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dioptase

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Journal Article
Published: 01 April 1996
European Journal of Mineralogy (1996) 8 (2): 301–310.
Journal Article
Published: 01 August 1977
American Mineralogist (1977) 62 (7-8): 807–811.
...P. H. Ribbe; G. V. Gibbs; M. M. Hamil Abstract The crystal structure of dioptase, Cu 6 [Si e O 18 ]-6H 2 0 ( a = 14.566, с = 7.778 A, R 3 ), was refined to R = 0.039 using 969 non-zero reflections. The structure consists of puckered trigonal rings of six water molecules with an ice-like...
Journal Article
Published: 01 October 1940
American Mineralogist (1940) 25 (10): 708–710.
...F. W. Galbraith; Truman H. Kuhn Abstract Dioptase (H 2 CuSiO 4 ), a mineral of comparatively rare occurrence in the United States and previously described from only a few localities in Arizona, 1,2,3,4 was recently discovered in considerable quantity at the Mammoth Mine of the Mammoth-St. Anthony...
Image
29Si NMR spectra for dioptase and dehydrated dioptase, with spinning speeds labeled. The offset of the peak from 20 to 10 kHz (arrow) is caused by a reduction in temperature of about 26 °C at the lower spinning speed. The complex MAS peak shapes for the hydrated sample may be due in part to non-uniform temperature in the rotor. Note that the frequency scale is expanded relative to that in Figure 1.
Published: 01 December 2017
Figure 2. 29 Si NMR spectra for dioptase and dehydrated dioptase, with spinning speeds labeled. The offset of the peak from 20 to 10 kHz (arrow) is caused by a reduction in temperature of about 26 °C at the lower spinning speed. The complex MAS peak shapes for the hydrated sample may be due
Journal Article
Published: 01 May 1917
American Mineralogist (1917) 2 (5): 57–62.
...Arthur P. Honess Abstract Several minerals of the hexagonal-alternating type have been investigated with reference to etch figures. Traube 1 obtained distinct figures on the negative rhombohedron of the first order of dioptase with KOH. These are triangular in outline, with the three sides unequal...
Journal Article
Published: 01 December 2017
American Mineralogist (2017) 102 (12): 2406–2414.
...Figure 2. 29 Si NMR spectra for dioptase and dehydrated dioptase, with spinning speeds labeled. The offset of the peak from 20 to 10 kHz (arrow) is caused by a reduction in temperature of about 26 °C at the lower spinning speed. The complex MAS peak shapes for the hydrated sample may be due...
FIGURES
First thumbnail for: Toward the wider application of 29 Si NMR spectros...
Second thumbnail for: Toward the wider application of 29 Si NMR spectros...
Third thumbnail for: Toward the wider application of 29 Si NMR spectros...
Journal Article
Published: 01 October 2014
Mineralogical Magazine (2014) 78 (5): 1325–1340.
... particularly with murdochite, but also with calcite, fluorite, hemimorphite and rarely dioptase in a highly siliceous hornfels. It forms bright bluish-green plates or flakes up to ~20 μm ×20 μm ×5 μm in size that are usually curved. The streak is pale bluish green and the lustre is adamantine, but often...
FIGURES
First thumbnail for: Bluebellite and mojaveite, two new minerals from t...
Second thumbnail for: Bluebellite and mojaveite, two new minerals from t...
Third thumbnail for: Bluebellite and mojaveite, two new minerals from t...
Journal Article
Published: 01 January 2000
American Mineralogist (2000) 85 (1): 118–132.
... also collected X-ray absorption fine structure (XAFS) data for several Cu 2+ -containing model compounds, including tenorite ( VI CuO), spertiniite [ VI Cu(OH) 2 ], dioptase ( VI CuSiO 2 ·H 2 O), shattuckite [ VI Cu 5 (SiO 3 ) 4 (OH) 2 ], chrysocolla [ VI (Cu,Al) 2 H 2 Si 2 O 5 (OH) 4 ·nH 2 O], and Cu...
FIGURES
First thumbnail for: XAFS study of Cu model compounds and Cu 2+ sorptio...
Second thumbnail for: XAFS study of Cu model compounds and Cu 2+ sorptio...
Third thumbnail for: XAFS study of Cu model compounds and Cu 2+ sorptio...
Journal Article
Published: 01 December 1974
American Mineralogist (1974) 59 (11-12): 1157–1159.
...W. John McLean; Richard A. Bideaux; Richard W. Thomssen Abstract Yedlinite is a new hydrated oxychloride of lead and chromium found associated with diaboleite, quartz, wulfenite, dioptase, phosgenite, and wherryite on specimens from the Mammoth Mine, Tiger, Arizona. Yedlinite occurs as prismatic...
Journal Article
Published: 01 October 1955
American Mineralogist (1955) 40 (9-10): 905–906.
... 0.05, and insoluble 1.11, yields the formula Cu 6 PbO 8 . The specific gravity is 6.47 at 4° C. The mineral forms in tiny lustrous black octahedra associated with wulfenite, dioptase, willemite, and fluorite. The new mineral was found by Percy W. Porter, now deceased, of Cavecreek, Ariz., and at his...
Journal Article
Published: 01 January 2010
American Mineralogist (2010) 95 (1): 171–176.
... counterpart, the mineral dioptase, Cu 6 Si 6 O 18 ·6H 2 O, or between the Cu polygermanate CuGeO 3 and synthetic germanate dioptase, Cu 6 Ge 6 O 18 ·6H 2 O. The compounds CuSiO 3 and CuGeO 3 , known as spin-Peierls phases, have been recently identified as isostructural with theoparacelsite ( Otto...
FIGURES
First thumbnail for: Lapeyreite, Cu 3 O[AsO 3 (OH)] 2 ·0.75H 2 O, a new...
Second thumbnail for: Lapeyreite, Cu 3 O[AsO 3 (OH)] 2 ·0.75H 2 O, a new...
Third thumbnail for: Lapeyreite, Cu 3 O[AsO 3 (OH)] 2 ·0.75H 2 O, a new...
Image
(see Fig. 18 and associated text in Chapter 14) Examples of secondary arsenate mineral assemblages from Tsumeb. (a) Bayldonite and arsentsumebite on azurite, Scale bar = 1 cm. (b) Olivenite on cuprian adamite, Scale bar = 2.5 cm. (c) Balydonite psuedomorphs of mimetite. Scale bar = 1.5 cm. (d) Keyite, Level Scale bar = 0.3 mm. (e) Olivenite with gartrellite. Scale bar = 1 cm. (f) Conichalcite, molbdofornacite with dioptase. Scale bar = 1 cm. (g) Legrandite on matrix. Scale bar = 1 mm. (h) Mimetite. Scale bar = 1 cm.
Published: 01 January 2014
= 1.5 cm. (d) Keyite, Level Scale bar = 0.3 mm. (e) Olivenite with gartrellite. Scale bar = 1 cm. (f) Conichalcite, molbdofornacite with dioptase. Scale bar = 1 cm. (g) Legrandite on matrix. Scale bar = 1 mm. (h) Mimetite. Scale bar = 1 cm.
Image
29Si MAS NMR spectra for copper silicates (Table 1). Peaks labeled “A” and “B” are for Si sites in the main phase; “C” may be from a Ca-silicate impurity; “D” may be due to an unknown diamagnetic impurity. “*” marks spinning sidebands. The entire known range of chemical shifts for SiO4 groups in diamagnetic silicates lies between the two dashed lines. Data shown for cuprorivaite were collected with an echo delay of 50 μs; for others with 100 μs. For planchéite and shattuckite, spectra shown were collected with transmitter frequency centered between two main peaks; for cuprorivaite and dioptase the transmitter frequency was centered on the single main peak.
Published: 01 December 2017
; for cuprorivaite and dioptase the transmitter frequency was centered on the single main peak.
Image
(a) Typical Cu polyhedron with four equatorial O atoms and two axial O atoms, (b) to (d) schematic illustrations of coordination environment (up to ≈ 3.5 Å) of Cu2+ model compounds: (b) CuO, (c) Cu(OH)2, and (d) dioptase. Dark gray spheres indicate Cu atoms, light gray spheres indicate oxygen atoms, small black spheres indicate hydrogen atoms; the tetrahedra in (d) are silicon tetrahedra. The atomic distances (in Å) from a central Cu atom are given next to the atoms; the distance information inside the tetrahedra is the distance to the silicon atom. For clarity, not all Cu second neighbors are shown in (c) and (d).
Published: 01 January 2000
F igure 3. ( a ) Typical Cu polyhedron with four equatorial O atoms and two axial O atoms, ( b ) to ( d ) schematic illustrations of coordination environment (up to ≈ 3.5 Å) of Cu 2+ model compounds: ( b ) CuO, ( c ) Cu(OH) 2 , and ( d ) dioptase. Dark gray spheres indicate Cu atoms, light
Journal Article
Published: 03 February 2025
Geochemistry: Exploration, Environment, Analysis (2024) 24 (4): geochem2024-031.
..., mica mineral, illite N-13 Gmelinite–Na, kaoliniteWX, goethite Quartz, montmorillonite, alkali feldspar, illite–montmorillonite, magnetite, kaolinite, hematite, mica mineral, illite O-5 Goethite, gmelinite–Na, halloysite Dioptase Quartz, montmorillonite, kaolinite, alkali feldspar...
FIGURES
First thumbnail for: Alteration and mineralization features of the Akca...
Second thumbnail for: Alteration and mineralization features of the Akca...
Third thumbnail for: Alteration and mineralization features of the Akca...
Journal Article
Journal: Interpretation
Published: 30 June 2021
Interpretation (2021) 9 (3): T711–T726.
... not drilled deep enough to ascertain and correlate the tripolite occurrence. Characteristic red staining was observed on a core of chat in wells G, H, and I ( Liner, 2015 ), and probably in well D. XRF analysis of these red stains in well I shows the presence of 2% dickite, 25% dioptase, 36% kaolinite...
FIGURES
First thumbnail for: Mississippian chat and tripolite zones in Osage Co...
Second thumbnail for: Mississippian chat and tripolite zones in Osage Co...
Third thumbnail for: Mississippian chat and tripolite zones in Osage Co...
Image
(for color see Plate 19) Examples of secondary arsenate mineral assemblages from Tsumeb. (a) Bayldonite and arsentsumebite on azurite, Level 8 “Easter Pocket,” first oxidation zone. Scale bar = 1 cm. (b) Olivenite on cuprian adamite, Level 10 Stope 15W, first oxidation zone. Scale bar = 2.5 cm. (c) Balydonite psuedomorphs of mimetite, first oxidation zone. Scale bar = 1.5 cm. (d) Keyite, second oxidation zone, Level 28 Stope 10E. Scale bar = 0.3 mm. (e) Olivenite with gartrellite, second oxidation zone. Scale bar = 1 cm. (f) Conichalcite, molbdofornacite with dioptase, second oxidation zone. Level 30 Stope 10W. Scale bar = 1 cm. (g) Legrandite on matrix, third oxidation zone. Scale bar = 1 mm. (h) Mimetite, “Gem pocket,” second oxidation zone, Level 34. Scale bar = 1 cm.
Published: 01 January 2014
= 2.5 cm. (c) Balydonite psuedomorphs of mimetite, first oxidation zone. Scale bar = 1.5 cm. (d) Keyite, second oxidation zone, Level 28 Stope 10E. Scale bar = 0.3 mm. (e) Olivenite with gartrellite, second oxidation zone. Scale bar = 1 cm. (f) Conichalcite, molbdofornacite with dioptase, second
Journal Article
Published: 01 January 2014
Reviews in Mineralogy and Geochemistry (2014) 79 (1): CP1–CP16.
... = 1.5 cm. (d) Keyite, Level Scale bar = 0.3 mm. (e) Olivenite with gartrellite. Scale bar = 1 cm. (f) Conichalcite, molbdofornacite with dioptase. Scale bar = 1 cm. (g) Legrandite on matrix. Scale bar = 1 mm. (h) Mimetite. Scale bar = 1 cm. ...
FIGURES
First thumbnail for: Arsenic ― Color Plates
Second thumbnail for: Arsenic ― Color Plates
Third thumbnail for: Arsenic ― Color Plates
Journal Article
Published: 01 May 2001
European Journal of Mineralogy (2001) 13 (3): 507–519.
... interaction. Note that the libration modes of H 2 O in dioptase were observed at 613 and 732 cm −1 ( Goryainov, 1996 ); such values are close to the corresponding modes in natrolite ( Table 3 ). For the M-1 model the diagonal force constants are K (Al-O) = 3.2 mdyn/Å, K (O-Si-O) = 0.89 mdyn·Å, K (O...
FIGURES
First thumbnail for: Raman spectra and lattice-dynamical calculations o...
Second thumbnail for: Raman spectra and lattice-dynamical calculations o...
Third thumbnail for: Raman spectra and lattice-dynamical calculations o...
Journal Article
Published: 01 January 2010
American Mineralogist (2010) 95 (1): 185–187.
... daphnite not listed Dat datolite G Dbr daubreelite G Dee deerite A Dia diamond G Dsp diaspore G Dck dickite G Dg digenite A Di diopside A Dpt dioptase G Dol dolomite G Drv dravite G Dum dumortierite G Eas eastonite Rd Ec ecandrewsite...