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gismondine

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Journal Article

New data on minerals with the GIS framework-type structure: gismondine-Sr from the Bellerberg volcano, Germany, and amicite and Ba-rich gismondine from the Hatrurim Complex, Israel

Katarzyna Skrzyńska, Georgia Cametti, Rafał Juroszek, Christof Schӓfer, Irina Galuskina
Published: 21 April 2023
Mineralogical Magazine (2023) 87 (3): 443–454.
DOI: https://doi.org/10.1180/mgm.2023.27
...Katarzyna Skrzyńska; Georgia Cametti; Rafał Juroszek; Christof Schӓfer; Irina Galuskina Abstract Gismondine-Sr, recently discovered in the Hatrurim Complex in Israel, has been recognised in a xenolith sample from the Bellerberg volcano in Germany. The empirical crystal-chemical formula indicates...
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Gismondine-Sr, Sr 4 (Al 8 Si 8 O 32 )·9H 2 O, a new strontium dominant, orthorhombic zeolite of the gismondine series from the Hatrurim Complex, Israel

Katarzyna Skrzyńska, Georgia Cametti, Irina O. Galuskina, Yevgeny Vapnik, Evgeny V. Galuskin
Published: 01 February 2023
American Mineralogist (2023) 108 (2): 249–258.
DOI: https://doi.org/10.2138/am-2022-8376
...Katarzyna Skrzyńska; Georgia Cametti; Irina O. Galuskina; Yevgeny Vapnik; Evgeny V. Galuskin Abstract A new mineral, gismondine-Sr with ordered gismondine framework type [ B 22 1 2 no. 20, Z = 1; a = 14.0256(2) Å, b = 10.45900(10) Å, c = 13.79360(10) Å, V = 2023.44(4) Å 3 ] and the ideal chemical...
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Topotactic transformation and dehydration of the zeolite gismondine to a novel Ca feldspar structure

Eva Wadoski-Romeijn, Thomas Armbruster
Published: 01 November 2013
American Mineralogist (2013) 98 (11-12): 1988–1997.
DOI: https://doi.org/10.2138/am.2013.4495
...Eva Wadoski-Romeijn; Thomas Armbruster Abstract Temperature-dependent single-crystal X-ray data were collected on gismondine ( GIS ) Ca 4 (Al 8 Si 8 O 32 )·18H 2 O from Rio Pian del Foco, Genova province, Italy, in steps of 25 °C up to 600 °C. At room temperature, gismondine has space group P 2 1...
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Pressure-induced over-hydration and water ordering in gismondine: A synchrotron powder diffraction study

Silvia Ori, Simona Quartieri, Giovanna Vezzalini, Vladimir Dmitriev
Published: 01 August 2008
American Mineralogist (2008) 93 (8-9): 1393–1403.
DOI: https://doi.org/10.2138/am.2008.2838
...Silvia Ori; Simona Quartieri; Giovanna Vezzalini; Vladimir Dmitriev Abstract This paper reports the results of an in situ HP synchrotron X-ray powder diffraction investigation on the natural zeolite gismondine (ideal chemical formula Ca 4 Al 8 Si 8 O 32 ·16H 2 O, space group P 2 1 / c ). The study...
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Structural changes in the natural zeolite gismondine (GIS) induced by cation exchange with Ag, Cs, Ba, Li, Na, K and Rb

Thomas Bauer, Werner H. Baur
Published: 01 February 1998
European Journal of Mineralogy (1998) 10 (1): 133–147.
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Montesommaite, (K,Na) 9 Al 9 Si 23 O 64 .10H 2 O, a new zeolite related to merlinoite and the gismondine group

Roland C. Rouse, Pete J. Dunn, Joel D. Grice, John L. Schlenker, John B. Higgins
Published: 01 December 1990
American Mineralogist (1990) 75 (11-12): 1415–1420.
... imply that montesommaite is related to merlinoite (K 5 Ca 2 Al 9 Si 23 O 64 · 24H 2 O) and to the members of the gismondine group. This suggestion is verified by a determination of the idealized substructure of montesommaite in 14,/amd symmetry using powder diffraction intensities. Copyright © 1990...
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Part of the framework containing 8- and 4-membered rings. ( a ) <span class="search-highlight">Gismondine</span>-...

Part of the framework containing 8- and 4-membered rings. ( a ) Gismondine-...

Published: 01 February 2023
Figure 8. Part of the framework containing 8- and 4-membered rings. ( a ) Gismondine-Ca projection along [001] ( Wadoski-Romeijn and Armbruster 2013 ). ( b ) Gismondine-Sr projection along [101]. ( c ) Partially dehydrated gismondine-Ca at 75 °C along [101] ( Wadoski-Romeijn and Armbruster 2013
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( a ) Gehlenite-wollastonite-garnet hornfels with small voids filled by zeo...

( a ) Gehlenite-wollastonite-garnet hornfels with small voids filled by zeo...

Published: 01 February 2023
Figure 3. ( a ) Gehlenite-wollastonite-garnet hornfels with small voids filled by zeolite including gismondine-Sr. Fragment outlined by frame is magnified in b . ( b ) Gismondine-Sr with gismondine-Ca (most probably) rim in amygdule, around which analcime occurs with an irregular distribution
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Ternary diagram showing atomic proportions in <span class="search-highlight">gismondine</span>-Sr (Gis-Sr) from t...

Ternary diagram showing atomic proportions in gismondine-Sr (Gis-Sr) from t...

Published: 21 April 2023
Figure 6. Ternary diagram showing atomic proportions in gismondine-Sr (Gis-Sr) from the Bellerberg volcano, gismondine-Sr, Ba-rich gismondine and amicite from the Hatrurim Complex ( Table 2 , Supplementary Table S3; Skrzyńska et al. 2023 ).
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Chemical composition of <span class="search-highlight">gismondine</span>-Sr from Germany, Ba-rich <span class="search-highlight">gismondine</span> and ...

Chemical composition of gismondine-Sr from Germany, Ba-rich gismondine and ...

Published: 21 April 2023
Table 2. Chemical composition of gismondine-Sr from Germany, Ba-rich gismondine and amicite from the Hatrurim Complex. * * S.D. – standard deviation; n – number of analyses; n.d. – not detected.
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BSE images: (a) the void of gehlenite-wollastonite paralava filled with ver...

BSE images: (a) the void of gehlenite-wollastonite paralava filled with ver...

Published: 02 November 2022
Figure 2 BSE images: (a) the void of gehlenite-wollastonite paralava filled with vertuminite and flörkeite; (b) crystals of phillipsite-K overgrown by flörkeite; (c) flörkeite overgrowing gismondine-Sr and gismondine-Ca in amygdule of gehlenite hornfels; x indicates a point of Raman spectra
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BSE images. (a) Cavity in xenolith from the Bellerberg volcano filled by gi...

BSE images. (a) Cavity in xenolith from the Bellerberg volcano filled by gi...

Published: 21 April 2023
Figure 2. BSE images. (a) Cavity in xenolith from the Bellerberg volcano filled by gismondine-Sr and flörkeite crystals on tobermorite; (b) gismondine-Sr in the xenolith association. Symbols from Warr ( 2021 ): Aeg – aegirine; Åk – åkermanite; Aåk – alumo åkermanite; Cbe – combeite; Gis-Sr
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Raman spectra of (a) <span class="search-highlight">gismondine</span>-Sr with corresponding vibrations of a 4-mem...

Raman spectra of (a) gismondine-Sr with corresponding vibrations of a 4-mem...

Published: 21 April 2023
Figure 4. Raman spectra of (a) gismondine-Sr with corresponding vibrations of a 4-membered ring; (b) Ba-rich gismondine; and (c) amicite.
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BSE images of paralava from the Hatrurim Complex, Israel. (a) General view ...

BSE images of paralava from the Hatrurim Complex, Israel. (a) General view ...

Published: 21 April 2023
Figure 3. BSE images of paralava from the Hatrurim Complex, Israel. (a) General view of paralava with voids filled by Ba-rich zeolite, the frame indicates the magnified fragment shown in: (b) crystals of Ba-rich gismondine. (c) General view of paralava with amygdaloidal voids filled by amicite
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Crystal data and refined parameters of <span class="search-highlight">gismondine</span>-Sr.

Crystal data and refined parameters of gismondine-Sr.

Published: 21 April 2023
Table 4. Crystal data and refined parameters of gismondine-Sr.
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Temperature dependence of normalized unit-cell volume for <span class="search-highlight">gismondine</span> upon d...

Temperature dependence of normalized unit-cell volume for gismondine upon d...

Published: 01 November 2013
Figure 2 Temperature dependence of normalized unit-cell volume for gismondine upon dehydration. From room temperature to formation of the novel Ca feldspar the volume decreases by 26%. Black dots symbolize measurements following dehydration path II (this study). The symbol size is considerably
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Interatomic distances of the extra-framework cations in the <span class="search-highlight">gismondine</span>-Sr s...

Interatomic distances of the extra-framework cations in the gismondine-Sr s...

Published: 21 April 2023
Table 6. Interatomic distances of the extra-framework cations in the gismondine-Sr structure.
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Framework of <span class="search-highlight">gismondine</span>-Sr. (a) Two types of cages filled by distinct extra...

Framework of gismondine-Sr. (a) Two types of cages filled by distinct extra...

Published: 21 April 2023
Figure 5. Framework of gismondine-Sr. (a) Two types of cages filled by distinct extra-framework cations and water molecules, view along [101]; (b) structure presented in (a) rotated by 90° around the b axis; (c) view along [010]; purple colour marks t-gsm 1 , green colour marks t-gsm 2 . Key
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( a and b ) Raman spectra of <span class="search-highlight">gismondine</span>-Sr in two orientations. (Color on...

( a and b ) Raman spectra of gismondine-Sr in two orientations. (Color on...

Published: 01 February 2023
Figure 4. ( a and b ) Raman spectra of gismondine-Sr in two orientations. (Color online.)
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The framework of <span class="search-highlight">gismondine</span>-Sr structure: ( a ) projection on (101); ( b ) ...

The framework of gismondine-Sr structure: ( a ) projection on (101); ( b ) ...

Published: 01 February 2023
Figure 5. The framework of gismondine-Sr structure: ( a ) projection on (101); ( b ) projection on (10 1 ), dashed circle indicates double crankshaft chain ( dcc ); ( c ) dcc running parallel to [10 1 ] with the marked T-O-T angle between the tetrahedra up and down. Silica tetrahedra are dark