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darrellhenryite

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Journal Article

Darrellhenryite, Na(LiAl 2 )Al 6 (BO 3 ) 3 Si 6 O 18 (OH) 3 O, a new mineral from the tourmaline supergroup

Milan Novák, Andreas Ertl, Pavel Povondra, Michaela Vašinová Galiová, George R. Rossman, Helmut Pristacz, Markus Prem, Gerald Giester, Petr Gadas, Radek Škoda
Published: 01 October 2013
American Mineralogist (2013) 98 (10): 1886–1892.
DOI: https://doi.org/10.2138/am.2013.4416
...Milan Novák; Andreas Ertl; Pavel Povondra; Michaela Vašinová Galiová; George R. Rossman; Helmut Pristacz; Markus Prem; Gerald Giester; Petr Gadas; Radek Škoda Abstract Darrellhenryite, Na(LiAl 2 )Al 6 (BO 3 ) 3 Si 6 O 18 (OH) 3 O, a new member of the tourmaline supergroup (related to the alkali...
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Chemical composition of tourmalines from the Nová Ves pegmatite. Open circles = EMPA data; solid symbols = wet chemical analyses (Povondra et al. 1985); square = black oxy-schorl; triangle = green Fe-rich fluor-elbaite; circles = pink darrellhenryite to darrellhenryite = fluor-elbaite; star = type material data (Table 2, analysis no. 2).

Chemical composition of tourmalines from the Nová Ves pegmatite. Open circl...

Published: 01 October 2013
Figure 3 Chemical composition of tourmalines from the Nová Ves pegmatite. Open circles = EMPA data; solid symbols = wet chemical analyses ( Povondra et al. 1985 ); square = black oxy-schorl; triangle = green Fe-rich fluor-elbaite; circles = pink darrellhenryite to darrellhenryite = fluor-elbaite
Journal Article

Iron-bearing to iron-rich tourmalines from granitic pegmatites of the Murzinka pluton, Central Urals, Russia

Tatiana A. Gvozdenko, Ivan A. Baksheev, Dmitry A. Khanin, Mikhail V. Voronin, Maria V. Chervyakovskaya, Vadim V. Smolensky
Published: 26 August 2022
Mineralogical Magazine (2022) 86 (6): 948–965.
DOI: https://doi.org/10.1180/mgm.2022.104
... pluton, Central Urals, Russia have been investigated using electron microprobe analysis, LA-ICP-MS, Raman and Mössbauer spectroscopy. Pegmatites are hosted by serpentinites and gneisses and are classified as schorl, oxy-schorl, fluor-schorl, dravite, oxy-dravite, foitite, oxy-foitite and darrellhenryite...
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View PDF for article title, Iron-bearing to iron-rich tourmalines from granitic pegmatites of the Murzinka pluton, Central Urals, Russia
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Comparative data for princivalleite, oxy-schorl and darrellhenryite. ...

Published: 14 January 2022
Table 9. Comparative data for princivalleite, oxy-schorl and darrellhenryite. Princivalleite a Oxy-schorl b Darrellhenryite c a (Å) 15.9155(2) 15.916(3) 15.809(2) c (Å) 7.1166(1) 7.107(1) 7.089(1) V (Å 3 ) 1561.15(4) 1559.1(4) 1534.4(4) Space group
Image
Near-IR spectrum of darrellhenryite (sample grr3075). (Color online.)

Near-IR spectrum of darrellhenryite (sample grr3075). (Color online.)

Published: 01 October 2013
Figure 2 Near-IR spectrum of darrellhenryite (sample grr3075). (Color online.)
Journal Article

Princivalleite, Na(Mn 2 Al)Al 6 (Si 6 O 18 )(BO 3 ) 3 (OH) 3 O, a new mineral species of the tourmaline supergroup from Veddasca Valley, Varese, Italy

Ferdinando Bosi, Federico Pezzotta, Henrik Skogby, Alessandra Altieri, Ulf Hålenius, Gioacchino Tempesta, Jan Cempírek
Published: 14 January 2022
Mineralogical Magazine (2022) 86 (1): 78–86.
DOI: https://doi.org/10.1180/mgm.2022.3
...Table 9. Comparative data for princivalleite, oxy-schorl and darrellhenryite. Princivalleite a Oxy-schorl b Darrellhenryite c a (Å) 15.9155(2) 15.916(3) 15.809(2) c (Å) 7.1166(1) 7.107(1) 7.089(1) V (Å 3 ) 1561.15(4) 1559.1(4) 1534.4(4) Space group...
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Total Al vs. Li in Al-rich tourmaline end-members. Note: a = Olenite; b = Darrellhenryite; c = Elbaite, fluor-elbaite; d = Fluorliddicoatite. Measured samples: PINK1 = Alumino-oxy-rossmanite (type material); PINK2 = Pink tourmaline with a major alumino-oxyrossmanite component.

Total Al vs. Li in Al-rich tourmaline end-members. Note: a = Olenite; b = D...

Published: 01 February 2022
Figure 7. Total Al vs. Li in Al-rich tourmaline end-members. Note: a = Olenite; b = Darrellhenryite; c = Elbaite, fluor-elbaite; d = Fluorliddicoatite. Measured samples: PINK1 = Alumino-oxy-rossmanite (type material); PINK2 = Pink tourmaline with a major alumino-oxyrossmanite component.
Image
Total Al vs. Si in different Al-rich tourmaline end-members. Note: a = Olenite; b = Darrellhenryite; c = Elbaite, fluorelbaite; d = Fluor-liddicoatite. Measured samples: PINK1 = Aluminooxy-rossmanite (type material); PINK2 = Pink tourmaline with a major alumino-oxy-rossmanite component.

Total Al vs. Si in different Al-rich tourmaline end-members. Note: a = Olen...

Published: 01 February 2022
Figure 6. Total Al vs. Si in different Al-rich tourmaline end-members. Note: a = Olenite; b = Darrellhenryite; c = Elbaite, fluorelbaite; d = Fluor-liddicoatite. Measured samples: PINK1 = Aluminooxy-rossmanite (type material); PINK2 = Pink tourmaline with a major alumino-oxy-rossmanite component.
Journal Article

Tourmaline as a petrogenetic monitor of the origin and evolution of the Berry-Havey pegmatite (Maine, U.S.A.)

Encarnación Roda-Robles, William Simmons, Alfonso Pesquera, Pedro P. Gil-Crespo, James Nizamoff, José Torres-Ruiz
Published: 01 January 2015
American Mineralogist (2015) 100 (1): 95–109.
DOI: https://doi.org/10.2138/am-2015-4829
... of the core zone, this exchange vector combined with the substitution ([X] Y Al 0.5 X Na −1 Y Li −0.5 ). Finally, the gemmy tourmalines from the pockets show a deprotonation related to the exchange vector Y Al W O 2 Y Li −1 W (OH) −2 and may be classified as darrellhenryite. These substitutions may reflect...
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View PDF for article title, Tourmaline as a petrogenetic monitor of the origin and evolution of the Berry-Havey pegmatite (Maine, U.S.A.)
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Representative Raman frequencies of tourmaline species. Notes: (1) Sa...

Published: 26 August 2022
-foitite, Ministerskaya; (7) Sample 85, foitite, Zheltyye Yamy; and (8) Sample 42, darrellhenryite, Ministerskaya. Fe* = (Fe 2+  + Mn 2+ ). Assignments are given according to Watenphul et al. ( 2016a , 2016b ).
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(a) The instrumental mass fractionation (IMF) is a linear function of Fe (apfu) and Altot (apfu). This is illustrated in the excellent correlation in measured vs. calculated IMF obtained for an individual SIMS session (see text for further explanations). (b) Illustration of the variation of IMF with chemical parameters: Fe (apfu) (solid solution dravite-schorl) and Altot (apfu) (solid solution schorl-elbaite-darrellhenryite). Note that the effect on IMF of Fe-Mg exchange is larger than the Al1Li1-Fe2 exchange. Error bars are uncertainties of the IMF (sIMF) determined as described in the text. Black squares represent end-member compositions.

( a ) The instrumental mass fractionation (IMF) is a linear function of Fe ...

Published: 01 October 2019
of the variation of IMF with chemical parameters: Fe (apfu) (solid solution dravite-schorl) and Al tot (apfu) (solid solution schorl-elbaite-darrellhenryite). Note that the effect on IMF of Fe-Mg exchange is larger than the Al 1 Li 1 -Fe 2 exchange. Error bars are uncertainties of the IMF (s IMF ) determined
Image
Positions of the VOH stretching modes related to 3YLiZAlZAl (circles), 2YLiZAlZAl-YAlZAlZAl (squares), and YLiZAlZAl-2YAlZAlZAl (diamonds) of elbaite (orange), fluor-liddicoatite (light blue), and darrellhenryite (yellow) vs. the content of (a) X(Na+Ca) per formula unit and (b) XNa/X(Na+Ca) obtained from EPMA. Data points with red contours are excluded from fitting (see text). Linear fits are given by gray lines. (Color online.)

Positions of the V OH stretching modes related to 3 Y Li Z Al Z Al (circle...

Published: 01 April 2016
Figure 11 Positions of the V OH stretching modes related to 3 Y Li Z Al Z Al (circles), 2 Y Li Z Al Z Al- Y Al Z Al Z Al (squares), and Y Li Z Al Z Al-2 Y Al Z Al Z Al (diamonds) of elbaite (orange), fluor-liddicoatite (light blue), and darrellhenryite (yellow) vs. the content of ( a ) X (Na
Journal Article

Exploring the potential of Raman spectroscopy for crystallochemical analyses of complex hydrous silicates: II. Tourmalines

Anke Watenphul, Martina Burgdorf, Jochen Schlüter, Ingo Horn, Thomas Malcherek, Boriana Mihailova
Published: 01 April 2016
American Mineralogist (2016) 101 (4): 970–985.
DOI: https://doi.org/10.2138/am-2016-5530
...Figure 11 Positions of the V OH stretching modes related to 3 Y Li Z Al Z Al (circles), 2 Y Li Z Al Z Al- Y Al Z Al Z Al (squares), and Y Li Z Al Z Al-2 Y Al Z Al Z Al (diamonds) of elbaite (orange), fluor-liddicoatite (light blue), and darrellhenryite (yellow) vs. the content of ( a ) X (Na...
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Representative EMPA compositions of tourmalines. Notes: (1) Sample 75...

Published: 26 August 2022
Table 1. Representative EMPA compositions of tourmalines. Notes: (1) Sample 75, oxy-foitite, Ministerskaya; (2) Sample 42, darrellhenryite, Ministerskaya; (3) Sample 71, oxy-schorl, Mokrusha; (4) Sample 79, oxy-schorl, Golodnaya; (5) Sample 90, oxy-schorl, Kopi Mora; (6) Sample 87, oxy
Journal Article

Fluor-rossmanite, □(Al 2 Li)Al 6 (Si 6 O 18 )(BO 3 ) 3 (OH) 3 F, a new tourmaline supergroup mineral from Malkhan pegmatite field, Western Siberia, Russia

Anatoly V. Kasatkin, Fabrizio Nestola, Maxwell C. Day, Liudmila A. Gorelova, Radek Škoda, Oleg S. Vereshchagin, Atali A. Agakhanov, Dmitriy I. Belakovskiy, Martha G. Pamato, Jan Cempírek, Mikhail Yu. Anosov
Published: 01 December 2024
Mineralogical Magazine (2024) 88 (6): 668–676.
DOI: https://doi.org/10.1180/mgm.2024.34
... of darrellhenryite. This zone is surrounded by a Mn-poor, light pink zone composed mainly of fluor-rossmanite as described here. This zone also includes local chemical compositions corresponding to rossmanite and its oxy-analogue, another potentially new tourmaline species with the end-member formula □(Li 0.5 Al 2.5...
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View PDF for article title, Fluor-rossmanite, □(Al 2 Li)Al 6 (Si 6 O 18 )(BO 3 ) 3 (OH) 3 F, a new tourmaline supergroup mineral from Malkhan pegmatite field, Western Siberia, Russia
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Journal Article

Alumino-oxy-rossmanite from pegmatites in Variscan metamorphic rocks from Eibenstein an der Thaya, Lower Austria, Austria: A new tourmaline that represents the most Al-rich end-member composition

Andreas Ertl, John M. Hughes, Stefan Prowatke, Thomas Ludwig, Christian L. Lengauer, Hans-Peter Meyer, Gerald Giester, Uwe Kolitsch, Albert Prayer
Published: 01 February 2022
American Mineralogist (2022) 107 (2): 157–166.
DOI: https://doi.org/10.2138/am-2022-8047
...Figure 7. Total Al vs. Li in Al-rich tourmaline end-members. Note: a = Olenite; b = Darrellhenryite; c = Elbaite, fluor-elbaite; d = Fluorliddicoatite. Measured samples: PINK1 = Alumino-oxy-rossmanite (type material); PINK2 = Pink tourmaline with a major alumino-oxyrossmanite component. ...
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View PDF for article title, Alumino-oxy-rossmanite from pegmatites in Variscan metamorphic rocks from Eibenstein an der Thaya, Lower Austria, Austria: A new tourmaline that represents the most Al-rich end-member composition
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Journal Article

New minerals and nomenclature modifications approved in 2012

P. A. Williams, F. Hatert, M. Pasero, S. J. Mills
Published: 01 October 2012
Mineralogical Magazine (2012) 76 (5): 1281–1288.
DOI: https://doi.org/10.1180/minmag.2012.076.5.15
.... Wessels mine, Kalahari Manganese Fields, Northern Cape Province, Republic of South Africa Darrellhenryite NaLiAl 2 Al 6 (BO 3 ) 3 Si 6 O 18 (OH) 3 O Nová Ves, Český Krumlov, southern Bohemia, Czech Republic Milan Novák*, Andreas Ertl, Pavel Povondra, Michaela Vašinová Galiová, Helmut...
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Journal Article

Lucchesiite, CaFe 2+ 3 Al 6 (Si 6 O 18 )(BO 3 ) 3 (OH) 3 O, a new mineral species of the tourmaline supergroup

Ferdinando Bosi, Henrik Skogby, Marco E. Ciriotti, Petr Gadas, Milan Novák, Jan Cempírek, Dalibor Všianský, Jan Filip
Published: 01 February 2017
Mineralogical Magazine (2017) 81 (1): 1–14.
DOI: https://doi.org/10.1180/minmag.2016.080.067
.... (2014 a ) Vanadio-oxy-chromium-dravite NaV 3 (Cr 4 Mg 2 )(Si 6 O 18 )(BO 3 ) 3 (OH) 3 O Bosi et al. (2014 b ) Chromo-alumino-povondraite NaCr 3 (Al 4 Mg 2 )(Si 6 O 18 )(BO 3 ) 3 (OH) 3 O Reznitskii et al. (2014) Darrellhenryite Na(LiAl 2 )Al 6 (Si 6 O 18 )(BO 3 ) 3 (OH) 3 O Novák...
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Journal Article

A Tribute To Milan Novák

Radek Škoda, Pietro Vignola, Axel Müller, Lee A. Groat
Published: 23 October 2018
The Canadian Mineralogist (2018) 56 (4): 357–363.
DOI: https://doi.org/10.3749/canmin.INT007
..., G.R., Pristacz, H., Prem, M., Giester, G., Gadas, P., & Škoda, R. (2013a) Darrellhenryite, Na(LiAl 2...
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Journal Article

Mn-bearing purplish-red tourmaline from the Anjanabonoina pegmatite, Madagascar

Ferdinando Bosi, Beatrice Celata, Henrik Skogby, Ulf Hålenius, Gioacchino Tempesta, Marco E. Ciriotti, Erica Bittarello, Alessandra Marengo
Published: 01 March 2021
Mineralogical Magazine (2021) 85 (2): 242–253.
DOI: https://doi.org/10.1180/mgm.2021.20
... by the chemical substitution O1 F – → O1 (OH) – or the deprotonation process O1 (OH) – + ¼ O 2 (g) → O1 O 2– + ½ H 2 O(g), both of which would favour the occurrence of fluor-liddicoatite and darrellhenryite type arrangements ( YYY )– O1 (O,F)– X (Na,Ca). Fig. 10. Simplified structure...
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