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![Secondary bonding environments in <span class="search-highlight">carlfriesite</span>. Primary bonds are shown as ...]()
![Color photograph of <span class="search-highlight">carlfriesite</span> occurring as radial crystals on a fracture...]()
![Pale yellow transparent crystals of <span class="search-highlight">carlfriesite</span> from Wildcat Prospect on s...]()
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![Pale emerald-green crystalline aggregates of tlapallite from Wildcat Prospe...]()
![Metal–oxygen bond lengths (Å) for <span class="search-highlight">carlfriesite</span>. Te1–O1 × 2 1.877(3...]()
![The crystal structure of <span class="search-highlight">carlfriesite</span>. Te 6+ O 6 octahedra are shown in da...]()
![Bond-valence sums (in valence units) for <span class="search-highlight">carlfriesite</span>. Te1 Te2 C...]()
![Back-scattered electron image of one of the grains used in the Caltech micr...]()
![Optical images of wildcatite. (a) Several forms of wildcatite (red-brown gl...]()
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![Atom coordinates, site occupancies and atomic displacement parameters (Å 2 ...]()
![Summary of information relating to data collection and structure refinement...]()
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1-20 OF 24 RESULTS FOR
carlfriesite
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1
Journal Article
The crystal structures of the mixed-valence tellurium oxysalts tlapallite, (Ca,Pb) 3 CaCu 6 [Te 4+ 3 Te 6+ O 12 ] 2 (Te 4+ O 3 ) 2 (SO 4 ) 2 ·3H 2 O, and carlfriesite, CaTe 4+ 2 Te 6+ O 8
Journal: Mineralogical Magazine
Published: 12 February 2019
Mineralogical Magazine (2019) 83 (4): 539–549.
... polyhedra and H 2 O groups fill the space between the layers. Tlapallite is only the second naturally occurring compound containing tellurium in both the 4 + and 6 + oxidation states with a known crystal structure, the other being carlfriesite, CaTe 4+ 2 Te 6+ O 8 . Carlfriesite is the predominant secondary...
FIGURES
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Journal Article
Carlfriesite; crystal structure, revision of chemical formula, and synthesis
Journal: American Mineralogist
Publisher: Mineralogical Society of America
Published: 01 October 1978
American Mineralogist (1978) 63 (9-10): 847–852.
...H. Effenberger; J. Zemann; H. Mayer Abstract The structure of natural carlfriesite, given by Williams and Gaines (1975) as H 4 Ca(TeO 3 ) 3 , was determined by single-crystal standard X-ray procedures. The least-squares refinement for 595 observed reflections resulted in a conventional reliability...
Image
Secondary bonding environments in carlfriesite. Primary bonds are shown as ...
in The crystal structures of the mixed-valence tellurium oxysalts tlapallite, (Ca,Pb) 3 CaCu 6 [Te 4+ 3 Te 6+ O 12 ] 2 (Te 4+ O 3 ) 2 (SO 4 ) 2 ·3H 2 O, and carlfriesite, CaTe 4+ 2 Te 6+ O 8
> Mineralogical Magazine
Published: 12 February 2019
Fig. 10. Secondary bonding environments in carlfriesite. Primary bonds are shown as thicker bonds, secondary as thin bonds.
Image
Color photograph of carlfriesite occurring as radial crystals on a fracture...
in Andymcdonaldite (Fe 3+ 2 Te 6+ O 6 ), a new ferric iron tellurate with inverse trirutile structure from the Detroit district, Juab County, Utah
> The Canadian Mineralogist
Published: 16 January 2020
Fig. 2. Color photograph of carlfriesite occurring as radial crystals on a fracture surface in jasperoid. Photograph © 2018 Dane S. Johnson.
Image
Pale yellow transparent crystals of carlfriesite from Wildcat Prospect on s...
in The crystal structures of the mixed-valence tellurium oxysalts tlapallite, (Ca,Pb) 3 CaCu 6 [Te 4+ 3 Te 6+ O 12 ] 2 (Te 4+ O 3 ) 2 (SO 4 ) 2 ·3H 2 O, and carlfriesite, CaTe 4+ 2 Te 6+ O 8
> Mineralogical Magazine
Published: 12 February 2019
Fig. 2. Pale yellow transparent crystals of carlfriesite from Wildcat Prospect on specimen number 67227. Field of view = 3.5 mm.
Journal Article
Wildcatite, CaFe 3+ Te 6+ O 5 (OH), the second new tellurate mineral from the Detroit district, Juab County, Utah
Journal: The Canadian Mineralogist
Publisher: Mineralogical Association of Canada
Published: 13 September 2021
The Canadian Mineralogist (2021) 59 (4): 729–739.
... oxysalts andymcdonaldite, burckhardtite, carlfriesite, eckhardite, frankhawthorneite, khinite, mcalpineite, tlapallite, and xocolatlite. The strongest powder diffraction lines are [ d obs Å( I obs )( hkl )]: 3.33(100)(011), 2.60(55)(110), 2.30(59)(111), 2.05(33)(021), and 1.80(88)(112). The average size...
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Journal Article
Andymcdonaldite (Fe 3+ 2 Te 6+ O 6 ), a new ferric iron tellurate with inverse trirutile structure from the Detroit district, Juab County, Utah
Journal: The Canadian Mineralogist
Publisher: Mineralogical Association of Canada
Published: 16 January 2020
The Canadian Mineralogist (2020) 58 (1): 85–97.
...Fig. 2. Color photograph of carlfriesite occurring as radial crystals on a fracture surface in jasperoid. Photograph © 2018 Dane S. Johnson. ...
FIGURES
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Image
Pale emerald-green crystalline aggregates of tlapallite from Wildcat Prospe...
in The crystal structures of the mixed-valence tellurium oxysalts tlapallite, (Ca,Pb) 3 CaCu 6 [Te 4+ 3 Te 6+ O 12 ] 2 (Te 4+ O 3 ) 2 (SO 4 ) 2 ·3H 2 O, and carlfriesite, CaTe 4+ 2 Te 6+ O 8
> Mineralogical Magazine
Published: 12 February 2019
Fig. 1. Pale emerald-green crystalline aggregates of tlapallite from Wildcat Prospect on specimen number 67231, closely associated with carlfriesite (yellow) and quartz. Field of view = 0.84 mm.
Image
Metal–oxygen bond lengths (Å) for carlfriesite. Te1–O1 × 2 1.877(3...
in The crystal structures of the mixed-valence tellurium oxysalts tlapallite, (Ca,Pb) 3 CaCu 6 [Te 4+ 3 Te 6+ O 12 ] 2 (Te 4+ O 3 ) 2 (SO 4 ) 2 ·3H 2 O, and carlfriesite, CaTe 4+ 2 Te 6+ O 8
> Mineralogical Magazine
Published: 12 February 2019
Table 9. Metal–oxygen bond lengths (Å) for carlfriesite. Te1–O1 × 2 1.877(3) Te2–O4 1.916(3) Ca–O4 × 2 2.374(3) Te1–O1 × 2 1.934(3) Te2–O2 1.961(3) Ca–O1 × 2 2.443(3) Te1–O3 × 2 1.971(3) Te2–O4 2.100(3) Ca–O2 × 2 2.513(3) <Te1–O> 1.927 Te2–O3 2.104(3) Ca
Image
The crystal structure of carlfriesite. Te 6+ O 6 octahedra are shown in da...
in The crystal structures of the mixed-valence tellurium oxysalts tlapallite, (Ca,Pb) 3 CaCu 6 [Te 4+ 3 Te 6+ O 12 ] 2 (Te 4+ O 3 ) 2 (SO 4 ) 2 ·3H 2 O, and carlfriesite, CaTe 4+ 2 Te 6+ O 8
> Mineralogical Magazine
Published: 12 February 2019
Fig. 9. The crystal structure of carlfriesite. Te 6+ O 6 octahedra are shown in dark green, Te 4+ cations in dark green, Ca 2+ cations in light blue, and O atoms in red. Note that the Ca 2+ cations fill pore space in the three-dimensional framework.
Image
Bond-valence sums (in valence units) for carlfriesite. Te1 Te2 C...
in The crystal structures of the mixed-valence tellurium oxysalts tlapallite, (Ca,Pb) 3 CaCu 6 [Te 4+ 3 Te 6+ O 12 ] 2 (Te 4+ O 3 ) 2 (SO 4 ) 2 ·3H 2 O, and carlfriesite, CaTe 4+ 2 Te 6+ O 8
> Mineralogical Magazine
Published: 12 February 2019
Table 10. Bond-valence sums (in valence units) for carlfriesite. Te1 Te2 Ca Σ O1 1.08 × 2↓ 0.31, 0.10 0.27 × 2↓ 1.76 O2 0.91 × 2↓ 1.00 0.23 × 2↓ 2.14 O3 0.98 × 2↓ 0.70, 0.03 0.22 × 2↓ 1.94 O4 1.11, 0.71 0.32 × 2↓ 2.15 Σ 5.95 3.97 2.08
Image
Back-scattered electron image of one of the grains used in the Caltech micr...
in The crystal structures of the mixed-valence tellurium oxysalts tlapallite, (Ca,Pb) 3 CaCu 6 [Te 4+ 3 Te 6+ O 12 ] 2 (Te 4+ O 3 ) 2 (SO 4 ) 2 ·3H 2 O, and carlfriesite, CaTe 4+ 2 Te 6+ O 8
> Mineralogical Magazine
Published: 12 February 2019
Fig. 3. Back-scattered electron image of one of the grains used in the Caltech microprobe analyses of tlapallite from Wildcat Prospect. Field of view is 100 μm. EDS analyses were recorded at the numbered spots. Spots 16, 17, 18, and 22 are tlapallite blades. Spot 19 is carlfriesite. Spots 20, 21
Image
Optical images of wildcatite. (a) Several forms of wildcatite (red-brown gl...
in Wildcatite, CaFe 3+ Te 6+ O 5 (OH), the second new tellurate mineral from the Detroit district, Juab County, Utah
> The Canadian Mineralogist
Published: 13 September 2021
(NHMLAC 74539). The radiating pattern may be due to replacement of carlfriesite, which is known at this locality to form radiating crystal groups of this size.
Journal Article
Tombstoneite, a new mineral from Tombstone, Arizona, USA, with a pinwheel-like Te 6+ O 3 (Te 4+ O 3 ) 3 cluster
Journal: Mineralogical Magazine
Published: 18 August 2022
Mineralogical Magazine (2023) 87 (1): 10–17.
... phyllotellurate anion [Te 4+ 3 Te 6+ O 12 ] 12− ; Missen et al. , 2019 ) and carlfriesite, CaTe 4+ 2 Te 6+ O 8 (nanoporous [Te 4+ 2 Te 6+ O 8 ] 2– framework; Missen et al. , 2019 ), which both have their own new unique configurations. Structures Editor and reviewers Oleg Siidra and Nicolas Meisser...
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Journal Article
The discreditation of oboyerite and a note on the crystal structure of plumbotellurite
Journal: Mineralogical Magazine
Published: 04 October 2019
Mineralogical Magazine (2019) 83 (6): 791–797.
... intergrowths. These sort of characterisations become even more problematic when more than one specimen is used to characterise the same mineral. Following the discreditations of ‘girdite’ and ‘oboyerite’, the number of remaining valid mixed-valence Te oxysalt minerals is just four. Carlfriesite and tlapallite...
FIGURES
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Image
Atom coordinates, site occupancies and atomic displacement parameters (Å 2 ...
in The crystal structures of the mixed-valence tellurium oxysalts tlapallite, (Ca,Pb) 3 CaCu 6 [Te 4+ 3 Te 6+ O 12 ] 2 (Te 4+ O 3 ) 2 (SO 4 ) 2 ·3H 2 O, and carlfriesite, CaTe 4+ 2 Te 6+ O 8
> Mineralogical Magazine
Published: 12 February 2019
Table 8. Atom coordinates, site occupancies and atomic displacement parameters (Å 2 ) for carlfriesite. All sites fully occupied. Atom x / a y / b z / c U eq U 11 U 22 U 33 U 23 U 13 U 12 Te1 ½ ½ ½ 0.00585(11) 0.00538(18) 0.0060(2) 0.00688
Image
Summary of information relating to data collection and structure refinement...
in The crystal structures of the mixed-valence tellurium oxysalts tlapallite, (Ca,Pb) 3 CaCu 6 [Te 4+ 3 Te 6+ O 12 ] 2 (Te 4+ O 3 ) 2 (SO 4 ) 2 ·3H 2 O, and carlfriesite, CaTe 4+ 2 Te 6+ O 8
> Mineralogical Magazine
Published: 12 February 2019
Table 7. Summary of information relating to data collection and structure refinement of carlfriesite. Crystal data Ideal chemical formula CaTe 4+ 2 Te 6+ O 8 Crystal system, space group Monoclinic, I 2/ a Temperature (K) 293 a , b , c (Å) 9.9866(7), 5.67205(19
Journal Article
Xocolatlite, Ca 2 Mn 2 4+ Te 2 O 12 ·H 2 O, a new tellurate related to kuranakhite: Description and measurement of Te oxidation state by XANES spectroscopy
Journal: American Mineralogist
Publisher: Mineralogical Society of America
Published: 01 November 2008
American Mineralogist (2008) 93 (11-12): 1911–1920.
... * (Å 3 ) Reference * Volume per oxygen atom. Tellurites Carlfriesite CaTe 3 4+ +O 8 645.0 4 20.2 Effenberger et al. 1978 Denningite (Mn 2+ ,Ca,Zn)[Te 2 4+ O 5 ] 1014.4 8 25.4 Walitzi 1965 Mroseite CaTe 4+ O 2 CO 3 827.0 8 20.7 Fischer et al. 1975...
FIGURES
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Journal Article
Matthiasweilite, PbTe 4+ O 3 , a New Tellurite Mineral from the Delamar Mine, Lincoln County, Nevada, USA
Journal: The Canadian Mineralogist
Publisher: Mineralogical Association of Canada
Published: 21 October 2022
The Canadian Mineralogist (2022) 60 (5): 805–814.
... minerals, including numerous Te oxysalts: adanite, bairdite, burckhardtite, carlfriesite, choloalite, emmonsite, eztlite, fairbankite, frankhawthorneite, jensenite, khinite, kinichilite, kuksite, leisingite, mcalpineite, mojaveite, müllerite, northstarite, paratimroseite, poughite, quetzalcoatlite...
FIGURES
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Journal Article
Subject Index
Journal: The Canadian Mineralogist
Publisher: Mineralogical Association of Canada
Published: 08 April 2021
The Canadian Mineralogist (2020) 58 (6): 867–869.
..., synthetic soldalite, 9, windmountainite, 484 acanthite, 195, adanite, 403, alluaudite, 742, amazonite, 689, amblygonite, 738, andymcdonaldite, 85, argyrodite, 196, badakhshanite-(Y), 382, belomarinaite, 170, beryl, 806, biotite, 299, bismuthinite, 720, bismutite, 721, bobshannonite, 19, carlfriesite...
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