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cupropavonite

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Journal Article

CUPROMAKOPAVONITE, Cu 8 Ag 3 Pb 4 Bi 19 S 38 , A NEW MINERAL SPECIES, ITS CRYSTAL STRUCTURE AND THE CUPROPAVONITE HOMOLOGOUS SERIES: ERRATUM

Published: 01 June 2012
The Canadian Mineralogist (2012) 50 (3): 773.
DOI: https://doi.org/10.3749/canmin.50.3.773
..., and both failed to notice the omission. The editor apologizes to the authors and readers. Table 10 is reproduced here. TABLE 10 NATURAL AND HYPOTHETICAL MEMBERS OF THE CUPROPAVONITE HOMOLOGOUS SERIES mineral N N p N 1 ,N 2 formula Cu Ag Pb Bi S total a (Å) b (Å) c (Å) β...
View PDF for article title, CUPROMAKOPAVONITE, Cu 8 Ag 3 Pb 4 Bi 19 S 38 , A NEW MINERAL SPECIES, ITS CRYSTAL STRUCTURE AND THE <span class="search-highlight">CUPROPAVONITE</span> HOMOLOGOUS SERIES: ERRATUM
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Journal Article

CUPROMAKOPAVONITE, Cu 8 Ag 3 Pb 4 Bi 19 S 38 , A NEW MINERAL SPECIES, ITS CRYSTAL STRUCTURE AND THE CUPROPAVONITE HOMOLOGOUS SERIES

Dan Topa, Emil Makovicky, Gheorghe Ilinca, Herbert Dittrich
Published: 01 April 2012
The Canadian Mineralogist (2012) 50 (2): 295–312.
DOI: https://doi.org/10.3749/canmin.50.2.295
.... Cupromakopavonite is the N = 4.5 member of the newly defined cupropavonite homologous series, and its name underscores its close structural relationships to its two neighboring members, cupromakovickyite (N = 4) and cupropavonite (N = 5). We define the structural and chemical properties of this series...
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View PDF for article title, CUPROMAKOPAVONITE, Cu 8 Ag 3 Pb 4 Bi 19 S 38 , A NEW MINERAL SPECIES, ITS CRYSTAL STRUCTURE AND THE <span class="search-highlight">CUPROPAVONITE</span> HOMOLOGOUS SERIES
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Journal Article

Cupropavonite from Hall's Valley, Park County, Colorado

E. W. Nuffield
Published: 01 May 1980
The Canadian Mineralogist (1980) 18 (2): 181–184.
View PDF for article title, <span class="search-highlight">Cupropavonite</span> from Hall&#x27;s Valley, Park County, Colorado
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Compositional scheme for pavonite homologues (void symbols) and cupropavonite homologues (solid symbols) in the Ag – Bi – (Cu + Pb) diagram. Lines for pavonite homologues of the order Np are indicated by points at 0, 25, 50, 75 and 100 at.% of imaginary (Ag+Bi)-for-2Pb substitution by Pb in the octahedral cation sites, for Cu-free cases. Points indicating Np values for the homologues of cupropavonite are situated on the ideal composition line for this series. Electron-microprobe data for the exsolution pairs are plotted into the scheme: makovickyite – cupromakovickyite from Băiţa Bihor, makovickyite – cupromakopavonite from Felbertal, pavonite – cupropavonite from the Alaska mine, Colorado, [1: Karup-Møller &amp; Makovicky (19790 and 2: this work], benjaminite – cuproplumbian benjaminite from Erzwies (Makovicky et al. 2010), and mummeite – cuproplumbian mummeite from the Alaska mine (this work). Abbreviations: Np: pavonite homologue with order value N, cupro-Np: cupropavonite homologue with order value N, lam: lamellae, hg: homogeneous.

Compositional scheme for pavonite homologues (void symbols) and cupropavoni...

Published: 01 April 2012
Fig. 10 Compositional scheme for pavonite homologues (void symbols) and cupropavonite homologues (solid symbols) in the Ag – Bi – (Cu + Pb) diagram. Lines for pavonite homologues of the order N p are indicated by points at 0, 25, 50, 75 and 100 at.% of imaginary (Ag+Bi)-for-2Pb substitution
Image
Compositions of Cu-free Pb-substituted Ag–Bi pavonites, and those of the cupropavonite series (the latter form a separate sequence of discrete homologue compositions) in the empirical Ag–Bi–(Pb+Cu) diagram. The indicated homologue order N values are valid for the Ag–Bi end-members and for the hypothetical Pb–Bi end-members of the pavonite series; they are given separately for the compositions of the cupropavonite series in the interior of the triangular diagram.

Compositions of Cu-free Pb-substituted Ag–Bi pavonites, and those of the cu...

Published: 01 January 2019
Fig. 4 Compositions of Cu-free Pb-substituted Ag–Bi pavonites, and those of the cupropavonite series (the latter form a separate sequence of discrete homologue compositions) in the empirical Ag–Bi–(Pb+Cu) diagram. The indicated homologue order N values are valid for the Ag–Bi end-members
Image
BSE photographs of exsolution aggregates involving members of the pavonite and cupropavonite homologous series. (a) Makovickyite – cupromakovickyite aggregate from Băiţa Bihor, Romania; (b) pavonite – cupropavonite aggregate from the Alaska mine, Colorado, U.S.A.; (c) benjaminite – cuproplumbian benjaminite aggregate from Erzwies, Austria (Makovicky et al. 2010); (d) mummeite – cuproplumbian mummeite aggregate from the Alaska mine, Colorado. In each image, the differences in the thickness of exsolution lamellae are primarily caused by their orientation. The length of the bars is 100 μm.

BSE photographs of exsolution aggregates involving members of the pavonite ...

Published: 01 April 2012
Fig. 9 BSE photographs of exsolution aggregates involving members of the pavonite and cupropavonite homologous series. (a) Makovickyite – cupromakovickyite aggregate from Băiţa Bihor, Romania; (b) pavonite – cupropavonite aggregate from the Alaska mine, Colorado, U.S.A.; (c) benjaminite
Image
Site labeling for the proposed structure of cupropavonite.

Site labeling for the proposed structure of cupropavonite.

Published: 01 April 2012
Fig. 7 Site labeling for the proposed structure of cupropavonite.
Image
The crystal structure of cupropavonite,Cu2AgPbBi5S10 (Mumme et al., 2015) (N = 5) in projection along [010]. Large white spheres, S; small white spheres, Cu; black spheres, Bi; large grey spheres, Pb; small grey spheres, Ag.

The crystal structure of cupropavonite,Cu 2 AgPbBi 5 S 10 ( Mumme et al ....

Published: 01 January 2019
Fig. 5 The crystal structure of cupropavonite,Cu 2 AgPbBi 5 S 10 ( Mumme et al ., 2015 ) ( N  = 5) in projection along [010]. Large white spheres, S; small white spheres, Cu; black spheres, Bi; large grey spheres, Pb; small grey spheres, Ag.
Image
The hypothetical structure of cupropavonite projected along b (~ 4 Å). In order of increasing size, circles represent Cu (red), Bi (white), Ag (green), Pb (blue) and S (white) positions. Void and shaded circles represent atoms at two y levels, 2 Å apart. Two types of 5P thicker layers (grey shading) are separated by asymmetric thin cupromakovickyite-like layers (unshaded).

The hypothetical structure of cupropavonite projected along b (~ 4 Å). In...

Published: 01 April 2012
Fig. 8 The hypothetical structure of cupropavonite projected along b (~ 4 Å). In order of increasing size, circles represent Cu (red), Bi (white), Ag (green), Pb (blue) and S (white) positions. Void and shaded circles represent atoms at two y levels, 2 Å apart. Two types of 5 P thicker
Image
Configuration of thicker layers of octahedra in the pavonite homologues. Large circles: S, smaller circles: cations. The order of the homologue Np is determined by the number of octahedra along a diagonal of the layer. The known examples from the cupropavonite homologous series follow the same pattern.

Configuration of thicker layers of octahedra in the pavonite homologues. La...

Published: 01 April 2012
Fig. 6 Configuration of thicker layers of octahedra in the pavonite homologues. Large circles: S, smaller circles: cations. The order of the homologue N p is determined by the number of octahedra along a diagonal of the layer. The known examples from the cupropavonite homologous series follow
Journal Article

WHAT IS THE REASON FOR THE DOUBLED UNIT-CELL VOLUMES OF COPPER–LEAD-RICH PAVONITE HOMOLOGUES? THE CRYSTAL STRUCTURES OF CUPROMAKOVICKYITE AND MAKOVICKYITE

Dan Topa, Emil Makovicky, Tonc̀i Balić-Žunić
Published: 01 April 2008
The Canadian Mineralogist (2008) 46 (2): 515–523.
DOI: https://doi.org/10.3749/canmin.46.2.515
... material allowed us to recognize a doubled c parameter of the (Cu, Pb)-rich variety. In analogy with the pair pavonite–cupropavonite (both with N = 5), the name of the (Cu, Pb)-poorer phase, makovickyite ( Žák et al . 1994 ), was used to give the name cupromakovickyite to the new, (Cu, Pb)-rich...
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View PDF for article title, WHAT IS THE REASON FOR THE DOUBLED UNIT-CELL VOLUMES OF COPPER–LEAD-RICH PAVONITE HOMOLOGUES? THE CRYSTAL STRUCTURES OF CUPROMAKOVICKYITE AND MAKOVICKYITE
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Journal Article

Algorithms for calculations of homologue order N in the homologous series of sulfosalts

Emil Makovicky
Published: 01 January 2019
European Journal of Mineralogy (2019) 31 (1): 83–97.
DOI: https://doi.org/10.1127/ejm/2018/0030-2791
...Fig. 4 Compositions of Cu-free Pb-substituted Ag–Bi pavonites, and those of the cupropavonite series (the latter form a separate sequence of discrete homologue compositions) in the empirical Ag–Bi–(Pb+Cu) diagram. The indicated homologue order N values are valid for the Ag–Bi end-members...
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View PDF for article title, Algorithms for calculations of homologue order N in the homologous series of sulfosalts
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CUPROMAKOVICKYITE, Cu 8 Pb 4 Ag 2 Bi 18 S 36 , A NEW MINERAL SPECIES OF THE PAVONITE HOMOLOGOUS SERIES

Dan Topa, Werner H. Paar
Published: 01 April 2008
The Canadian Mineralogist (2008) 46 (2): 503–514.
DOI: https://doi.org/10.3749/canmin.46.2.503
... distributed as lamellae down to few unit cells in thickness. It is for this reason that the Pb content reported is lower than expected. Cupromakovickyite is related to makovickyite in exactly the same way as cupropavonite is related to pavonite ( Karup-Moller & Makovicky 1979 ). In order...
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Selected examples of thinner structural slabs from the crystal structures of pavonite (a, b, and c) and cupropavonite homologues (d1 and d2). a) Synthetic pavonite AgBi3S5 (Makovicky et al. 1977); the octahedral Ag site (green) is fully occupied. b) Makovickyite (Topa et al. 2008) and c) Cu-bearing benjaminite (D. Topa, unpubl. data); Ag site (green) and Cu sites (blue and red) are partially occupied. d) Two adjacent thin layers d1 and d2 in cupromakovickyite and cupromakopavonite (Topa et al. 2008, this study); the Pb site (dark blue) and Cu sites (red) with opposite orientations are fully occupied.

Selected examples of thinner structural slabs from the crystal structures o...

Published: 01 April 2012
Fig. 5 Selected examples of thinner structural slabs from the crystal structures of pavonite (a, b, and c) and cupropavonite homologues (d 1 and d 2 ). a) Synthetic pavonite AgBi 3 S 5 ( Makovicky et al . 1977 ); the octahedral Ag site (green) is fully occupied. b) Makovickyite ( Topa et al
Journal Article

THE CRYSTAL STRUCTURE OF BERRYITE, Cu 3 Ag 2 Pb 3 Bi 7 S 16

Dan Topa, Emil Makovicky, Hubert Putz, W. Gus Mumme
Published: 01 April 2006
The Canadian Mineralogist (2006) 44 (2): 465–480.
DOI: https://doi.org/10.2113/gscanmin.44.2.465
... . The pairing of square coordination pyramids of Bi with bicapped coordination prisms of Pb leads in these slices to a structural analogy with cupromakovickyite and cupropavonite rather than to that with pavonite, in which only paired Bi pyramids occur in the thin, non-accretional layers ( Topa et al. 2006...
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View PDF for article title, THE CRYSTAL STRUCTURE OF BERRYITE, Cu 3 Ag 2 Pb 3 Bi 7 S 16
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Composition of the analyzed Ag–Bi phases (a); see the text for more information. Enlargement of (a) to focus on berryite, gustavite, ourayite, and eskimoite (b). Minerals written in bold are without Cu, whereas minerals written in italics contain Cu. Symbols: Aca: acanthite, Aik: aikinite, Asl: aschamalmite, Ber: berryite, Bmt: bismuthinite, Bnj: benjaminite, Can: cannizzarite, Cos: cosalite, Cpv: cupropavonite, Eml: emilite, Emp: emplectite, Esk: eskimoite, Frd: friedrichite, Gld: gladite, Gn: galena, Gnb: galenobismutite, Gvt: gustavite, Ham: hammarite, Hey: heyrovskyite, Kpk: krupkaite, Lds: lindströmite, Lil: lillianite, Lrs: larosite, Mat: matildite, Mky: makovickyite, Mum: mummeite, Ney: neyite, Nuf: nuffieldite, Our: ourayite, Paa: paarite, Pad: paděraite, Pav: pavonite, Slz: salzburgite, Spb: schapbachite, Trs: treasurite, Vik: vikingite, Witc: wittichenite, Witt: wittite, Xil: xilingolite.

Composition of the analyzed Ag–Bi phases (a); see the text for more informa...

Published: 01 June 2010
: aikinite, Asl: aschamalmite, Ber: berryite, Bmt: bismuthinite, Bnj: benjaminite, Can: cannizzarite, Cos: cosalite, Cpv: cupropavonite, Eml: emilite, Emp: emplectite, Esk: eskimoite, Frd: friedrichite, Gld: gladite, Gn: galena, Gnb: galenobismutite, Gvt: gustavite, Ham: hammarite, Hey: heyrovskyite, Kpk
Journal Article

DANTOPAITE, Ag 5 Bi 13 S 22 , THE 6 P NATURAL MEMBER OF THE PAVONITE HOMOLOGOUS SERIES, FROM ERZWIES, AUSTRIA

Emil Makovicky, Werner H. Paar, Hubert Putz, Georg Zagler
Published: 01 June 2010
The Canadian Mineralogist (2010) 48 (3): 467–481.
DOI: https://doi.org/10.3749/canmin.48.3.467
... cupropavonite (N = 5) with a unit cell doubled compared to that of pavonite. TABLE 8. RELATIONSHIP TO KNOWN SPECIES In homologous series of minerals, members with certain values of the order number N may be very common, whereas other members, with N values interspersed between the common ones...
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View PDF for article title, DANTOPAITE, Ag 5 Bi 13 S 22 , THE 6 P NATURAL MEMBER OF THE PAVONITE HOMOLOGOUS SERIES, FROM ERZWIES, AUSTRIA
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Journal Article

HRTEM observations of structural and chemical modulations in cosalite and its relationship to the lillianite homologues

A. Pring, B. Etschmann
Published: 01 June 2002
Mineralogical Magazine (2002) 66 (3): 451–458.
DOI: https://doi.org/10.1180/0026461026630041
... , S. and Makovicky , E. ( 1979 ) On pavonite, cupropavonite, benjaminite and ‘over-substituted’ gustavite . Bulletin de la Société Francaise de Mineralogie et Cristallographie , 102 , 351 – 367 . Makovicky , E. ( 1977 ) Chemistry and crystallography of the lillianite...
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View PDF for article title, HRTEM observations of structural and chemical modulations in cosalite and its relationship to the lillianite homologues
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Tellurium-rich stibiogoldfieldite and Se-bearing dantopaite from Goldfield, Nevada, USA: new crystal chemical data

Silvia Musetti, Jiří Sejkora, Cristian Biagioni, Zdeněk Dolníček
Published: 16 October 2023
Mineralogical Magazine (2024) 88 (1): 40–48.
DOI: https://doi.org/10.1180/mgm.2023.77
... E. ( 1979 ) On pavonite, cupropavonite, benjaminite and «oversubstituted» gustavite . Bulletin de Minéralogie , 102 , 351 – 367 . Kolitsch U. , Bayerl R...
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View PDF for article title, Tellurium-rich stibiogoldfieldite and Se-bearing dantopaite from Goldfield, Nevada, USA: new crystal chemical data
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Journal Article

Mineralogy of the scheelite-bearing ores of Monte Tamara, SW Sardinia: insights for the evolution of a Late Variscan W–Sn skarn system

Matteo L. Deidda, Stefano Naitza, Marilena Moroni, Giovanni B. De Giudici, Dario Fancello, Alfredo Idini, Andrea Risplendente
Published: 21 November 2022
Mineralogical Magazine (2023) 87 (1): 86–108.
DOI: https://doi.org/10.1180/mgm.2022.119
... ) and cupropavonite (Cu 0.9 Ag 0.5 Pb 0.6 Bi 2.5 S 5 ) were identified. Bismuthinite occurs in both chalcopyrite–scheelite (zone 1; sample VMd5b) and sphalerite–pyrite ore facies (zone 3a; sample MTB3), whereas the other Bi phases occur in the chalcopyrite-rich facies only (zone 1–3a; samples VMd5b-MTB1). All the Bi...
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View PDF for article title, Mineralogy of the scheelite-bearing ores of Monte Tamara, SW Sardinia: insights for the evolution of a Late Variscan W–Sn skarn system
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