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ferriphlogopite

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Journal Article
Published: 01 October 2011
European Journal of Mineralogy (2011) 23 (5): 703–715.
...Isabella Pignatelli; Massimo Nespolo Abstract The coexistence of two types of layer ( M 1 and M 2, differing for the origin in the octahedral sheet) in a mica polytype is confirmed for the first time in this work. The sample analysed is a 5-layer ferriphlogopite from the Ruiz Peak volcano...
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Journal Article
Published: 01 January 2011
European Journal of Mineralogy (2011) 23 (1): 73–84.
...Isabella Pignatelli; Michal Dusek; George De Titta; Massimo Nespolo Abstract The first reliable structural refinement of a non-MDO mica polytype from single-crystal X-ray diffraction data is presented. The sample is a 4-layer ferriphlogopite from the Ruiz Peak volcano, New Mexico, with cell...
FIGURES
Journal Article
Published: 01 November 2002
European Journal of Mineralogy (2002) 14 (6): 1075–1085.
... addresses the three end-members phlogopite, annite and tetra-ferriphlogopite, used as reference materials, and enters later in the interpretation of nine trioctahedral micas intermediate in composition along the joins phlogopite-tetra-ferriphlogopite and phlogopite-annite. A detailed analysis...
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Journal Article
Published: 01 November 2001
European Journal of Mineralogy (2001) 13 (6): 1099–1108.
...Gabriele GIULI; Eleonora PARIS; Ziyu WU; Maria Franca BRIGATT; Giannantonio CIBIN; Annibale MOTTANA; Augusto MARCELLI Abstract Experimental and theoretical EXAFS and XANES data on Fe coordination and bond distances have been obtained for a natural tetra-ferriphlogopite. XANES data show...
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Journal Article
Published: 01 August 1996
Clays and Clay Minerals (1996) 44 (4): 540–545.
Image
a) Mean <T–O> bond-distance versus Xtetra-ferriphlogopite. b) Mean proportion of unshared edges at the M2 site (eu(M2)) versus Xtetra-ferriphlogopite. c) Tetrahedron rotation angle, α, versus the proportion of the tetra-ferriphlogopite end member (Xtetra-ferriphlogopite). Filled symbols refer to trioctahedral micas from this study, whereas open symbols refer to trioctahedral mica crystals from Brigatti et al. (1996a, b, 1999). Samples from the Tapira complex: crosses: dunite, circles: bebedourite, diamonds enclosing a cross: perovskite magnetitite, diamonds: glimmerite, squares: garnet magnetitite, star: clinopyroxenite. Titanian phlogopite from Presidente Olegario lavas: triangle pointing up, ferroan [4]Fe3+-bearing phlogopite from Limeira I: triangle pointing down, tetra-ferriphlogopite of Hazen et al.(1981): hexagon, tetra-ferriphlogopite of Semenova et al.(1977): hexagon enclosing a cross.
Published: 01 October 2001
F ig . 3. a) Mean <T–O> bond-distance versus X tetra-ferriphlogopite . b) Mean proportion of unshared edges at the M 2 site (e u(M2) ) versus X tetra-ferriphlogopite . c) Tetrahedron rotation angle, α, versus the proportion of the tetra-ferriphlogopite end member (X tetra
Journal Article
Published: 01 August 2014
Clays and Clay Minerals (2014) 62 (4): 243–252.
.... a tetra-ferriphlogopite from an alkaline-carbonatitic complex near Tapira, Belo Horizonte, Minas Gerais, Brazil, and an Fe 2+ -bearing phlogopite containing less tetrahedral Fe 3+ from the Kovdor carbonatite-bearing, alkaline-ultrabasic complex, Kola Peninsula, Russia, are explored here. Mineral-surface...
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Journal Article
Published: 01 June 2000
The Canadian Mineralogist (2000) 38 (3): 617–626.
...Roger H. Mitchell; Viktor N. Yakovenchuk; Anton R. Chakhmouradian; Peter C. Burns; Yakov A. Pakhomovsky Abstract A new hollandite-type titanate, henrymeyerite, occurs in a vein of tetra-ferriphlogopite – calcite – dolomite carbonatite of the Kovdor alkaline ultramafic complex, Kola Peninsula...
FIGURES
Journal Article
Published: 01 February 2008
The Canadian Mineralogist (2008) 46 (1): 19–40.
... contents, likely due to the different position of this phase in the crystallization sequence; Sc reaches values as high as 200 ppm, whereas the lanthanides show very variable enrichment in light over heavy REE, and commonly show a negative Eu anomaly. The olivine, phlogopite (and tetra-ferriphlogopite), Cr...
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Journal Article
Published: 01 October 2001
The Canadian Mineralogist (2001) 39 (5): 1333–1345.
...F ig . 3. a) Mean <T–O> bond-distance versus X tetra-ferriphlogopite . b) Mean proportion of unshared edges at the M 2 site (e u(M2) ) versus X tetra-ferriphlogopite . c) Tetrahedron rotation angle, α, versus the proportion of the tetra-ferriphlogopite end member (X tetra...
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Image
Mössbauer spectrum from several crystals of the ferriphlogopite sample.
Published: 01 October 2011
Fig. 1. Mössbauer spectrum from several crystals of the ferriphlogopite sample.
Image
Fe K-XANES spectra of the clinochlore studied compared with those of tetra-ferriphlogopite and annite.
Published: 01 April 2009
Figure 1. Fe K -XANES spectra of the clinochlore studied compared with those of tetra-ferriphlogopite and annite.
Image
Variation in unit-cell parameter a versus Xtetra-ferriphlogopite. Symbols as in Figure 3.
Published: 01 October 2001
F ig . 7. Variation in unit-cell parameter a versus X tetra-ferriphlogopite . Symbols as in Figure 3 .
Image
Si2p spectrum of tetra-ferriphlogopite (a) and Fe-bearing phlogopite (b) displayed as a plot of electron binding energy vs. intensity (the number of electrons per second in a fixed and small energy interval). Dotted lines: experimental spectra; solid lines: fitted spectra.
Published: 01 August 2014
Figure 1 Si 2p spectrum of tetra-ferriphlogopite (a) and Fe-bearing phlogopite (b) displayed as a plot of electron binding energy vs . intensity (the number of electrons per second in a fixed and small energy interval). Dotted lines: experimental spectra; solid lines: fitted spectra.
Image
Mg1s spectra of tetra-ferriphlogopite (a) and Fe-bearing phlogopite (b) displayed as a plot of electron binding energy vs. intensity (the number of electrons per second in a fixed and small energy interval). Dotted lines: experimental spectra; solid lines: fitted spectra.
Published: 01 August 2014
Figure 3 Mg 1s spectra of tetra-ferriphlogopite (a) and Fe-bearing phlogopite (b) displayed as a plot of electron binding energy vs . intensity (the number of electrons per second in a fixed and small energy interval). Dotted lines: experimental spectra; solid lines: fitted spectra.
Image
Fe2p spectrum with the curve fit obtained for tetra-ferriphlogopite (a). The spectrum is displayed as a plot of electron binding energy vs. intensity (the number of electrons per second in a fixed and small energy interval). The Fe3+ and Fe2+ multiplet peaks are labeled on the spectrum. Fesat3+ and Fesat2+ refer to the associated satellite peaks of Fe3+ and Fe2+, respectively. Fe2p spectrum obtained for Fe-bearing phlogopite (b). Dotted lines: experimental spectra; solid lines: deconvoluted peaks. See text for additional explanations.
Published: 01 August 2014
Figure 4 Fe 2p spectrum with the curve fit obtained for tetra-ferriphlogopite (a). The spectrum is displayed as a plot of electron binding energy vs . intensity (the number of electrons per second in a fixed and small energy interval). The Fe 3+ and Fe 2+ multiplet peaks are labeled
Image
K2p spectra of tetra-ferriphlogopite (a) and Fe-bearing phlogopite (b) displayed as a plot of electron binding energy vs. intensity (the number of electrons per second in a fixed and small energy interval). Dotted lines: experimental spectra; solid lines: deconvoluted peaks. See text for additional explanations.
Published: 01 August 2014
Figure 5 K 2p spectra of tetra-ferriphlogopite (a) and Fe-bearing phlogopite (b) displayed as a plot of electron binding energy vs . intensity (the number of electrons per second in a fixed and small energy interval). Dotted lines: experimental spectra; solid lines: deconvoluted peaks. See text
Image
Angle-dependent K K-XANES spectra recorded on tetra-ferriphlogopite Tas22-1 (Tapira, Minas Gerais, Brazil) at various 𝛉 angles (inset: enlargement of the FMS to IMS section for two extreme rotations).
Published: 01 July 2006
F igure 3. Angle-dependent K K -XANES spectra recorded on tetra-ferriphlogopite Tas22-1 (Tapira, Minas Gerais, Brazil) at various 𝛉 angles (inset: enlargement of the FMS to IMS section for two extreme rotations).
Image
Fe K-edge XAS spectra of studied ferroan phlogopite PBA90-94 compared with tetra-ferriphlogopite and annite.
Published: 01 October 2008
F ig . 2. Fe K -edge XAS spectra of studied ferroan phlogopite PBA90-94 compared with tetra-ferriphlogopite and annite.
Image
Changes in a Tapira tetra-ferriphlogopite Si K-edge spectrum due to changing the orientation of the same crystal blade against the impinging, horizontally-polarized synchrotron radiation beam. In the right panel a magnified view of the changes undergone by the edge and FMS regions.
Published: 01 January 2002
Figure 11. Changes in a Tapira tetra-ferriphlogopite Si K- edge spectrum due to changing the orientation of the same crystal blade against the impinging, horizontally-polarized synchrotron radiation beam. In the right panel a magnified view of the changes undergone by the edge and FMS regions.