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batisivite

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Journal Article
Published: 01 October 2008
European Journal of Mineralogy (2008) 20 (5): 975–981.
...Thomas Armbruster; Milen Kadiyski; Leonid Z. Reznitsky; Evgeny V. Sklyarov; Evgeny V. Galuskin Abstract The crystal structure (space group P 1̅, a = 7.5208(4), b = 7.6430(4), c = 9.5724(4) Å, α= 110.204(3), β = 103.338(6), γ= 98.281(7)°, V = 487.14(7) Å 3 , Z = 1) of the new mineral batisivite...
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Ordered arrangement of Si2O7 and Ba in batisivite; the octahedral framework is omitted and only the dominant Ba and Si2O7 sites are shown. Dashed lines indicate the C-centred monoclinic sub-cell, which is in batisivite only obeyed for the octahedral framework but not for the distribution of the occupants within the cube-octahedral cages. The largest cell represents a pseudo-monoclinic supercell with the same orientation as the basic C-centred subcell but all axes are doubled. The supercell is A, B, and C-centred and displays an awkward representation of Ba and Si2O7 order. The small cell with solid thin lines depicts the triclinic cell, which is sufficient for the description of Ba and Si2O7 order.
Published: 01 October 2008
Fig. 1. Ordered arrangement of Si 2 O 7 and Ba in batisivite; the octahedral framework is omitted and only the dominant Ba and Si 2 O 7 sites are shown. Dashed lines indicate the C -centred monoclinic sub-cell, which is in batisivite only obeyed for the octahedral framework
Image
Coordination of the extraframework cations in the cube-octahedral cavities in the structures of batisivite, graeserite, tomichite and barian tomichite, and derbylite; small white spheres represent oxygen atoms.
Published: 01 October 2008
Fig. 5. Coordination of the extraframework cations in the cube-octahedral cavities in the structures of batisivite, graeserite, tomichite and barian tomichite, and derbylite; small white spheres represent oxygen atoms.
Image
Polyhedral model of the structure of batisivite with Ba (spheres with bonds) and disilicate units (cross-hatched tetrahedra) alternating in the cube-octahedral cavities. Channels run parallel to [011].
Published: 01 October 2008
Fig. 4. Polyhedral model of the structure of batisivite with Ba (spheres with bonds) and disilicate units (cross-hatched tetrahedra) alternating in the cube-octahedral cavities. Channels run parallel to [011].
Journal Article
Published: 01 February 2013
Mineralogical Magazine (2013) 77 (1): 33–44.
... . In the metamorphic rocks of the Sludyanka complex, vanadium can be present as V 4+ and V 3+ within the same mineral (e.g. in batisivite, schreyerite and berdesinskiite). Kyzylkumite has a flexible composition with respect to the M 4+ /M 3+ ratio. The relationship between kyzylkumite and a closely related Be-bearing...
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Journal Article
Published: 01 October 2012
The Canadian Mineralogist (2012) 50 (5): 1233–1242.
... from the Wigwam deposit of Southeastern British Columbia, Canada. It is a metamorphic mineral formed under greenschist-facies conditions as part of an assemblage that includes quartz, celsian, apatite, sphalerite, pyrrhotite, galena, pyrite, zoltaiite, and batisivite. Greenwoodite has a Mohs hardness...
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(a) Construction scheme of the octahedral framework of derbylite-hemolite group minerals assembled of α-PbO2-type zigzag double-chains (cross-hatched) and V3O5-type columns of edge-sharing MO6 octahedra (white). Unit cell directions conform to the triclinic cell of batisivite. (b) Polyhedral model of schreyerite (Döbelin et al., 2006) projected parallel to the b-axis. The structure is interpreted as a 1:1 polysome composed of berdesinskiite- type (V3O5-type) chains (white octahedra) and α-PbO2-type chains (cross-hatched octahedra).
Published: 01 October 2008
Fig. 3. (a) Construction scheme of the octahedral framework of derbylite-hemolite group minerals assembled of α-PbO 2 -type zigzag double-chains (cross-hatched) and V 3 O 5 -type columns of edge-sharing MO 6 octahedra (white). Unit cell directions conform to the triclinic cell of batisivite. (b
Journal Article
Published: 01 July 2009
American Mineralogist (2009) 94 (7): 1075–1083.
...T. Scott Ercit; Paula C. Piilonen; Glenn Poirier; Kimberly T. Tait † E-mail: [email protected] © 2009 American Mineralogist 2009 Batisivite is triclinic, P 1̅, a = 7.521(1), b = 7.643(1), c = 9.572(1) Å, α = 110.20, β = 103.34(1), γ = 98.28(1)°, V = 487.14(7...
Journal Article
Published: 01 August 2009
European Journal of Mineralogy (2009) 21 (4): 885–891.
... ): Batisivite, the first silicate related to the derbylite-hemloite group . Eur. J. Mineral ., 20 , 975 – 981 . Åsbrink , S. ( 1980 ): The crystal structure and valency distribution in the low-temperature modification of V 3 O 5 . The decisive importance of a few very weak reflexions...
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Journal Article
Published: 01 April 2009
American Mineralogist (2009) 94 (4): 648–652.
.... For example, our Mössbauer refinement, taken in conjunction with the chemical data, gives 0.37 Fe 3+ at each of M1 and M2, but only 0.11 Fe 3+ at each of M3–M6. K.T.T. T. Armbruster, M. Kadiyski, L.Z. Reznitsky, E.V. Sklyarov, and E.V. Galuskin (2008) Batisivite, the first silicate related...
Journal Article
Published: 01 December 2016
Russ. Geol. Geophys. (2016) 57 (12): 1716–1727.
...+ coexist, in different proportions, in Ti-V oxide phases (schreyerite, berdesinskiite, and batisivite) from the Sludyanka Cr-V-bearing rocks. This is especially the case of the oxyvanite ( V 2 3 + V 4 + O 5 ) –berdesinskiite ( V 2 3 + TiO 5 ) solid solution...
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Journal Article
Published: 04 March 2022
Mineralogical Magazine (2022) 86 (2): 307–313.
..., namely batisivite BaV 8 Ti 6 (Si 2 O 7 )O 22 , magnesiocoulsonite MgV 2 O 4 , natalyite NaV(Si 2 O 6 ), oxyvanite V 3+ 2 V 4+ O 5 , and vanadio-pargasite NaCa 2 (Mg 4 V)(A l2 Si 6 O 22 )(OH) 2 and a co-author of first descriptions of three vanadian tourmalines: vanadio-oxy-chromium-dravite NaV 3 (Cr 4...
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Journal Article
Published: 01 November 2012
American Mineralogist (2012) 97 (11-12): 2024–2030.
... Lake Baikal, Siberia, Russia. The Pereval quarry is the type locality for natalyite, florensovite, kalininite, magnesiocoulsonite, vanadium-dravite, batisivite, oxyvanite, and cuprokalininite. Oxy-chromium-dravite was found in the two rock-types: chromphyllite-bearing quartzite (sample TMt3b...
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Journal Article
Published: 01 August 2014
American Mineralogist (2014) 99 (8-9): 1767–1773.
... Reznitsky et al. 2001 and Bosi et al. 2012a for a more detailed description) for natalyite, florensovite, kalininite, magnesiocoulsonite, oxy-vanadium-dravite, oxy-chromium-dravite, vanadio-oxy-chromium-dravite, vanadio-oxy-dravite, batisivite, oxyvanite, and cuprokalininite. Minerals associated...
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Journal Article
Published: 01 May 2014
American Mineralogist (2014) 99 (5-6): 1155–1162.
...) for natalyite, florensovite, kalininite, magnesiocoulsonite, oxy-vanadium-dravite, batisivite, oxyvanite, and cuprokalininite. Minerals associated with the holotype specimen PR76 are: quartz, Cr-V-bearing tremolite, and dioctahedral mica (muscovite-celadonite-chromphyllite-roscoelite), diopside-kosmochlor...
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Journal Article
Published: 01 January 2014
American Mineralogist (2014) 99 (1): 218–224.
... detailed description) for natalyite, florensovite, kalininite, magnesiocoulsonite, oxy-vanadium-dravite, oxy-chromium-dravite, vanadio-oxy-chromium-dravite, chromo-alumino-povondraite, batisivite, oxyvanite, and cuprokalininite. Minerals associated with the holotype specimen are: quartz, Cr-V-bearing...
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Journal Article
Published: 01 July 2014
American Mineralogist (2014) 99 (7): 1511–1518.
.... It is found in greenschist-facies conditions in association with quartz, celsian, apatite, sphalerite, pyrrhotite, galena, pyrite, zoltaiite, and batisivite. Greenwoodite occurs as small, disseminated semi-prismatic to tabular grains, as well as irregular grains intergrown with other phases, with grain size...
Journal Article
Published: 01 February 2024
American Mineralogist (2024) 109 (2): 359–373.
.... , Armbruster , T. , Galuskin , E.V. , Ushchapovskaya , Z.F. , Polekhovsky , Y.S. , Karmanov , N.S. , Kashaev , A.A. , and Barash , I.G. ( 2009 ) Batisivite, V 8 Ti 6 [Ba(Si 2 O)]O 28 , a new mineral species from the derbylite group . Geology of Ore Deposits , 50 , 565 – 573...
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