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boronic acid

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Schematic of a boronic acid sugar sensor. When boronic acid is linked to sugar OH groups, the organic group on the acid undergoes a measurable change (fluorescence) that can be used to detect the presence or absence of sugar.
Published: 01 August 2017
Figure 4 Schematic of a boronic acid sugar sensor. When boronic acid is linked to sugar OH groups, the organic group on the acid undergoes a measurable change (fluorescence) that can be used to detect the presence or absence of sugar.
Journal Article
Journal: Elements
Published: 01 August 2017
Elements (2017) 13 (4): 255–260.
...Figure 4 Schematic of a boronic acid sugar sensor. When boronic acid is linked to sugar OH groups, the organic group on the acid undergoes a measurable change (fluorescence) that can be used to detect the presence or absence of sugar. ...
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Journal Article
Published: 01 January 2002
American Mineralogist (2002) 87 (1): 56–68.
... that boric acid is an abundant component in volatile-rich melt inclusions and in genetically linked primary and pseudosecondary fluid inclusions, particularly in tourmaline-bearing granites and boron-rich pegmatites. In quenched pegmatite melt boron occurs predominantly as a trigonal coordinated B(OH) 3...
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Sassolite (H3BO3 - boric acid), an ephemeral boron mineral, from two very different age and geological settings. (A) Sassolite in a quartz fluid inclusion from the Tanco mine (Manitoba, Canada), dated at 2,640 Ma. Microphotograph taken with crossed polars. Image credit: Rainer Thomas; see also Thomas et al. (2012). (B) Group of tabular sassolite crystals up to 2 mm across from Vulcano volcano (Italy). Crystals have sublimated from recent volcanic emanations. Photograph reproduced, with permission, from Campostrini et al. (2011) and with permission of Marco Ciriotti (editor and president of the Associazione Micro-mineralogica Italiana).
Published: 01 August 2017
Figure 3 Sassolite (H 3 BO 3 - boric acid), an ephemeral boron mineral, from two very different age and geological settings. ( A ) Sassolite in a quartz fluid inclusion from the Tanco mine (Manitoba, Canada), dated at 2,640 Ma. Microphotograph taken with crossed polars. Image credit: Rainer
Journal Article
Journal: AAPG Bulletin
Published: 01 June 2016
AAPG Bulletin (2016) 100 (6): 943–967.
... salinity) pore water with more radiogenic strontium, the latter derived from silicate reactions during burial diagenesis. Short-chain organic acids are present in high concentrations (>1000 mg/L) along with the organophilic ions boron and iodide. The concentrations of boron, iodide, and organic acids do...
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Proportion of boron species dissolved in water and their isotopic composition as a function of fluid pH. The blue vertical rectangle shows the range of modern surface seawater pH (pHsw). The dashed horizontal line in (B) shows the δ11B value of modern seawater (~40‰). This figure was generated using the supplementary spreadsheet of Rae (2018) with a temperature of 25 °C, salinity of 35 ppt, and a water depth of 0 m. When pH is higher (less acidic), the boron isotopic composition of B(OH)4−, and therefore in carbonates, will also be higher (with more positive δ11B values), and vice versa.
Published: 01 April 2025
was generated using the supplementary spreadsheet of Rae (2018) with a temperature of 25 °C, salinity of 35 ppt, and a water depth of 0 m. When pH is higher (less acidic), the boron isotopic composition of B ( OH ) 4 − , and therefore in carbonates, will also be higher (with more
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Illustration of “frustrated Lewis pairs”. The bulky groups on boron and phosphorus mean the boron of the Lewis acid (C6F5)3B cannot get close enough to the phosphorus of the Lewis base PtBu3 to form a B–P bond, resulting in a “frustrated Lewis pair”. If H2 is present, the pair reacts with hydrogen, with boron accepting a hydride (H−) and phosphorous accepting a proton (H+). Shown is the resulting ion pair (left)[(C6F5)3BH]− and (right) [HPtBu3]+ formed from the reaction of (C6F5)3B and PtBu3 with H2. From Welch and Stephan (2007).
Published: 01 August 2017
Figure 8 Illustration of “frustrated Lewis pairs”. The bulky groups on boron and phosphorus mean the boron of the Lewis acid (C 6 F 5 ) 3 B cannot get close enough to the phosphorus of the Lewis base P t Bu 3 to form a B–P bond, resulting in a “frustrated Lewis pair”. If H 2 is present
Journal Article
Published: 01 June 2014
Italian Journal of Geosciences (2014) 133 (2): 161–168.
... to extract boric acid from the thermal waters that emerged naturally or from shallow wells ( D ickson & F anelli , 2004 ). Boric acid was obtained by evaporating the hot waters, rich in boron, in metal boilers, using wood from the nearby forests as fuel. In 1827, Francesco Larderello, founder...
FIGURES
Journal Article
Published: 01 February 2000
Russ. Geol. Geophys. (2000) 41 (2): 193–205.
... crystalline orthoboric acid – sassolite (H 3 BO 3 ). This paper deals with sassolite-bearing fluid inclusions. 22 02 1999 © 2001 by Allerton Press, Inc. 2001 Allerton Press, Inc. Granitic pegmatites tourmaline fluid inclusions boron orthoboric acid sassolite Boron, along...
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Series: Society of Economic Geologists Guidebook Series
Published: 01 January 1991
DOI: 10.5382/GB.12
EISBN: 9781934969656
Journal Article
Journal: Geology
Published: 15 February 2018
Geology (2018) 46 (4): 351–354.
... is highly soluble). Instead, the highly consistent behavior of boron within the soil column is best explained by the extremely low vapor pressure of boric acid at cold temperatures. The environment is sufficiently dry that mobility of salt species within the soil column is controlled by vapor phase effects...
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Published: 01 June 2014
Table 1 The ability of boric acid to alter stomach and/or intestine pH at equilibrium with gastrointestinal fluids. Simulation was carried out with different boron concentrations: 0.1, 1, 10, 50, 100, 200 mg/L as B.
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Boron and arsenic steam-liquid distribution coefficients (KD = Cvapor/Cliquid) as a function of temperature from wet steam wells. Data from Iceland (Giroud 2008), Kamchatka (Nikolaeva and Bychkov 2007), New Zealand (Glover 1988) and Geysers, USA (Smith et al. 1987). The solid lines indicate equilibrium vapor-liquid partitioning of both elements according to Nikolaeva (2009) (boric acid) and Pokrovski et al. (2002b) (arsenous acid).
Published: 01 January 2013
Figure 12 Boron and arsenic steam-liquid distribution coefficients ( K D = C vapor / C liquid ) as a function of temperature from wet steam wells. Data from Iceland ( Giroud 2008 ), Kamchatka ( Nikolaeva and Bychkov 2007 ), New Zealand ( Glover 1988 ) and Geysers, USA ( Smith et al. 1987
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Boron and arsenic concentrations (in parts per billion, ppb) in the coexisting vapor and liquid phase from surface springs in the geothermal fields of Kamtchatka indicated in the legend, according to data from Nikolaeva (2009). The solid line corresponds to equilibrium vapor-liquid partitioning at 100 °C according to Nikolaeva (2009) for boric acid, and Pokrovski et al. (2002b) for arsenous acid, whereas dashed lines with corresponding values indicate vapor-liquid distribution coefficients.
Published: 01 January 2013
Figure 14 Boron and arsenic concentrations (in parts per billion, ppb) in the coexisting vapor and liquid phase from surface springs in the geothermal fields of Kamtchatka indicated in the legend, according to data from Nikolaeva (2009) . The solid line corresponds to equilibrium vapor-liquid
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Boron isotopic fractionation between tourmaline and white mica as a function of temperature: comparison of natural samples and experimental data. The fractionation between tourmaline and mica (dashed line; Tur–mica) was calculated from two experimental sets, which investigated the B isotope fractionation between acidic fluids and tourmaline (Meyer et al. 2008) and boromuscovite and acidic fluids (Wunder et al. 2005). δ11B (mineral/mineral or mineral/fluid) = δ11B (mineral) – δ11B (mineral or fluid). Literature data include dravite–phengite pairs from Syros (Greece) with both prograde and retrograde growth-histories (Marschall 2005) and tourmaline–muscovite from the Bradshaw Mountains, Arizona (Hervig et al. 2002). The retrograde Syros samples all crystallized at the same temperature (400 to 430°C), but are offset for clarity. Error bars on boron isotope values are two standard deviations of the propagated errors on tourmaline and mica analyses, but do not include uncertainties on reference values and on instrumental mass-fractionation.
Published: 01 February 2011
Fig. 4. Boron isotopic fractionation between tourmaline and white mica as a function of temperature: comparison of natural samples and experimental data. The fractionation between tourmaline and mica (dashed line; Tur–mica) was calculated from two experimental sets, which investigated the B
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Type-B melt inclusions in graphic quartz from the Elba pegmatite, a and b are unheated, c and d are from the same growth zone, but re-homogenized at 700 °C, 2 kbar in 20 h using the cold-seal pressure vessel technique. 1 = ramanite-(Cs), 2 = sassolite, 3 = ramanite-(Rb), 4 = santite, 5 = topaz, V = vapor, L = boric acid saturated liquid, G = boron-rich silicate glass, scale bars are 50 μm. The melt inclusion in c is an unexposed equivalent of d, so the phase composition is preserved. The extremely high concentration of boric acid in the solution phase, as well as in bubble inside the glass, are characteristic—here formed by exsolution during quenching. The melt inclusion in d is composed of more or less stable boron- and cesium-rich glass, and a large bubble that is now exposed on the sample surface by polishing during preparation for the microprobe analysis. Significant amounts of boric acid were lost when this bubble was breached. Part e is representative of an unheated type-B melt inclusion in graphic quartz (similar to a and b), showing both new PBT minerals in a close contact, and demonstrating the relative relationship of their refractive indexes. Or = orthoclase, 1 = ramanite-(Cs), 2 = sassolite, 3 = ramanite-(Rb).
Published: 01 July 2008
= santite, 5 = topaz, V = vapor, L = boric acid saturated liquid, G = boron-rich silicate glass, scale bars are 50 μm. The melt inclusion in c is an unexposed equivalent of d , so the phase composition is preserved. The extremely high concentration of boric acid in the solution phase, as well
Journal Article
Published: 01 December 1970
American Mineralogist (1970) 55 (11-12): 1911–1931.
... 2 (OH) 3 ] 1- , the dimer of boric acid. The establishment of this type of polymerization significantly extends the principles governing the formation of complex boron-oxygen polyanions in crystals. The [B 14 O 20 (OH) 6 ] 4- polyanions are linked into sheets parallel to (010); the sheets contain 8...
Journal Article
Published: 01 August 1968
Canadian Journal of Earth Sciences (1968) 5 (4): 921–927.
... a corresponding range in the boron atomic weight of 10.814 to 10.810 (0.04% variation). The absolute ratios are 7% lower than those reported by early workers, but are in accord with the results of recent investigations. Igneous rocks and boric acid are found to have high isotopic ratios, whereas Tokyo Bay water...
Published: 01 January 1962
DOI: 10.1130/Petrologic.1962.397
EISBN: 9780813759425
... they become slightly acid because of mixing with downward percolating waters containing H 2 SO 4 resulting from oxidation of H 2 S. Films of condensate in the areas of most intense acid leaching may have pH values of 1 or less. The present thermal waters are very highin total CO 2 , boron, ammonia, sodium...
Journal Article
Published: 01 March 2023
Jour. Geol. Soc. India (2023) 99 (3): 421–429.
... ). Boron is one of the essential nutrient elements for crop production with a very narrow limit between sufficiency and deficiency. Boron concentration of <0.4 ppm is considered thresh hold for acid soils (Tandon, 2009). In the present study area, Chittor recorded the lowest value of extractable B (0.39...
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