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hielscherite

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Journal Article

The sulfite anion in ettringite-group minerals: a new mineral species hielscherite, Ca 3 Si(OH) 6 (SO 4 )(SO 3 )·11H 2 O, and the thaumasite–hielscherite solid-solution series

I. V. Pekov, N. V. Chukanov, S. N. Britvin, Y. K. Kabalov, J. Göttlicher, V. O. Yapaskurt, A. E. Zadov, S. V. Krivovichev, W. Schüller, B. Ternes
Published: 01 October 2012
Mineralogical Magazine (2012) 76 (5): 1133–1152.
DOI: https://doi.org/10.1180/minmag.2012.076.5.06
...I. V. Pekov; N. V. Chukanov; S. N. Britvin; Y. K. Kabalov; J. Göttlicher; V. O. Yapaskurt; A. E. Zadov; S. V. Krivovichev; W. Schüller; B. Ternes Abstract Hielscherite, ideally Ca 3 Si(OH) 6 (SO 4 )(SO 3 )·11H 2 O, (IMA 2011-037) is the first ettringite-group mineral with essential sulfite. We have...
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View PDF for article title, The sulfite anion in ettringite-group minerals: a new mineral species <span class="search-highlight">hielscherite</span>, Ca 3 Si(OH) 6 (SO 4 )(SO 3 )·11H 2 O, and the thaumasite–<span class="search-highlight">hielscherite</span> solid-solution series
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Image
The arrangement of CO3, SO3 and SO4 anions in the crystal structures of thaumasite hielscherite series minerals: (left) sulfate and carbonate groups in thaumasite (Effenberger et al., 1983); (right) sulfate and superimposed sulfite/carbonate groups in hielscherite and SO3-bearing thaumasite; (middle) presumed arrangement of sulfate and sulfite groups in the hypothetical CO3-free hielscherite endmember Ca3Si(SO4)(SO3)(OH)6·11H2O.

The arrangement of CO 3 , SO 3 and SO 4 anions in the crystal structures ...

Published: 01 October 2012
F ig . 9. The arrangement of CO 3 , SO 3 and SO 4 anions in the crystal structures of thaumasite hielscherite series minerals: (left) sulfate and carbonate groups in thaumasite ( Effenberger et al. , 1983 ); (right) sulfate and superimposed sulfite/carbonate groups in hielscherite and SO 3
Image
The IR spectra of thaumasite–hielscherite series minerals: (1–2) hielscherite; (3–5) sulfite-bearing thaumasite. Samples are in order of decreasing SO3 content as follows: (1) G-3234, (2) G-3231, (3) G-3227, (4) G-3235, and (5) R-3240 (for chemical data see Table 2). The IR spectrum of sample Zb-01 is almost identical to that of G-3235 (4).

The IR spectra of thaumasite–hielscherite series minerals: (1–2) hielscheri...

Published: 01 October 2012
F ig . 5. The IR spectra of thaumasite–hielscherite series minerals: (1–2) hielscherite; (3–5) sulfite-bearing thaumasite. Samples are in order of decreasing SO 3 content as follows: (1) G-3234, (2) G-3231, (3) G-3227, (4) G-3235, and (5) R-3240 (for chemical data see Table 2 ). The IR spectrum
Image
Crystals of hielscherite on the holotype specimen (G-3049) from Graulay quarry. Secondary electron SEM image.

Crystals of hielscherite on the holotype specimen (G-3049) from Graulay qua...

Published: 01 October 2012
F ig . 1. Crystals of hielscherite on the holotype specimen (G-3049) from Graulay quarry. Secondary electron SEM image.
Image
Clusters of acicular hielscherite crystals on phillipsite-K on the holotype specimen (G-3049) from Graulay quarry. Secondary electron SEM image.

Clusters of acicular hielscherite crystals on phillipsite-K on the holotype...

Published: 01 October 2012
F ig . 2. Clusters of acicular hielscherite crystals on phillipsite-K on the holotype specimen (G-3049) from Graulay quarry. Secondary electron SEM image.
Image
Crystal structures of hielscherite and sulfite-rich thaumasite. They differ primarily in the occupancies of the S2 sites (corresponding to SO3 groups) and the C sites (see text). The unit cell is shown.

Crystal structures of hielscherite and sulfite-rich thaumasite. They differ...

Published: 01 October 2012
F ig . 8. Crystal structures of hielscherite and sulfite-rich thaumasite. They differ primarily in the occupancies of the S2 sites (corresponding to SO 3 groups) and the C sites (see text). The unit cell is shown.
Image
Hielscherite from Graulay quarry: (a) matted aggregate (1 mm across) on phillipsite in a miarolitic cavity in alkaline basalt (on the holotype specimen, G-3049); (b) matted aggregate (1.5 mm across) filling a small gas cavity in fresh volcanic glass (G-3229); (c) groups of crystals (up to 0.2 mm long) in a cavity in altered volcanic glass (G-3231). Photos (a–b) I.V. Pekov and A.V. Kasatkin, (c) F. Krujen.

Hielscherite from Graulay quarry: ( a ) matted aggregate (1 mm across) on p...

Published: 01 October 2012
F ig . 3. Hielscherite from Graulay quarry: ( a ) matted aggregate (1 mm across) on phillipsite in a miarolitic cavity in alkaline basalt (on the holotype specimen, G-3049); ( b ) matted aggregate (1.5 mm across) filling a small gas cavity in fresh volcanic glass (G-3229); ( c ) groups
Image
The sulfur K-edge XANES spectrum of (a) hielscherite, with the following spectra of sulfur compounds with different S valences for comparison: (b) thaumasite; (c) synthetic CaSO4 with S6+ in sulfate anion; (d) synthetic Na2SO3, with S4+ in the sulfite anion; (e) native sulfur, with So; (f) pyrite, FeS2, with S22− in disulfide; and (g) synthetic FeS with S2− in sulfide.

The sulfur K -edge XANES spectrum of (a) hielscherite, with the following ...

Published: 01 October 2012
F ig . 7. The sulfur K -edge XANES spectrum of (a) hielscherite, with the following spectra of sulfur compounds with different S valences for comparison: (b) thaumasite; (c) synthetic CaSO 4 with S 6+ in sulfate anion; (d) synthetic Na 2 SO 3 , with S 4+ in the sulfite anion; (e) native
Image
The IR spectra of (1) kottenheimite from Bellerberg, Eifel, Germany; (2) thaumasite from Uraveli, Akhaltsikhe, Georgia; (3) ettringite from Nickenicher Sattel, Eifel; and (4) holotype hielscherite G-3049 from Graulay quarry: (a) the region 400–2000 cm−1; (b) the O–H-stretching region (2500–3800 cm−1).

The IR spectra of (1) kottenheimite from Bellerberg, Eifel, Germany; (2) th...

Published: 01 October 2012
F ig . 4. The IR spectra of (1) kottenheimite from Bellerberg, Eifel, Germany; (2) thaumasite from Uraveli, Akhaltsikhe, Georgia; (3) ettringite from Nickenicher Sattel, Eifel; and (4) holotype hielscherite G-3049 from Graulay quarry: ( a ) the region 400–2000 cm −1 ; ( b ) the O–H-stretching
Journal Article

KOTTENHEIMITE, Ca 3 Si(OH) 6 (SO 4 ) 2 ·12H 2 O, A NEW MEMBER OF THE ETTRINGITE GROUP FROM THE EIFEL AREA, GERMANY

Nikita V. Chukanov, Sergey N. Britvin, Konstantin V. Van, Steffen Möckel, Aleksandr E. Zadov
Published: 01 February 2012
The Canadian Mineralogist (2012) 50 (1): 55–63.
DOI: https://doi.org/10.3749/canmin.50.1.55
... : Ca 6 ( Al 1.88 Si 0.08 ) Σ 1.96 ( OH , O ) 12 ( SO 4 ) 2.77 ( CO 3 ) x · n H 2 O hielscherite : Ca 3 ( Si 0.73 Al 0.28 ) Σ 1.01 ( OH ) 5.71 ( SO 4...
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View PDF for article title, KOTTENHEIMITE, Ca 3 Si(OH) 6 (SO 4 ) 2 ·12H 2 O, A NEW MEMBER OF THE ETTRINGITE GROUP FROM THE EIFEL AREA, GERMANY
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IR spectra of kottenheimite (1), thaumasite from the outcrop at the mouth of Uraveli river, near Akhaltsykhe, Georgia (2), ettringite from Nickenicher Sattel, Eifel, Germany (3) and hielscherite Ca3Si(OH)6(SO4) (SO3)·11H2O (IMA 2011–037), a SO3-dominant analogue of thaumasite (4) in the region 400–2000 cm−1 (a) and in the region of O–H stretching vibrations, 2500–3800 cm−1 (b).

IR spectra of kottenheimite (1), thaumasite from the outcrop at the mouth o...

Published: 01 February 2012
Fig. 3 IR spectra of kottenheimite (1), thaumasite from the outcrop at the mouth of Uraveli river, near Akhaltsykhe, Georgia (2), ettringite from Nickenicher Sattel, Eifel, Germany (3) and hielscherite Ca 3 Si(OH) 6 (SO 4 ) (SO 3 )·11H 2 O (IMA 2011–037), a SO 3 -dominant analogue of thaumasite
Image
IR spectra of kottenheimite (1), thaumasite from the outcrop at the mouth of Uraveli river, near Akhaltsykhe, Georgia (2), ettringite from Nickenicher Sattel, Eifel, Germany (3) and hielscherite Ca3Si(OH)6(SO4) (SO3)·11H2O (IMA 2011–037), a SO3-dominant analogue of thaumasite (4) in the region 400–2000 cm−1 (a) and in the region of O–H stretching vibrations, 2500–3800 cm−1 (b).

IR spectra of kottenheimite (1), thaumasite from the outcrop at the mouth o...

Published: 01 February 2012
Fig. 3 IR spectra of kottenheimite (1), thaumasite from the outcrop at the mouth of Uraveli river, near Akhaltsykhe, Georgia (2), ettringite from Nickenicher Sattel, Eifel, Germany (3) and hielscherite Ca 3 Si(OH) 6 (SO 4 ) (SO 3 )·11H 2 O (IMA 2011–037), a SO 3 -dominant analogue of thaumasite
Journal Article

New Mineral Names,

Fernando Cámara, Olivier C. Gagné, Dmitriy I. Belakovskiy, Yulia Uvarova
Published: 01 May 2015
American Mineralogist (2015) 100 (5-6): 1319–1332.
DOI: https://doi.org/10.2138/am-2015-NMN1005-616
... for 25 new minerals, including alcaparrosaite, bastnäsite-(Nd), calciolangbeinite, chovanite, chromio-pargasite (ehimeite), chukhrovite-(Ca), dzhuluite, eltyubyuite, ferrisepiolite, hereroite, hielscherite, iseite, itsiite, jakobssonite, kazanskiite, meisserite, nashite, omsite, schindlerite, tanohataite...
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Journal Article

The new mineral tomiolloite, Al 12 (Te 4+ O 3 ) 5 [(SO 3 ) 0.5 (SO 4 ) 0.5 ](OH) 24 : A unique microporous tellurite structure

Owen P. Missen, Stuart J. Mills, Michael S. Rumsey, John Spratt, Jens Najorka, Anthony R. Kampf, Brent Thorne
Published: 01 December 2022
American Mineralogist (2022) 107 (12): 2167–2175.
DOI: https://doi.org/10.2138/am-2022-8368
..., Ca 3 (SO 3 ) 2 (SO 4 )·12H 2 O ( Weidenthaler et al. 1993 ) and hielscherite, Ca 3 Si(SO 4 )(SO 3 )(OH) 6 ·11H 2 O ( Pekov et al. 2012 ). Additionally, tomiolloite is the third Al–Te oxy-salt mineral to be described, and the other two contain at least one other metallic cation. Burckhardtite [P...
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View PDF for article title, The new mineral tomiolloite, Al 12 (Te 4+ O 3 ) 5 [(SO 3 ) 0.5 (SO 4 ) 0.5 ](OH) 24 : A unique microporous tellurite structure
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Journal Article

Chiyokoite, Ca 3 Si(CO 3 )[B(OH) 4 ]O(OH) 5 ·12H 2 O, a new ettringite-group mineral from the Fuka mine, Okayama Prefecture, Japan

Inna Lykova, Nikita V. Chukanov, Igor V. Pekov, Vasiliy O. Yapaskurt, Leonid A. Pautov, Vladimir Yu. Karpenko, Dmitry I. Belakovskiy, Dmitry A. Varlamov, Sergey N. Britvin, Katharina S. Scheidl
Published: 24 November 2020
The Canadian Mineralogist (2020) 58 (5): 653–662.
DOI: https://doi.org/10.3749/canmin.2000030
... minerals belong to the second structure type: jouravskite, Ca 3 Mn 4+ (SO 4 )(CO 3 )(OH) 6 ·12H 2 O ( Granger & Protas 1969 , Chukanov et al . 2019 ); thaumasite, Ca 3 Si(SO 4 )(CO 3 )(OH) 6 ·12H 2 O ( Effenberger et al . 1983 , Martucci & Cruciani 2006 ); hielscherite, Ca 3 Si(SO 4 )(SO 3 )(OH...
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View PDF for article title, Chiyokoite, Ca 3 Si(CO 3 )[B(OH) 4 ]O(OH) 5 ·12H 2 O, a new ettringite-group mineral from the Fuka mine, Okayama Prefecture, Japan
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Journal Article

Imayoshiite, Ca 3 Al(CO 3 )[B(OH) 4 ](OH) 6 ·12H 2 O, a new mineral of the ettringite group from Ise City, Mie Prefecture, Japan

D. Nishio-Hamane, M. Ohnishi, K. Momma, N. Shimobayashi, R. Miyawaki, T. Minakawa, S. Inaba
Published: 01 April 2015
Mineralogical Magazine (2015) 79 (2): 413–423.
DOI: https://doi.org/10.1180/minmag.2015.079.2.18
...+ (SO 4 )(CO 3 )(OH) 6 ·12H 2 O 11.06 10.50 P 6 3 2 Hielscherite Ca 3 Si(SO 4 )(SO 3 )(OH) 6 ·11H 2 O 11.11 10.49 P 6 3 3 Micheelsenite (Ca,y) 3 Al(PO 3 OH)CO 3 (OH) 6 ·12H 2 O 10.83 10.52 P 6 3 4 Ettringite Ca 3 Al(SO 4 ) 1.5 (OH) 6 ·13H 2 O 11.23 21.48 P 31 c 5...
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View PDF for article title, Imayoshiite, Ca 3 Al(CO 3 )[B(OH) 4 ](OH) 6 ·12H 2 O, a new mineral of the ettringite group from Ise City, Mie Prefecture, Japan
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Journal Article

Mikenewite, the natural analogue of synthetic α-Mn 2+ (S 4+ O 3 )⋅3H 2 O, a new sulfite mineral from the Ojuela mine, Mapimí, Mexico

Hexiong Yang, Robert A. Jenkins, James A. McGlasson, Ronald B. Gibbs, Robert T. Downs
Published: 19 April 2023
Mineralogical Magazine (2023) 87 (4): 534–541.
DOI: https://doi.org/10.1180/mgm.2023.24
... in ettringite-group minerals: a new mineral species hielscherite, Ca 3 Si(OH) 6 (SO 4 )(SO 3 )⋅11H 2 O, and the thaumasite-hielscherite solid-solution series . Mineralogical Magazine , 76 , 1133 – 1152 . Rastsvetaeva R.K...
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View PDF for article title, Mikenewite, the natural analogue of synthetic α-Mn 2+ (S 4+ O 3 )⋅3H 2 O, a new sulfite mineral from the Ojuela mine, Mapimí, Mexico
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Journal Article

Siwaqaite, Ca 6 Al 2 (CrO 4 ) 3 (OH) 12 ·26H 2 O, a new mineral of the ettringite group from the pyrometamorphic Daba-Siwaqa complex, Jordan

Rafał Juroszek, Biljana Krüger, Irina Galuskina, Hannes Krüger, Yevgeny Vapnik, Evgeny Galuskin
Published: 01 March 2020
American Mineralogist (2020) 105 (3): 409–421.
DOI: https://doi.org/10.2138/am-2020-7208
... structures: jouravskite, Ca 3 Mn 4+ (SO 4 )(CO 3 )(OH) 6 ·12H 2 O ( Granger and Protas 1969 ), thaumasite, Ca 3 Si(OH) 6 (CO 3 )(SO 4 )·12H 2 O ( Effenberger et al. 1983 ; Gatta et al. 2012 ), micheelsenite, (Ca,Y) 3 Al(PO 3 OH) (CO 3 )(OH) 6 ·12H 2 O ( McDonald et al. 2001 ), hielscherite, Ca 6 Si 2 (SO 4...
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View PDF for article title, Siwaqaite, Ca 6 Al 2 (CrO 4 ) 3 (OH) 12 ·26H 2 O, a new mineral of the ettringite group from the pyrometamorphic Daba-Siwaqa complex, Jordan
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Journal Article

Genplesite, Ca 3 Sn(SO 4 ) 2 (OH) 6 ∙3H 2 O, a new mineral of the fleischerite group: first occurrence of a tin sulfate in nature

Igor V. Pekov, Evgeny V. Sereda, Natalia V. Zubkova, Vasiliy O. Yapaskurt, Nikita V. Chukanov, Sergey N. Britvin, Inna S. Lykova, Dmitry Y. Pushcharovsky
Published: 01 March 2018
European Journal of Mineralogy (2018) 30 (2): 375–382.
DOI: https://doi.org/10.1127/ejm/2018/0030-2722
.... , Britvin , S.N. , Kabalov , Y.K. , Göttlicher , J. , Yapaskurt , V.O , Zadov , A.E. , Krivovichev , S.V. , Schüller , W. , Ternes , B. ( 2012 ): The sulfite anion in ettringite-group minerals: a new mineral species hielscherite, Ca 3 Si(OH) 6 (SO 4 )(SO 3 )∙11H 2 O...
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View PDF for article title, Genplesite, Ca 3 Sn(SO 4 ) 2 (OH) 6 ∙3H 2 O, a new mineral of the fleischerite group: first occurrence of a tin sulfate in nature
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Journal Article

The crystal structure of girvasite, NaCa 2 Mg 3 (PO 4 ) 3 (CO 3 )(H 2 O) 6 , a complex phosphate-carbonate hydrate based upon electroneutral heteropolyhedral layers

S.V. Krivovichev, A.P. Chernyatieva, S.N. Britvin, V.N. Yakovenchuk
Published: 01 January 2015
Russ. Geol. Geophys. (2015) 56 (1-2): 155–163.
DOI: https://doi.org/10.1016/j.rgg.2015.01.009
.... , Britvin , S.N. , Kabalov , Yu.K. , Göttlicher , J. , Yapaskurt , V.O. , Zadov , A.E. , Krivovichev , S.V. , Schüller , W. , Ternes , B. , 2012 . The sulfite anion in ettringite-group minerals: a new mineral species hielscherite, Ca 3 Si(OH) 6 (SO 4 )(SO 3 )·11H 2 O...
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View PDF for article title, The crystal structure of girvasite, NaCa 2 Mg 3 (PO 4 ) 3 (CO 3 )(H 2 O) 6 , a complex phosphate-carbonate hydrate based upon electroneutral heteropolyhedral layers
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