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braggite

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Journal Article
Published: 10 March 2023
The Canadian Journal of Mineralogy and Petrology (2023) 61 (1): 167–175.
...Louis J. CABRI; Andrew M. McDONALD Abstract A re-evaluation of data relating to the crystal structures, phase equilibria, and ideal chemical formulae of the key minerals belonging to the PtS–PdS binary, namely vysotskite, braggite, and cooperite, has led to redefinitions of the ideal chemical...
FIGURES
Journal Article
Published: 01 June 1999
Mineralogical Magazine (1999) 63 (3): 363–367.
...R. K. W. Merkle; R. Pikl; S. M. C. Verryn; D. de Waal Abstract Raman spectra of synthetic "braggite" (Pd, Pt, Ni)S) vary systematically with changes in Pt/Pd ratios, but this change is less pronounced than in "cooperite" ((Pt, Pd, Ni)S). Compared to "vysotskite" (ideally PdS), the incorporation...
Journal Article
Published: 01 June 1994
Mineralogical Magazine (1994) 58 (2): 223–234.
Journal Article
Published: 01 May 1985
The Canadian Mineralogist (1985) 23 (2): 149–162.
Journal Article
Published: 01 October 1978
American Mineralogist (1978) 63 (9-10): 832–839.
...L. J. Cabri; J. H. G. Laflamme; J. M. Stewart; K. Turner; B. J. Skinner Abstract Detailed mineralogical analyses of cooperite, braggite, and vysotskite, together with phase equilibrium studies, reveal that, though there is no uncertainty regarding the identity of cooperite (PtS; P 4 2 /mmc), one...
Journal Article
Published: 01 April 2002
The Canadian Mineralogist (2002) 40 (2): 571–584.
...Sabine M.C. Verryn; Roland K.W. Merkle Abstract Results of experimental investigations in the dry system PtS–PdS–NiS between 1200° and 700°C are presented. The phases encountered in the experimental runs are synthetic cooperite [( Pt ,Pd,Ni)S], synthetic braggite [( Pt,Pd ,Ni)S], synthetic...
FIGURES | View All (9)
Journal Article
Published: 26 March 2025
American Mineralogist (2025)
... of the Stillwater Complex, Montana, USA. Wangyanite occurs as anhedral-subhedral granular crystals 200–400 µm in size, associated with isoferroplatinum, braggite, pentlandite, and chalcopyrite interstitial to plagioclase grains within anorthosite. Wangyanite exhibits a yellowish brown color with a black streak...
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Compositional variations, expressed in atoms per formula unit (apfu), of the vysotskite–braggite series from the Kirakkajuppura deposit, Penikat complex, in the Pd–Pt–Ni diagram. A total of 60 EMP analyses (n = 60), made on variously textured large grains and inclusions of vysotskite–braggite in other PGM, are plotted. Compositions of vysotskite from late-stage alteration zones (“AZ”: most enriched in Ni) developed in some of the large vysotskite –braggite grains are shown by filled stars.
Published: 01 October 2005
F ig . 4. Compositional variations, expressed in atoms per formula unit ( apfu ), of the vysotskite–braggite series from the Kirakkajuppura deposit, Penikat complex, in the Pd–Pt–Ni diagram. A total of 60 EMP analyses ( n = 60), made on variously textured large grains and inclusions
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Compositions of zoned vysotskite – braggite from the Penikat complex in the Pd–Pt–Ni compositional space (atom %). Symbols: U: unaltered vysotskite – braggite, Z: zones of alteration (Figs. 11A–C, Table 8).
Published: 01 April 2004
F ig . 13. Compositions of zoned vysotskite – braggite from the Penikat complex in the Pd–Pt–Ni compositional space (atom %). Symbols: U: unaltered vysotskite – braggite, Z: zones of alteration (Figs. 11A–C , Table 8 ).
Journal Article
Published: 01 April 2004
The Canadian Mineralogist (2004) 42 (2): 515–537.
...F ig . 13. Compositions of zoned vysotskite – braggite from the Penikat complex in the Pd–Pt–Ni compositional space (atom %). Symbols: U: unaltered vysotskite – braggite, Z: zones of alteration (Figs. 11A–C , Table 8 ). ...
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Published: 10 March 2023
TABLE 1. COMPARISON OF DATA FOR COOPERITE, BRAGGITE, AND VYSOTSKITE
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(a) Back-scattered electron (BSE) micrograph of anhedral braggite [Brg, (Pt,Pd,Ni)S] grains from sample MR10, the top reef-enriched horizon in ELF-395 that was analyzed by energy-dispersive spectrometry (EDS) hyperspectral imaging (6 kV, 920 × 920 pixels, 46 nm pixel size). The arrows show rims of compositionally distinct minerals on the braggite grains. (b) Chemical phase map showing the distribution of braggite, pentlandite [Pn, (Fe,Ni)9S8], pyrrhotite (Po, Fe7S8), chalcopyrite (Ccp; CuFeS2), sperrylite (Spr; PtAs2), platinum antimonide (Ptsb; geversite, PtSb2, or stumpflite, PtSb), quartz (Qtz), and chlorite (Chl). Similarly composed spectra were detected by consideration of the X-ray line families (Pd L, Pt M, Fe L, Ni L, Cu L, As L, Sb L, S K, O K, Mg K, Al K, Si K) observed in defined areas. (c) Detail of the rectangle in (b) showing at the braggite rim a triple layer of discontinuous pyrrhotite to relatively continuous platinum antimonide and outer sperrylite. Anhedral chalcopyrite is present in the triple layer. The thickness for the different layers ranges between 46 nm and ∼1.1 μm. (d–f) Net intensity maps of cations [platinum group elements (PGE) and transition elements] and anions (arsenic, antimony, sulfur) in the areas shown in (b, c). (g) BSE micrograph of euhedral PGE mineral grains from sample MR-11, part of the top reef enriched horizon in ELF-395, that were analyzed by EDS (6 kV, 256 × 200 pixels, 38 nm pixel size). (h) Chemical phase map showing the distribution of laurite (Lau; RuS2), sperrylite, irarsite [Ira; (Ir,Ru,Rh,Pt)AsS], pyrrhotite, pyroxene (Px) and rhodium sulfarsenide (Rh-As-S). The phases were detected by cluster analysis under consideration of Os M, Ir M, Pt M, Ru L, Fe L, S K, Al L, O K, Mg K, Si K. Black areas represent mixed phase compositions at grain boundaries. (i–l) Net intensity maps of cations (sulfur, arsenic, oxygen) and PGE.
Published: 13 December 2021
Fig. 6. (a) Back-scattered electron (BSE) micrograph of anhedral braggite [Brg, (Pt,Pd,Ni)S] grains from sample MR10, the top reef-enriched horizon in ELF-395 that was analyzed by energy-dispersive spectrometry (EDS) hyperspectral imaging (6 kV, 920 × 920 pixels, 46 nm pixel size). The arrows
Journal Article
Published: 01 August 2007
The Canadian Mineralogist (2007) 45 (4): 775–792.
..., and froodite. Additional minerals identified are braggite, vysotskite, sperrylite, stillwaterite, hollingworthite, plumbo-palladinite, Pt–Fe alloy, sopcheite, and paolovite. Sperrylite, Pt–Fe alloy, and braggite are the main carriers of Pt; Ir-, Os-, or Ru-based PGM were not encountered. Gold and Au–Ag alloy...
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Journal Article
Published: 01 October 2005
The Canadian Mineralogist (2005) 43 (5): 1711–1734.
... voir remplacer par des “oxydes” hétérogènes de Pt–Fe(Cu,Pd) qui peuvent contenir des concentrations importantes de SiO 2 et MgO. D’autres grains de l’alliage Pt–Fe sont recouverts d’un mince liseré de PtS. Cooperite et braggite, et à un degré moindre, sperrylite, sont recouverts d’une couche de...
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Journal Article
Published: 01 October 2001
The Canadian Mineralogist (2001) 39 (5): 1397–1403.
..., in a sulfide-poor (≤5 vol.% of base-metal sulfides) enstatite orthocumulate of the Merensky Reef, Bushveld layered complex, South Africa. This seems to be the first reported occurrence of a Pb–Cl–(OH) compound in mafic-ultramafic rocks. The associated platinum-group minerals are members of the braggite series...
FIGURES
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Backscattered SEM image of iron oxide ore, showing presence of braggite (Pt, Pd, Ni)S as disseminated particles in silicates, magnetites, occasionally in slip/fracture planes.
Published: 01 September 2019
Fig.4. Backscattered SEM image of iron oxide ore, showing presence of braggite (Pt, Pd, Ni)S as disseminated particles in silicates, magnetites, occasionally in slip/fracture planes.
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PGM mineralogy in the Richmond samples. (a and b) Large laurite grain with a needle of moncheite (RMO 5). (c) The only four detected PGM (cooperite–braggite) within the entire RMO 35 core. (d) Large relict cooperite–braggite (co–br) grain between Fe-hydroxide (fe-hy) and pyroxene (px) (RMO 42). (e) Relict laurite with fissures (RMO 42). (f) Native Pt grain with several internal fissures (RMO 42).
Published: 13 December 2021
Fig. 10. PGM mineralogy in the Richmond samples. (a and b) Large laurite grain with a needle of moncheite (RMO 5). (c) The only four detected PGM (cooperite–braggite) within the entire RMO 35 core. (d) Large relict cooperite–braggite (co–br) grain between Fe-hydroxide (fe-hy) and pyroxene (px
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(a) Reflected light image (oil immersion) of braggite and moncheite grains (labelled in image) in the MSZ ore of the Great Dyke. (b) Backscatter electron micrograph of euhedral laurite grain intergrown with base-metal sulfides (chalcopyrite and pyrrhotite) from the MSZ. A grain of moncheite (labelled) also occurs. (c) Ternary (PtS–PdS–NiS mol.%) diagram illustrating the range of compositions of cooperite and braggite from pristine and altered (oxidized) MSZ base-metal sulfide ores. Panels (a) and (b) are reproduced from Figures 5a and 5e of Oberthür et al. (2003) and (c) is a reproduction of Figure 7 of that paper. All panels are reproduced with the permission of the author and of Mineralium Deposita.
Published: 01 January 2016
Figure 7 (a) Reflected light image (oil immersion) of braggite and moncheite grains (labelled in image) in the MSZ ore of the Great Dyke. (b) Backscatter electron micrograph of euhedral laurite grain intergrown with base-metal sulfides (chalcopyrite and pyrrhotite) from the MSZ. A grain
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Compositions (in at.%) of cooperite and braggite, projected in the triangular diagram PtS–PdS–NiS.
Published: 01 April 2013
Fig. 9 Compositions (in at.%) of cooperite and braggite, projected in the triangular diagram PtS–PdS–NiS.
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Composition of braggite (filled circles) and vysotskite (open circles) from the MSP (in at.%).
Published: 01 August 2007
F ig . 10. Composition of braggite (filled circles) and vysotskite (open circles) from the MSP (in at.%).