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![The crystal structures of mendipite (a) and damaraite (b) projected along the b and a axes, respectively. Legend as in Fig. 1.]()
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![Coordination of Pb atoms in mendipite and damaraite. Legend: Pb - small dark circles, Cl - large dark circles, O - large light circles.]()
![Sheets of [O2Pb3] chains of (OPb4) tetrahedra and OH groups in damaraite (a), Pb6O4(OH)(CO3)(NO3) (b) and Pb3O2(OH)(NO3) (c).]()
![Oxo/hydroxocentred units in the structures of Pb oxy- and hydroxy-halide minerals and synthetic compounds: (a) Pb2O(OH)I (OPb4 tetrahedra = red, OHPb3 triangles = blue), (b) sidpietersite, (c) penfieldite and (d) damaraite.]()
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![The arrangement of [O2Pb3]2+ chains in lead oxychloride minerals and inorganic compounds. (a) The quincunx arrangement in Pb7O4(OH)4X2 (X = Cl, Br). (b) Shifted [O2Pb3]2+ chains in chloroxiphite. (c) The parallel arrangement in rickturnerite. (d) The mutually perpendicular arrangement in mendipite. (e) The zigzag arrangement in damaraite.]()
![[O2Pb3] double chain of (OPb4) oxocentered tetrahedra shown in ball-and-stick (a) and polyhedral (b) representations. Connectivity diagrams for (OPb4) tetrahedra in mendipite (c) and damaraite (d, e) with O-Pb distances written near the corners, and usual OPb distances for such a tetrahedron in Pb oxide salts (f). The edges identified by semibold lines are common to two adjacent tetrahedra, whereas the corners designated by circles link the tetrahedron to another.]()
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Journal Article
Crystal chemistry of lead oxide chlorides. I. Crystal structures of synthetic mendipite, Pb 3 O 2 Cl 2 , and synthetic damaraite, Pb 3 O 2 (OH)Cl Available to Purchase
Journal: European Journal of Mineralogy
Publisher: GeoScienceWorld Journals
Published: 01 July 2001
European Journal of Mineralogy (2001) 13 (4): 801–809.
...Sergey V. KRIVOVICHEV; Peter C. BURNS Abstract The crystal structure of synthetic damaraite, Pb 3 O 2 (OH)Cl (orthorhombic, Pmc2 1 , a = 5.8052(7), b = 6.9025(8), c = 15.141(2) Å, V = 606.7(1) Å 3 has been solved by direct methods and refined to R1 = 0.039. The crystal structure of synthetic...
FIGURES
Image
Comparison of results of EMP analyses of damaraite specimens obtained by C... Available to Purchase
in Crystal chemistry of lead oxide chlorides. I. Crystal structures of synthetic mendipite, Pb 3 O 2 Cl 2 , and synthetic damaraite, Pb 3 O 2 (OH)Cl
> European Journal of Mineralogy
Published: 01 July 2001
Table 7. Comparison of results of EMP analyses of damaraite specimens obtained by Criddle et al. (1990) with chemical composition of synthetic damaraite.
Image
Crystallographic data for synthetic mendipite and damaraite. Available to Purchase
in Crystal chemistry of lead oxide chlorides. I. Crystal structures of synthetic mendipite, Pb 3 O 2 Cl 2 , and synthetic damaraite, Pb 3 O 2 (OH)Cl
> European Journal of Mineralogy
Published: 01 July 2001
Table 1. Crystallographic data for synthetic mendipite and damaraite.
Image
Bond valence sums for Pb and O atoms in structures of synthetic mendipite a... Available to Purchase
in Crystal chemistry of lead oxide chlorides. I. Crystal structures of synthetic mendipite, Pb 3 O 2 Cl 2 , and synthetic damaraite, Pb 3 O 2 (OH)Cl
> European Journal of Mineralogy
Published: 01 July 2001
Table 6. Bond valence sums for Pb and O atoms in structures of synthetic mendipite and damaraite.
Image
Selected interatomic distances (Å) for synthetic damaraite, Pb 3 O 2 C1 2 ... Available to Purchase
in Crystal chemistry of lead oxide chlorides. I. Crystal structures of synthetic mendipite, Pb 3 O 2 Cl 2 , and synthetic damaraite, Pb 3 O 2 (OH)Cl
> European Journal of Mineralogy
Published: 01 July 2001
Table 5. Selected interatomic distances (Å) for synthetic damaraite, Pb 3 O 2 C1 2 .
Image
The crystal structures of mendipite (a) and damaraite (b) projected along t... Available to Purchase
in Crystal chemistry of lead oxide chlorides. I. Crystal structures of synthetic mendipite, Pb 3 O 2 Cl 2 , and synthetic damaraite, Pb 3 O 2 (OH)Cl
> European Journal of Mineralogy
Published: 01 July 2001
Fig. 3. The crystal structures of mendipite (a) and damaraite (b) projected along the b and a axes, respectively. Legend as in Fig. 1 .
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Atomic coordinates and displacement parameters (Å 2 × 10 3 ) for syntheti... Available to Purchase
in Crystal chemistry of lead oxide chlorides. I. Crystal structures of synthetic mendipite, Pb 3 O 2 Cl 2 , and synthetic damaraite, Pb 3 O 2 (OH)Cl
> European Journal of Mineralogy
Published: 01 July 2001
Table 3. Atomic coordinates and displacement parameters (Å 2 × 10 3 ) for synthetic damaraite, Pb 3 O 2 (OH)Cl.
Image
Coordination of Pb atoms in mendipite and damaraite. Legend: Pb - small dar... Available to Purchase
in Crystal chemistry of lead oxide chlorides. I. Crystal structures of synthetic mendipite, Pb 3 O 2 Cl 2 , and synthetic damaraite, Pb 3 O 2 (OH)Cl
> European Journal of Mineralogy
Published: 01 July 2001
Fig. 1. Coordination of Pb atoms in mendipite and damaraite. Legend: Pb - small dark circles, Cl - large dark circles, O - large light circles.
Image
![Sheets of [O2Pb3] chains of (OPb4) tetrahedra and OH groups in damaraite (a), Pb6O4(OH)(CO3)(NO3) (b) and Pb3O2(OH)(NO3) (c).](https://gsw.silverchair-cdn.com/gsw/Content_public/Journal/eurjmin/13/4/10.1127_0935-1221_2001_0013-0801/3/s_801fig4.jpeg?Expires=2147483647&Signature=Tyr7DH8tdUc5LYQZtbYV7Pf4JNgqN5yAOYwRakfP1HoOVAcrJU5vJG-BYYOOqmGh7bpf5UcUVwS3DNKzps4Hle0yLZC3qcRy~b1M0ulsdCqQ40llmkoO~XS7atbmXG~ODjHRVEefgLljdX3Xmm6WVdxI-h5x54iqzTO1TSj4-y~DhBgWdvvKOpgR93W1q-mw~5j4NUdGMAyumkGMWSgojez9xECo1sIdPdGAzHQI4UxXG~rSi3hoEfCTWA1weUStZDtfA73tcYyhipslZxnlpedSqPezYLen3rRoCIt8L0NqWxbvbERwFQSHqrcS38UC~4OVRfSozauHQLEgZiZGCA__&Key-Pair-Id=APKAIE5G5CRDK6RD3PGA)
Sheets of [O 2 Pb 3 ] chains of (OPb 4 ) tetrahedra and OH groups in damara... Available to Purchase
in Crystal chemistry of lead oxide chlorides. I. Crystal structures of synthetic mendipite, Pb 3 O 2 Cl 2 , and synthetic damaraite, Pb 3 O 2 (OH)Cl
> European Journal of Mineralogy
Published: 01 July 2001
Fig. 4. Sheets of [O 2 Pb 3 ] chains of (OPb 4 ) tetrahedra and OH groups in damaraite (a), Pb 6 O 4 (OH)(CO 3 )(NO 3 ) (b) and Pb 3 O 2 (OH)(NO 3 ) (c).
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Oxo/hydroxocentred units in the structures of Pb oxy- and hydroxy-halide mi... Available to Purchase
in Crystal structure of a novel synthetic compound, Pb 2 O(OH)I, and structure refinement of ‘iodolaurionite’, Pb(OH)I: hydroxo- and oxocentred units in Pb minerals and synthetic compounds
> Mineralogical Magazine
Published: 01 December 2013
F ig . 5. Oxo/hydroxocentred units in the structures of Pb oxy- and hydroxy-halide minerals and synthetic compounds: ( a ) Pb 2 O(OH)I (OPb 4 tetrahedra = red, OHPb 3 triangles = blue), ( b ) sidpietersite, ( c ) penfieldite and ( d ) damaraite.
Journal Article
Hereroite and vladkrivovichevite: two novel lead oxychlorides from the Kombat mine, Namibia Available to Purchase
Journal: Mineralogical Magazine
Published: 01 August 2012
Mineralogical Magazine (2012) 76 (4): 883–890.
..., damaraite, kombatite, sahlinite, copper, quartz, barysilite, Mn silicates and a number of Mn oxyhydroxide minerals on a specimen from the Kombat mine in Namibia. The minerals formed as late-stage products of hydrothermal reworking of primary sulfide minerals. Hereroite is monoclinic, C 2/ c with a = 23.14(1...
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Journal Article
Pb 2 (AsO 2 OH)Cl 2 , a new phase from the Lavrion ancient slags, Greece: occurrence and characterization Available to Purchase
Journal: Mineralogical Magazine
Published: 01 June 2012
Mineralogical Magazine (2012) 76 (3): 597–602.
... is closely related to that of Pb oxysalt minerals containing [O 2 Pb 3 ] 2+ chains of oxocentred [OPb 4 ] 6+ tetrahedra including mendipite, damaraite, rickturnerite and plumboselite. The infrared (IR) spectrum was collected using a double-beam technique. A sample was pulverized, mixed with anhydrous...
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![The arrangement of [O2Pb3]2+ chains in lead oxychloride minerals and inorganic compounds. (a) The quincunx arrangement in Pb7O4(OH)4X2 (X = Cl, Br). (b) Shifted [O2Pb3]2+ chains in chloroxiphite. (c) The parallel arrangement in rickturnerite. (d) The mutually perpendicular arrangement in mendipite. (e) The zigzag arrangement in damaraite.](https://gsw.silverchair-cdn.com/gsw/Content_public/Journal/minmag/76/1/10.1180_minmag.2012.076.1.59/5/s_05-rum-08.jpeg?Expires=2147483647&Signature=tE-U2OEG~HD-d8fspi~Je6NSlDkDvHlEPiOq4PdPFET8lF1nhvO7ppAfcbsGMQXpmKqlEsr8B0e-zt6Sc~u3wWawxImaUhqXLNLCAkfi9W1xrgjVKNqJ68xdAxtekRWW5EASHZ~~7KSiqXEJmC3lxmrf08bF05xMLhbltiM5mFdTFMUsns2qADvvF53bt9W1gyj4i2LjDGmYUi4TefgSAaxYICzGu-Nx7tAc7zUlM2Cq~Hq80m34UdUtMWRhyTwexR9uYFoRERQDgySkCnybCI6-fXwNSZ~fnrquIXOGEsjmwKf-0kKWQUBCG0yIlmOHj9HGjx4l8Pn2NlD6IKPpYA__&Key-Pair-Id=APKAIE5G5CRDK6RD3PGA)
The arrangement of [O 2 Pb 3 ] 2+ chains in lead oxychloride minerals and ... Available to Purchase
in Rickturnerite, Pb 7 O 4 [Mg(OH) 4 ](OH)Cl 3 , a complex new lead oxychloride mineral
> Mineralogical Magazine
Published: 01 February 2012
) The mutually perpendicular arrangement in mendipite. ( e ) The zigzag arrangement in damaraite.
Image
![[O2Pb3] double chain of (OPb4) oxocentered tetrahedra shown in ball-and-stick (a) and polyhedral (b) representations. Connectivity diagrams for (OPb4) tetrahedra in mendipite (c) and damaraite (d, e) with O-Pb distances written near the corners, and usual OPb distances for such a tetrahedron in Pb oxide salts (f). The edges identified by semibold lines are common to two adjacent tetrahedra, whereas the corners designated by circles link the tetrahedron to another.](https://gsw.silverchair-cdn.com/gsw/Content_public/Journal/eurjmin/13/4/10.1127_0935-1221_2001_0013-0801/3/s_801fig2.jpeg?Expires=2147483647&Signature=pZgGvRRxQ7Aav4qIDOXW5GjCBWZFgl7kKCUB8pl9~aqickYXPgIYxFSAml6Oh3spCq~OeNCN1URqauP8p4PD2FHTpiEcO9kWc57r7T6PH6svYL1gp3o-o~MNPwHdOSWXdWKMnYwLZmy~VIjewE9Oo6YkYb67M~keF5zt6612gQo~0cWyYw5chl7SqKcwoNc9a31OK1WndK7QWgWx3IDR3OMmquvbp5B9usGyynj6CAf~JixhxALFOx2ddvLJznDaAJuIXQO~M2eaS~GoI0dSe~F6bNONxvnYpkxiHPYBNmn0W1lctg3pXV-TT4~JYVlvwKXXIpN1jtZyKSyRX~QVPA__&Key-Pair-Id=APKAIE5G5CRDK6RD3PGA)
[O 2 Pb 3 ] double chain of (OPb 4 ) oxocentered tetrahedra shown in ball-a... Available to Purchase
in Crystal chemistry of lead oxide chlorides. I. Crystal structures of synthetic mendipite, Pb 3 O 2 Cl 2 , and synthetic damaraite, Pb 3 O 2 (OH)Cl
> European Journal of Mineralogy
Published: 01 July 2001
Fig. 2. [O 2 Pb 3 ] double chain of (OPb 4 ) oxocentered tetrahedra shown in ball-and-stick (a) and polyhedral (b) representations. Connectivity diagrams for (OPb 4 ) tetrahedra in mendipite (c) and damaraite (d, e) with O-Pb distances written near the corners, and usual OPb distances
Journal Article
Crystal chemistry of lead oxide chlorides. II. Crystal structure of Pb 7 O 4 (OH) 4 Cl 2 Available to Purchase
Journal: European Journal of Mineralogy
Publisher: GeoScienceWorld Journals
Published: 01 January 2002
European Journal of Mineralogy (2002) 14 (1): 135–139.
... ] double chains of (OPb 4 ) oxocentered tetrahedra [see Krivovichev & Burns (2001a) for more details]. Amongst lead oxide chlorides, these chains have been previously observed in damaraite and mendipite ( Keller et al. , 2000 , 2001 ; Pasero & Vacchiano, 2000 ; Krivovichev & Burns, 2001a...
FIGURES
Journal Article
Crystal structure of a novel synthetic compound, Pb 2 O(OH)I, and structure refinement of ‘iodolaurionite’, Pb(OH)I: hydroxo- and oxocentred units in Pb minerals and synthetic compounds Available to Purchase
Journal: Mineralogical Magazine
Published: 01 December 2013
Mineralogical Magazine (2013) 77 (8): 3239–3248.
...F ig . 5. Oxo/hydroxocentred units in the structures of Pb oxy- and hydroxy-halide minerals and synthetic compounds: ( a ) Pb 2 O(OH)I (OPb 4 tetrahedra = red, OHPb 3 triangles = blue), ( b ) sidpietersite, ( c ) penfieldite and ( d ) damaraite. ...
FIGURES
Journal Article
Chloroxiphite Pb 3 CuO 2 (OH) 2 Cl 2 : structure refinement and description in terms of oxocentred OPb 4 tetrahedra Available to Purchase
Journal: Mineralogical Magazine
Published: 01 June 2008
Mineralogical Magazine (2008) 72 (3): 793–798.
... a ). In mendipite ( Krivovichev and Burns, 2001 ; Siidra et al. , 2008 b ), the chains extend along the b axis. They have two mutually perpendicular orientations and are linked through weak Pb–Cl bonds only. In contrast, in damaraite, the [O 2 Pb 3 ] 2+ chains are linked through OH groups to form [Pb 3 O 2...
FIGURES
Journal Article
NEW MINERAL NAMES Available to Purchase
Journal: American Mineralogist
Publisher: Mineralogical Society of America
Published: 01 January 2002
American Mineralogist (2002) 87 (1): 181–184.
... data no further comparison is possible. J.L.J. P. Keller, F. Lissner, T. Schleid (2001) Damaraite, Pb 3 O 2 (OH)Cl: Crystal structure and new chemical formula. Neues Jahrb. Mineral. Mon., 326–336. Single-crystal X-ray structure study ( R = 0.0424) of a type crystal of damaraite gave...
Journal Article
THE CRYSTAL STRUCTURE OF LENINGRADITE, PbCu 3 (VO 4 ) 2 Cl 2 Available to Purchase
Journal: The Canadian Mineralogist
Publisher: Mineralogical Association of Canada
Published: 01 June 2007
The Canadian Mineralogist (2007) 45 (3): 445–449.
... , T. ( 2001 ): Damaraite, Pb 3 O 2 (OH)Cl: crystal structure and new chemical formula . Neues Jahrb. Mineral., Monatsh ., 326 – 336 . Krivovichev , S.V. & Brown , I.D. ( 2001 ): Are the compressive effects of encapsulation an artifact of the bond valence parameters? Z...
FIGURES
Journal Article
Rickturnerite, Pb 7 O 4 [Mg(OH) 4 ](OH)Cl 3 , a complex new lead oxychloride mineral Available to Purchase
Journal: Mineralogical Magazine
Published: 01 February 2012
Mineralogical Magazine (2012) 76 (1): 59–73.
... ) The mutually perpendicular arrangement in mendipite. ( e ) The zigzag arrangement in damaraite. ...
FIGURES
Cl 3 , a co...](https://gsw.silverchair-cdn.com/gsw/Content_public/Journal/minmag/76/1/10.1180_minmag.2012.076.1.59/5/s_05-rum-01.jpeg?Expires=1755882251&Signature=uT11hUAWIT7QHJoaCSqCWg-Q2ZKD-6wPbjzVD5-q~~s5uh7M9IPno0kk~ixMY5tPGwEnAnK4IPuR0XNiqhygoH65lQoCRKgwtZg-31s7L7XsDQad8Ymf9LSGIgWq9Exsh43kl7XiCo-KPYBZy5Mbn923xgvSNWJ1cHbpDcP86VErCO0A8VI22Pv39VobSnOjiTGi0RFahk437REEWf9gpnjxp8Udf~xbhDQa8sxaMHZxFZ15-Oh4iQimjY~fvvdelnHYfXvoyMrm25Cguw4oT7B0XftPBjYsjGAUPkM76AZtSIx-TcjXNFUntCCzCKUQgVgFR3HhxLp63j6PC8T9qA__&Key-Pair-Id=APKAIE5G5CRDK6RD3PGA)
Cl 3 , a co...](https://gsw.silverchair-cdn.com/gsw/Content_public/Journal/minmag/76/1/10.1180_minmag.2012.076.1.59/5/s_05-rum-02.jpeg?Expires=1755882251&Signature=TN5ak4hawUbtded-KJS-sVBYOMA7R0VqIvy35ByqNEk0uUqX-uTo0G0aXOuwOMJ7O33yd-a872P8Hts~eS-xQixG-QktLPe-87c~bla1f21pinUUVA0Zh0~N7gx2~Mp6Go9TknBb9EvhzI2UkUBRYVEy4g~pa6IJGso1qmhjRngMZC4vGy0-HMj7J~4zJe5VHlQ5iaVsKiW3DN-EWctkpEq880CBUKAmuYbVLKNAm~sUbtLpaHGr0hWIBJDqT2mo3OUPv4A1SO4-xE4RMjh5odybEKCdbAbElmUA6HUTARmYfxebnULzz3kR7LAnCf7OP-1Fz7ZkjUoNEPjLLYyPew__&Key-Pair-Id=APKAIE5G5CRDK6RD3PGA)
Cl 3 , a co...](https://gsw.silverchair-cdn.com/gsw/Content_public/Journal/minmag/76/1/10.1180_minmag.2012.076.1.59/5/s_05-rum-03.jpeg?Expires=1755882251&Signature=wdKvVxnfkBDorbtvPHmZK-DaS84VGsq88FtkY7RRgQcoYMkh2Dh9fyG3d3s8oVh5DV4RK4fJzz6nWX3g56K95iQSZEe-gW8~Nof-Cf2ls9FF1B1A4cokNrVHUZ0HvUVE2w0msDroTtPUGxOlsNLSmJJ1QoXB2GRImYJqAGAv1cmW0gKVxPwG0sHlk8gKHdeCZ6TbFs7Wam7~yyoeGA4-AaCGq3M3W2u-Wx~fDJCb-pS2T3qL1mRet~jlcJmI5A2Kgm2Tw~yiJKxxgUloduMQChnh1kAuMBPjll8W6mjGkc~zEiCD9VXNTl~iKPgqgeMpAjqgX0ZfJGtnZxaVgfP1rQ__&Key-Pair-Id=APKAIE5G5CRDK6RD3PGA)
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