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carletonite

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Journal Article

Crystal-chemical characterisation and spectroscopy of fluorcarletonite and carletonite

Ekaterina Kaneva, Alexander Bogdanov, Tatiana Radomskaya, Olga Belozerova, Roman Shendrik
Published: 03 March 2023
Mineralogical Magazine (2023) 87 (3): 356–368.
DOI: https://doi.org/10.1180/mgm.2023.15
...Ekaterina Kaneva; Alexander Bogdanov; Tatiana Radomskaya; Olga Belozerova; Roman Shendrik Abstract The minerals of carletonite group, fluorcarletonite, KNa 4 Ca 4 [Si 8 O 18 ](CO 3 ) 4 (F,OH)·H 2 O and carletonite, Na 4 Ca 4 [Si 8 O 18 ](CO 3 ) 4 (OH,F)·H 2 O, were investigated using a multi-method...
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The crystal structure of carletonite, Kna 4 Ca 4 Si 8 O 8 (Co 3 ) 4 (F, Oh).H 2 O, A Double-Sheet Silicate

G. Y. CHAO
Published: 01 June 1972
American Mineralogist (1972) 57 (5-6): 765–778.
...G. Y. CHAO Abstract Carletonite, a new mineral from Mont St. Hilaire, Quebec, is tetragonal P4/mbm , with a = 13.178 Å, c = 16.695 Å, and z = 4. The structure was solved by threedimensional Patterson synthesis and refined by full-matrix least-squares method using anisotropic temperature parameters...
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Carletonite, KNa 4 Ca 4 Si 8 O 18 (CO 3 ) 4 (F, OH)·H 2 O A new Mineral From Mount St. Hilaire, Quebec

G. Y. Chao
Published: 01 December 1971
American Mineralogist (1971) 56 (11-12): 1855–1866.
...G. Y. Chao Abstract Carletonite, KNa 4 Ca 4 Si 8 O 18 (CO 3 )·(F,OH)·H 2 O, occurs in thermally metamorphosed inclusions in the nepheline syenite at Mount St. Hilaire, Quebec. It is associated mainly with pectolite. albite, arfvedsonite, calcite, fluorite, and apophyllite. The mineral is tetragonal...
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Photoluminescence spectra of fluorcarletonite (curve 1) and carletonite (cu...

Published: 03 March 2023
Figure 7. Photoluminescence spectra of fluorcarletonite (curve 1) and carletonite (curve 2) under 330 nm excitation and excitation spectra of fluorcarletonite (curve 3) and carletonite (curve 4) monitored at 400 nm.
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Perspective views of the fluorcarletonite and carletonite crystal-structure...

Published: 03 March 2023
Figure 3. Perspective views of the fluorcarletonite and carletonite crystal-structure fragments showing the environment around the (a) C1O 3 group and (b) C2O 3 group. C atoms are brown and CO 3 triangles are outlined in brown. The positions occupied by F in fluorcarletonite and by oxygen
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The crystal structure of the studied fluorcarletonite and carletonite proje...

Published: 03 March 2023
Figure 1. The crystal structure of the studied fluorcarletonite and carletonite projected along the b axis. Si-tetrahedra are black, Ca-, Na- and K-polyhedra are blue, yellow and violet, respectively. Oxygen atoms are drawn in red, Ow atoms (oxygen of H 2 O molecule) are drawn in lavender. C
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Calculated density of states for (a) fluorcarletonite and (b) carletonite; ...

Published: 03 March 2023
Figure 12. Calculated density of states for (a) fluorcarletonite and (b) carletonite; and (c) electronic charge density corresponding to states at the top of the VB in fluorcarletonite.
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Perspective view of the carletonite crystal structure fragment with the dis...

Published: 03 March 2023
Figure 2. Perspective view of the carletonite crystal structure fragment with the disordered potassium site. The partially white colouring of the spheres indicates a vacancy.
Journal Article

High-temperature behaviour of fluorcarletonite, KNa 4 Ca 4 Si 8 O 18 (CO 3 ) 4 (F,OH)⋅H 2 O, from the Murun Alkaline Complex, Russia, appraised by experimental and theoretical methods

Ernesto Mesto, Maria Lacalamita, Ekaterina Kaneva, Roman Shendrik, Alexander Bogdanov, Marcello Merli, Emanuela Schingaro
Published: 01 August 2024
Mineralogical Magazine (2024) 88 (4): 493–502.
DOI: https://doi.org/10.1180/mgm.2024.50
.... , 2019 ). The first description of this mineral was provided by Kaneva et al . ( 2020a ), who also explained the difference with respect to the structural analogue carletonite, KNa 4 Ca 4 Si 8 O 18 (CO 3 ) 4 (OH,F)⋅H 2 O (Kaneva et al ., 2023 ). The latter is a rare mineral named after Carleton...
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Selected bond distances (Å) for tetrahedra, polyhedra and angles (°) for te...

Published: 03 March 2023
Table 5. Selected bond distances (Å) for tetrahedra, polyhedra and angles (°) for tetrahedra of the studied fluorcarletonite (Murun massif) and carletonite (Mont Saint Hilaire massif) samples.
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Crystallographic coordinates, occupancies and equivalent/isotropic atomic d...

Published: 03 March 2023
Table 4. Crystallographic coordinates, occupancies and equivalent/isotropic atomic displacement parameters (Å 2 ) for carletonite. *Occupancies: K1 = 0.889(5), K2 = 0.058(4), Ow11 = 0.737(8) and Ow12 = 0.489(8).
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The parent upper single-layer sheets and double-layer sheets in ( a ) macd...

Published: 01 December 2015
F ig . 34. The parent upper single-layer sheets and double-layer sheets in ( a ) macdonaldite , and ( b ) carletonite . The chemical compositions are shown in bold in the mineral formulae.
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Average chemical composition (wt.%) for the fluorcarletonite and carletonit...

Published: 03 March 2023
Table 1. Average chemical composition (wt.%) for the fluorcarletonite and carletonite crystals studied compared with literature data. b.d.l. – below detection limit; n.d. – not determined; a calculated according to the principle of electroneutrality of the chemical formula; b determined
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Selected data on single crystals, data collection and structure refinement ...

Published: 03 March 2023
Table 2. Selected data on single crystals, data collection and structure refinement parameters of the studied fluorcarletonite and carletonite. a R  = Σ[| F o | – | F c |]/Σ| F o |. b R w  = [Σ[ w ( F o 2 – F c 2 ) 2 ]/Σ[ w ( F o 2 ) 2 ]] ½ ; w  = Chebyshev optimised
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Double-sheets of tetrahedra based on the 3-connected plane net 4.8 2 plus ...

Published: 01 February 2019
how all d tetrahedra are occupied by Al 3+ ; and ( c ) the (u 2 d 2 ) 4 (u 2 d 2 u 2 d 2 ) 2 (udududud) 2 arrangement in carletonite .
Journal Article

Mineralogical Society of the UK and Ireland

Journal: Elements
Published: 01 June 2023
Elements (2023) 19 (3): 184–185.
DOI: https://doi.org/10.2138/gselements.19.3.184
...) from rare-element pegmatites using Raman spectroscopy Yuanyuan Hao, Yonggang Feng, Ting Liang, Matthew Brzozowski, Minghui Ju, Ruili Zhou, and Yan Wang ƒ Crystal-chemical characterization and spectroscopy of fluorcarletonite and carletonite Ekaterina Kaneva, Alexander Bogdanov, Tatiana Radomskaya, Olga...
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Mineralogical Society of the UK and Ireland

Journal: Elements
Published: 01 April 2023
Elements (2023) 19 (2): 116–117.
DOI: https://doi.org/10.2138/gselements.19.2.116
... Feng, Ting Liang, Matthew Brzozowski, Minghui Ju, Ruili Zhou, and Yan Wang Crystal-chemical characterization and spectroscopy of fluorcarletonite and carletonite Ekaterina Kaneva, Alexander Bogdanov, Tatiana Radomskaya, Olga Belozerova, and Roman Shendrik Zincorietveldite, Zn(UO2)(SO4)2(H2O)5, the zinc...
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Generating functions for stoichiometry and structure of single- and double-layer sheet-silicates

Frank C. Hawthorne
Published: 01 December 2015
Mineralogical Magazine (2015) 79 (7): 1675–1709.
DOI: https://doi.org/10.1180/minmag.2015.079.7.17
...F ig . 34. The parent upper single-layer sheets and double-layer sheets in ( a ) macdonaldite , and ( b ) carletonite . The chemical compositions are shown in bold in the mineral formulae. ...
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THE STRUCTURE OF SPURRITE, TILLEYITE AND SCAWTITE, AND RELATIONSHIPS TO OTHER SILICATE–CARBONATE MINERALS

Joel D. Grice
Published: 01 October 2005
The Canadian Mineralogist (2005) 43 (5): 1489–1500.
DOI: https://doi.org/10.2113/gscanmin.43.5.1489
... structure and bonding . In Structure and Bonding in Crystals ( M. O’Keeffe and A. Navrotsky , eds.). Academic Press , New York, N.Y . (1–30). Chao , G.Y. ( 1972 ): The crystal structure of carletonite, KNa 4 Ca 4 Si 8 O 18 (CO 3 ) 4 (F, OH) 2 O, a double sheet silicate . Am...
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New minerals and nomenclature modifications approved in 2019

Ritsuro Miyawaki, Frédéric Hatert, Marco Pasero, Stuart J. Mills
Published: 01 October 2019
Mineralogical Magazine (2019) 83 (5): 757–761.
DOI: https://doi.org/10.1180/mgm.2019.58
...*, Tatiana A. Radomskaya, Ludmila F. Suvorova and Mikhail A. Mitichkin *E-mail: [email protected] The F-dominant analogue of carletonite Tetragonal: P 4/ mbn ; structure determined a  = 13.219(1), c  = 16.707(2) Å 16.92(22), 8.417(76), 4.190(100), 3.358(20), 2.917(28), 2.790(27), 2.758(20...
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