Journal Article
Published: 01 June 2023
American Mineralogist (2023) 108 (6): 1064–1071.
... and homogeneous heating compared with a conventional laser-heated DAC and thus allows us to conduct more reliable diffusion experiments under high pressure. We determined the coefficients of Fe–nickel (Ni) interdiffusion in the Fe–Si 2 wt% alloy. The obtained diffusion coefficients follow a homologous temperature...
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Journal Article
Published: 01 October 2019
American Mineralogist (2019) 104 (10): 1444–1454.
... archipelago. In this work, we aim to complete the previously published internally consistent database by focusing on the interdiffusion of eight major elements (Si, Al, Ti, Fe, Mg, Ca, Na, and K) occurring between nominally dry (ca. 0.02 wt% H 2 O) shoshonitic and rhyolitic melts at atmospheric pressure...
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Journal Article
Published: 01 October 2016
American Mineralogist (2016) 101 (10): 2210–2221.
...Ralf Dohmen; Jan H. Ter heege; Hans-Werner Becker; Sumit Chakraborty Abstract We have measured Fe-Mg interdiffusion coefficients, D Fe-Mg , parallel to the three main crystallographic axes in two natural orthopyroxene single crystals [approximately En 98 Fs 1 ( X Fs = X Fe = 0.01) and En 91 Fs 9...
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Journal Article
Published: 01 November 2013
American Mineralogist (2013) 98 (11-12): 1919–1929.
... and polycrystalline D-doped brucite showed an asymmetric pattern characterized by faster diffusion in aggregates. The D/H interdiffusion rate determined from the analysis of the single crystal side indicates that the interdiffusion rate increases with increasing H/D ratio. The H-D interdiffusion rate in the direction...
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Journal Article
Published: 01 December 2009
Russ. Geol. Geophys. (2009) 50 (12): 1146–1152.
...V.N. Korolyuk; G.G. Lepezin Abstract Literature data on the coefficients of heterovalent NaSi–CaAl interdiffusion in plagioclases are analyzed. It is shown that activation energy and frequency factor decrease as the partial pressure of water and plagioclase basicity increase. A general expression...
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First thumbnail for: The coefficients of heterovalent NaSi–CaAl <span c...
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Journal Article
Published: 01 November 2006
European Journal of Mineralogy (2006) 18 (6): 705–718.
...Alexandre Dimanov; Michael Wiedenbeck Abstract We investigated (Fe,Mn)-Mg interdiffusion along the [001] axis in single crystals of natural diopside at ambient pressure, at temperatures between 1000°C to 1200°C and at oxygen fugacities between 10 −18.5 atm to 10 −6 atm. Thin layers (~350–550 Å...
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Journal Article
Published: 01 July 2000
European Journal of Mineralogy (2000) 12 (4): 749–760.
...Alexandre DIMANOV; Violaine SAUTTER Abstract (Fe,Mn)-Mg interdiffusion has been investigated in single crystals of natural diopside at ambient pressure, high temperatures (900°C to 1240°C) and low oxygen fugacity (pO 2 ≈ 10 −18 atm to 10 −13 atm). Interdiffusion couples were made...
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Journal Article
Published: 01 April 1995
European Journal of Mineralogy (1995) 7 (2): 295–307.
Journal Article
Published: 01 October 1994
American Mineralogist (1994) 79 (9-10): 930–937.
Journal Article
Published: 01 April 1993
American Mineralogist (1993) 78 (3-4): 316–324.
...Don R. Baker Abstract Interdiffusion experiments between peralkaline fluoridated melts of rhyolitic and dacitic composition (with ∼ 1.3 wt% F) at 1200–1600°C, 1.0 G P a, have yielded effective binary diffusion coefrcients for Si. Similar interdiffusion experiments between a natural peralkaline...
Journal Article
Published: 01 April 1992
American Mineralogist (1992) 77 (3-4): 275–283.
...Ming Liu; Richard A. Yund Abstract Average NaSi-CaAl interdiffusion coefficients ( D̃ ) have been determined for the plagioclase Huttenlocher interval (~An 70 to ~An 90 ) using the method of lamellar homogenization at 1500 MPa, 1050 to 900 °C, ∼1.0 wt% H 2 O added, and fugacities fixed...
Journal Article
Journal: Geology
Published: 01 July 1989
Geology (1989) 17 (7): 626–629.
... in the various lithologic units in the macrodikes and experimental observations involving liquid immiscibility and silicate liquid interdiffusion suggests that chemical equilibrium between the magma reservoirs was approached through diffusive element exchange. Geological Society of America 1989 ...
Journal Article
Journal: Economic Geology
Published: 01 October 1988
Economic Geology (1988) 83 (6): 1205–1220.
...Toshio Mizuta Abstract The interdiffusion coefficients of zinc and iron in natural iron-poor and iron-rich sphalerites were determined experimentally using electron microprobe analysis. The diffusion couples were heated in sealed silica tubes for predetermined lengths of time together with f (sub S...
Journal Article
Published: 01 December 1986
American Mineralogist (1986) 71 (11-12): 1409–1414.
...Sarah A. Hokanson; Richard A. Yund Abstract Lamellar homogenization rates were used to determine “average” interdiffusion coefficients ( D ) for seven largely disordered cryptoperthites with relatively straight, coherent lamellae and <1.6 mol% An and for two highly ordered samples...
Journal Article
Published: 01 February 1983
American Mineralogist (1983) 68 (1-2): 106–111.
...John B. Brady; Richard A. Yund Abstract The rates of homogenization of coherent exsolution lamellae in cryptoperthites have been used to evaluate K-Na interdiffusion in alkali feldspars. An “average” interdiffusion coefficient ( D ) is between 2 and 4 x 10 -17 cm 2 /sec for a synthetic...
Journal Article
Published: 01 August 1980
American Mineralogist (1980) 65 (7-8): 797–799.
...Nabil Z. Boctor; John B. Brady Abstract Diffusion coefficients for S–Se interdiffusion in tiemannite (HgSe) single crystals have been determined in the temperature range 500°–700°C. The measured diffusivities may be fit by the equation D = ( 5.7 × 10 − 12 ) exp ⁡ − 105 , 000 8.314 T cm 2 / sec...
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Summary of data for CaAl-NaSi interdiffusion (obtained via lamellar homogenization under a variety of experimental conditions) and Si diffusion (obtained through direct profiling using a 30Si tracer). CaAl-NaSi interdiffusion is considerably faster under hydrothermal conditions than under dry conditions. Both the CaAl-NaSi interdiffusion and Si diffusion measurements indicate some dependence on plagioclase composition, with CaAl-NaSi interdiffusion and Si diffusion slower in more calcic plagioclase. Data for Si diffusion in anorthite (An93) and those for the more Na-rich plagioclases labradorite (An66) and oligoclase (An23) (all for experiments run under anhydrous conditions) bracket the determination of CaAl-NaSi interdiffusion in bytownite under dry conditions. Sources for data: CaAl-NaSi interdiffusion, An70–90, dry – Grove et al. (1984); CaAl-NaSi interdiffusion, An0–26, dry – Yund (1986); CaAl-NaSi, peristerite (An0–26), xH2O = 0.5 – Baschek and Johannes (1995); CaAl-NaSi interdiffusion, MH buffer, 1500 MPa, An0–26, An70–90– Lin and Yund (1992); Si diffusion – Cherniak (2003b).
Published: 01 January 2010
Figure 5. Summary of data for CaAl-NaSi interdiffusion (obtained via lamellar homogenization under a variety of experimental conditions) and Si diffusion (obtained through direct profiling using a 30 Si tracer). CaAl-NaSi interdiffusion is considerably faster under hydrothermal conditions than
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Summary of experimental data for diffusion of Ni in periclase. (a) Ni-Mg interdiffusion coefficients as a function of Ni cation fraction and temperature (all data from Blank and Pask 1969). In air, the interdiffusion coefficients increase strongly with Ni concentration. Under vacuum the interdiffusion coefficients are independent of composition and similar to the values in air at xNi = 0) (b) Ni tracer diffusion coefficients and interdiffusion coefficients at xNi ~ 0)
Published: 01 January 2010
Figure 10. Summary of experimental data for diffusion of Ni in periclase. (a) Ni-Mg interdiffusion coefficients as a function of Ni cation fraction and temperature (all data from Blank and Pask 1969 ). In air, the interdiffusion coefficients increase strongly with Ni concentration. Under vacuum
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Exemplary crystals and results for Fe-Mg interdiffusion time-scale modeling. (A) Backscattered electron (BSE) images of analyzed crystals. Red boxes indicate area used to derive grayscale profiles. Scale bars are 100 µm. (B) Crystal-axis data from electron backscatter diffraction analyses: 100 (a-axis), 010 (b-axis) and 001 (c-axis) are displayed on equal-area, lower-hemisphere stereographic projections. Red arrow indicates trend of modeled profile. (C) Measured (black diamonds) and modeled (red line) compositional profiles. Values of Mg# [100 × Mg / (Mg + Fe)] were converted from grayscale intensity values derived from BSE images using electron probe microanalysis data. (D) Time-scale results determined by Fe-Mg interdiffusion modeling for type 1 orthopyroxene crystals. Results for crystals from glassy samples (green diamonds) and holocrystalline samples (gray diamonds) are distinguished, and crystals with optimal c-axis orientations for modeling are marked with black outlines. Error bars are 1σ modeling uncertainties (T—temperature).
Published: 25 June 2020
Figure 3. Exemplary crystals and results for Fe-Mg interdiffusion time-scale modeling. (A) Backscattered electron (BSE) images of analyzed crystals. Red boxes indicate area used to derive grayscale profiles. Scale bars are 100 µm. (B) Crystal-axis data from electron backscatter diffraction
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Comparison of the Fe-Mg interdiffusion data in spinel obtained in this study with those in olivine (Dohmen et al. 2007), garnet (Borinski et al. 2012), clinopyroxene (Müller et al. 2013), and orthopyroxene (Dohmen et al. personal communication).
Published: 01 October 2015
Figure 11 Comparison of the Fe-Mg interdiffusion data in spinel obtained in this study with those in olivine ( Dohmen et al. 2007 ), garnet ( Borinski et al. 2012 ), clinopyroxene ( Müller et al. 2013 ), and orthopyroxene (Dohmen et al. personal communication).