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![(a) Argentotetrahedrite-(Zn) (Attr-Zn) and tetrahedrite-(Zn) (Ttr-Zn) associated with argentotetrahedrite-(Cd) (Attr-Cd) replaced by acanthite (Aca) and galena (Gn), Johan de Deo vein, Rudno nad Hronom, back-scattered electron (BSE) image (holotype, P1P 8/2022). (b) Argentotetrahedrite-(Cd) (Attr-Cd) associated with pyrargyrite (Pyg) are replacing argentotetrahedrite-(Zn) (Attr-Zn). The association is rimmed by younger galena (Gn), Priečna vein, Rudno nad Hronom, BSE image (specimen number is PR 0751). Symbols based on Warr (2021).]()
![BSE images of tetrahedrite-(Zn) and argentotetrahedrite-(Zn) sulfosalts from the pre-gold association. a – large (about 1.2 mm) segregation of Fe-bearing tetrahedrite-(Zn) in quartz; b – fragment of Fig. 1a: lamellar inclusions of senarmontite in the outer part of the tetrahedrite-(Zn) grain; c – small subhedral grain of tetrahedrite-(Zn) in quartz matrix; d – intergrowth of tetrahedrite-(Zn) and galena; e – arsenopyrite grain in intergrowth with pyrite, surrounded by interstitial shapes of later mimetite, which also fills cracks in quartz; f – zoned crystal of argentotetrahedrite in mimetite, intergrown with arsenopyrite in quartz. Ttr-Zn, Fe – tetrahedrite Cu10(Zn,Fe)2(Sb,As)4S13; Gn – galena PbS; Sen – senarmontite Sb2O3; Attr-Fe,Zn – argentotetrahedrite Ag6(Cu4ZnFe)Sb4S13; Mim – mimetite Pb5[AsO4]3Cl; Apy – arsenopyrite FeAsS.]()
![Argentotetrahedrite-(Zn) from Lengenbach. (a) Tristetrahedral crystal, 1 mm in size, with dolomite. Collection H. Geuer, photo T. Raber. (b) Back-scattered electron (BSE) image of the same crystal. The red line indicates the grain selected for single-crystal X-ray diffraction study. (c) BSE image showing the chemical zoning of the grain used for the structural study. Red and blue circles indicate argentotetrahedrite-(Zn) and tetrahedrite-(Zn) spot analyses, respectively.]()
![Argentotetrahedrite-(Zn), anhedral grains up to 0.1 mm in length as seen in reflected light microscopy (a) and back-scattered electrons (b). The darker rims in (b) have a composition corresponding to the potential end-member argentotennantite-(Fe). The red box indicates the area where the grain used for single-crystal X-ray diffraction was extracted. Holotype material from Kremnica, Slovak Republic, catalogue number P1P 51/2020.]()
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![Reflectance curves for argentotetrahedrite-(Zn) from Kremnica, Lengenbach and Zvěstov compared with the curve for Ag-bearing tetrahedrite-(Zn) from Lengenbach.]()
![Argentotetrahedrite-(Zn) from Zvěstov, Czech Republic. Aggregates up to 0.1 mm in in size as seen in the BSE image. The lighter rims have a composition corresponding to kenoargentotetrahedrite-(Fe). The red box indicates the area where the grain used for single-crystal X-ray diffraction was extracted.]()
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![The relationships between Sb, Te, and As in the solid solutions of the tetrahedrite sulfosalts from the Maletoyvayam deposit; the red dashed line indicates the boundaries of mineral species; the thin black dashed line outlines the proposed immiscibility field according to [Biagioni et al., 2022]; argentotetrahedrite-(Zn,Fe) – solid solutions between argentotetrahedrite-(Zn) and argentotetrahedrite-(Fe), here and below. 1 – ideal compositions of sulfosalts; 2 – goldfieldite; 3 – stibiogoldfieldite; 4 – tetrahedrite-(Zn, Fe); 5 – argentotetrahedrite-(Zn,Fe); 6 – arsenogoldfieldite.]()
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Journal Article
Argentotetrahedrite-(Zn), Ag 6 (Cu 4 Zn 2 )Sb 4 S 13 , a new member of the tetrahedrite group Available to Purchase
Journal: Mineralogical Magazine
Published: 07 March 2022
Mineralogical Magazine (2022) 86 (2): 319–330.
...Jiří Sejkora; Cristian Biagioni; Martin Števko; Thomas Raber; Philippe Roth; Luboš Vrtiška Abstract Argentotetrahedrite-(Zn), Ag 6 (Cu 4 Zn 2 )Sb 4 S 13 , has been approved as a new mineral species by the International Mineralogical Association Commission on New Minerals, Nomenclature...
FIGURES
Journal Article
Rozhdestvenskayaite Ag 10 Zn 2 Sb 4 S 13 and argentotetrahedrite Ag 6 Cu 4 (Fe 2+ ,Zn) 2 Sb 4 S 13 : two Ag-dominant members of the tetrahedrite group Available to Purchase
Journal: European Journal of Mineralogy
Publisher: GeoScienceWorld Journals
Published: 01 November 2018
European Journal of Mineralogy (2018) 30 (6): 1163–1172.
...Mark D. Welch; Chris J. Stanley; John Spratt; Stuart J. Mills We report the characterisation of two new tetrahedrite-group minerals, rozhdestvenskayaite, Ag 10 Zn 2 Sb 4 S 13 , and argentotetrahedrite, Ag 6 Cu 4 (Fe 2+ ,Zn) 2 Sb 4 S 13 , and discuss the structural chemistry of the Ag-rich...
FIGURES
Includes: Supplemental Content
Image
(a) Argentotetrahedrite-(Zn) (Attr-Zn) and tetrahedrite-(Zn) (Ttr-Zn) assoc... Available to Purchase
in Argentotetrahedrite-(Cd), Ag 6 (Cu 4 Cd 2 )Sb 4 S 13 , a new member of the tetrahedrite group from Rudno nad Hronom, Slovakia.
> Mineralogical Magazine
Published: 19 December 2022
Fig. 2. (a) Argentotetrahedrite-(Zn) (Attr-Zn) and tetrahedrite-(Zn) (Ttr-Zn) associated with argentotetrahedrite-(Cd) (Attr-Cd) replaced by acanthite (Aca) and galena (Gn), Johan de Deo vein, Rudno nad Hronom, back-scattered electron (BSE) image (holotype, P1P 8/2022). (b) Argentotetrahedrite
Image
![BSE images of tetrahedrite-(Zn) and argentotetrahedrite-(Zn) sulfosalts from the pre-gold association. a – large (about 1.2 mm) segregation of Fe-bearing tetrahedrite-(Zn) in quartz; b – fragment of Fig. 1a: lamellar inclusions of senarmontite in the outer part of the tetrahedrite-(Zn) grain; c – small subhedral grain of tetrahedrite-(Zn) in quartz matrix; d – intergrowth of tetrahedrite-(Zn) and galena; e – arsenopyrite grain in intergrowth with pyrite, surrounded by interstitial shapes of later mimetite, which also fills cracks in quartz; f – zoned crystal of argentotetrahedrite in mimetite, intergrown with arsenopyrite in quartz. Ttr-Zn, Fe – tetrahedrite Cu10(Zn,Fe)2(Sb,As)4S13; Gn – galena PbS; Sen – senarmontite Sb2O3; Attr-Fe,Zn – argentotetrahedrite Ag6(Cu4ZnFe)Sb4S13; Mim – mimetite Pb5[AsO4]3Cl; Apy – arsenopyrite FeAsS.](https://gsw.silverchair-cdn.com/gsw/Content_public/Journal/rgg/66/5/10.2113_RGG20244818/1/s_tolstykh_page_4_1.jpeg?Expires=2147483647&Signature=wK8XGoZeKpa9Wy9qnR2XDtqz6cJgsTf~aamFK65dxt4-Jax9kRNh494j-rGDmwl2pilwAxFzzhp8DUy1g4tPPPA6F9lPHlCvrbu9gZct9~z9wVIbiKGwRKOTE0Zs4X3pi~zQlXobrpXvvrV6umLNE~r46ZbmfUWHrkW0V~kNqupeDZ0lm12m9vvpAWtmDyfz6Hp74Vzc7m6wa~YVb-p9umKHhPwhVQSQbivCBRTmTawVD6FHurxFeYrihqrv6j35ZBFWc2nBL0cM8eqFPb7IGMov4jOD-DHKuF7YM8QZfH7DecfdklcMuJ7rzn3EXZkPbNnX3fLpe7kbB6VXrt6~4Q__&Key-Pair-Id=APKAIE5G5CRDK6RD3PGA)
BSE images of tetrahedrite-(Zn) and argentotetrahedrite-(Zn) sulfosalts fro... Available to Purchase
in EVOLUTION OF COMPOSITION OF TETRAHEDRITE AND ENARGITE SULFOSALTS IN THE MALETOYVAYAM EPITHERMAL Au-Ag DEPOSIT ( Kamchatka )
> Russian Geology and Geophysics
Published: 01 May 2025
Fig. 1. BSE images of tetrahedrite-(Zn) and argentotetrahedrite-(Zn) sulfosalts from the pre-gold association. a – large (about 1.2 mm) segregation of Fe-bearing tetrahedrite-(Zn) in quartz; b – fragment of Fig. 1 a : lamellar inclusions of senarmontite in the outer part of the tetrahedrite
Image
Argentotetrahedrite-(Zn) from Lengenbach. (a) Tristetrahedral crystal, 1 mm... Available to Purchase
in Argentotetrahedrite-(Zn), Ag 6 (Cu 4 Zn 2 )Sb 4 S 13 , a new member of the tetrahedrite group
> Mineralogical Magazine
Published: 07 March 2022
Fig. 3. Argentotetrahedrite-(Zn) from Lengenbach. (a) Tristetrahedral crystal, 1 mm in size, with dolomite. Collection H. Geuer, photo T. Raber. (b) Back-scattered electron (BSE) image of the same crystal. The red line indicates the grain selected for single-crystal X-ray diffraction study. (c
Image
Argentotetrahedrite-(Zn), anhedral grains up to 0.1 mm in length as seen in... Available to Purchase
in Argentotetrahedrite-(Zn), Ag 6 (Cu 4 Zn 2 )Sb 4 S 13 , a new member of the tetrahedrite group
> Mineralogical Magazine
Published: 07 March 2022
Fig. 1. Argentotetrahedrite-(Zn), anhedral grains up to 0.1 mm in length as seen in reflected light microscopy (a) and back-scattered electrons (b). The darker rims in (b) have a composition corresponding to the potential end-member argentotennantite-(Fe). The red box indicates the area where
Image
Compositional data for argentotetrahedrite-(Zn) from Kremnica (grain 2) and... Available to Purchase
in Argentotetrahedrite-(Zn), Ag 6 (Cu 4 Zn 2 )Sb 4 S 13 , a new member of the tetrahedrite group
> Mineralogical Magazine
Published: 07 March 2022
Table 3. Compositional data for argentotetrahedrite-(Zn) from Kremnica (grain 2) and Zvěstov. Kremnica ( n = 17) Zvěstov ( n = 93) Standard wt.% range e.s.d. wt.% range e.s.d. Cu 23.01 22.77–23.26 0.13 23.65 23.09–24.13 0.24 chalcopyrite Ag 21.12
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Comparison of argentotetrahedrite-(Zn) samples and other members of the fre... Available to Purchase
in Argentotetrahedrite-(Zn), Ag 6 (Cu 4 Zn 2 )Sb 4 S 13 , a new member of the tetrahedrite group
> Mineralogical Magazine
Published: 07 March 2022
Table 10. Comparison of argentotetrahedrite-(Zn) samples and other members of the freibergite series. Argentotetrahedrite-(Zn) Argentotetrahedrite-(Fe) Kenoargentotetrahedrite-(Zn) Kenoargentotetrahedrite-(Fe) Kremnica Lengenbach Zvěstov Yakutia Keno Hill Yindongpo
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Weighted bond-valence sums (in vu) in argentotetrahedrite-(Zn). ... Available to Purchase
in Argentotetrahedrite-(Zn), Ag 6 (Cu 4 Zn 2 )Sb 4 S 13 , a new member of the tetrahedrite group
> Mineralogical Magazine
Published: 07 March 2022
Table 9. Weighted bond-valence sums (in vu) in argentotetrahedrite-(Zn). Site M (1) M (2a) M (2b) X (3) Σanions Theoretical Kremnica S(1) 2×→ 0.36 ×4↓ 0.24 ×2↓ 2×→ 0.06 ×2 1.02 ×3↓ 2.10 2.00 S(2) 6×→ 0.30 12×→ 0.10 3.00 2.00 Σcations
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Reflectance curves for argentotetrahedrite-(Zn) from Kremnica, Lengenbach a... Available to Purchase
in Argentotetrahedrite-(Zn), Ag 6 (Cu 4 Zn 2 )Sb 4 S 13 , a new member of the tetrahedrite group
> Mineralogical Magazine
Published: 07 March 2022
Fig. 2. Reflectance curves for argentotetrahedrite-(Zn) from Kremnica, Lengenbach and Zvěstov compared with the curve for Ag-bearing tetrahedrite-(Zn) from Lengenbach.
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Argentotetrahedrite-(Zn) from Zvěstov, Czech Republic. Aggregates up to 0.1... Available to Purchase
in Argentotetrahedrite-(Zn), Ag 6 (Cu 4 Zn 2 )Sb 4 S 13 , a new member of the tetrahedrite group
> Mineralogical Magazine
Published: 07 March 2022
Fig. 4. Argentotetrahedrite-(Zn) from Zvěstov, Czech Republic. Aggregates up to 0.1 mm in in size as seen in the BSE image. The lighter rims have a composition corresponding to kenoargentotetrahedrite-(Fe). The red box indicates the area where the grain used for single-crystal X-ray diffraction
Image
Calculated powder X-ray diffraction data for argentotetrahedrite-(Zn).* ... Available to Purchase
in Argentotetrahedrite-(Zn), Ag 6 (Cu 4 Zn 2 )Sb 4 S 13 , a new member of the tetrahedrite group
> Mineralogical Magazine
Published: 07 March 2022
Table 4. Calculated powder X-ray diffraction data for argentotetrahedrite-(Zn).* I calc d calc h k l I calc d calc h k l 24 7 . 460 1 1 0 6 1.926 5 2 1 1 4.307 2 1 1 35 1 . 865 4 4 0 2 3.730 2 2 0 3 1.809 4 3 3 1
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Selected bond distances (Å) for argentotetrahedrite-(Zn). Site ... Available to Purchase
in Argentotetrahedrite-(Zn), Ag 6 (Cu 4 Zn 2 )Sb 4 S 13 , a new member of the tetrahedrite group
> Mineralogical Magazine
Published: 07 March 2022
Table 7. Selected bond distances (Å) for argentotetrahedrite-(Zn). Site Kremnica Lengenbach Zvěstov M (1)–S(1)×4 2.3386(19) 2.3475(15) 2.342(2) M (2a)–S(2) 2.298(7) 2.292(5) 2.259(12) M (2a)–S(1)×2 2.386(5) 2.363(4) 2.422(9) M (2b)–S(2) 2.284(17) 2.263
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Reflectance data for argentotetrahedrite-(Zn) from Kremnica, Lengenbach, an... Available to Purchase
in Argentotetrahedrite-(Zn), Ag 6 (Cu 4 Zn 2 )Sb 4 S 13 , a new member of the tetrahedrite group
> Mineralogical Magazine
Published: 07 March 2022
Table 1. Reflectance data for argentotetrahedrite-(Zn) from Kremnica, Lengenbach, and Zvěstov.* R (%) λ (nm) R (%) λ (nm) Kremnica Lengenbach Zvěstov Kremnica Lengenbach Zvěstov 400 31.0 30.6 30.7 560 29.9 29.7 29.9 420 31.0 30.5 30.7 580 29.8
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Compositional data for argentotetrahedrite-(Zn) from Kremnica (holotype sam... Available to Purchase
in Argentotetrahedrite-(Zn), Ag 6 (Cu 4 Zn 2 )Sb 4 S 13 , a new member of the tetrahedrite group
> Mineralogical Magazine
Published: 07 March 2022
Table 2. Compositional data for argentotetrahedrite-(Zn) from Kremnica (holotype sample) and Lengenbach (cotype sample). Kremnica ( n = 13) Lengenbach ( n = 14) Standard wt.% range e.s.d. wt.% range e.s.d. Cu 23.97 23.82–24.18 0.12 23.99 23.58–24.28 0.18
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![The relationships between Sb, Te, and As in the solid solutions of the tetrahedrite sulfosalts from the Maletoyvayam deposit; the red dashed line indicates the boundaries of mineral species; the thin black dashed line outlines the proposed immiscibility field according to [Biagioni et al., 2022]; argentotetrahedrite-(Zn,Fe) – solid solutions between argentotetrahedrite-(Zn) and argentotetrahedrite-(Fe), here and below. 1 – ideal compositions of sulfosalts; 2 – goldfieldite; 3 – stibiogoldfieldite; 4 – tetrahedrite-(Zn, Fe); 5 – argentotetrahedrite-(Zn,Fe); 6 – arsenogoldfieldite.](https://gsw.silverchair-cdn.com/gsw/Content_public/Journal/rgg/66/5/10.2113_RGG20244818/1/s_tolstykh_page_7_1.jpeg?Expires=2147483647&Signature=fT6Q9fBZ0RJSYfM6InXPYFeKWlv3oWMZ-s-xPNGJTaUk7OE7GptuJalAbSPm-u5UBEEwmHhLQeXTiTuZMQjTThz~XmiMYkDMM-kE-pA-dTdMEEkF9uBhCm0oY6vl5LX02WfKjB-MBRyQnQsA9Zbd80trxbOzOiXfTm-gBN3mq6skDv5fEgNMu2qI7cSiRzrpCwLrObi~TKDVYWMNR4cpHG-0IPvBE6wwz1MgBeMIKZVLRm-qbVbh-hhbr2ld9atdcmOnEqbNt7PdLfX3xruYXSxkRjwe34pbM3WgR-wEx3xRP8B8xvbOHDcVGxrlsME1fOlhmG9l9~UYPmIhRnpThw__&Key-Pair-Id=APKAIE5G5CRDK6RD3PGA)
The relationships between Sb, Te, and As in the solid solutions of the tetr... Available to Purchase
in EVOLUTION OF COMPOSITION OF TETRAHEDRITE AND ENARGITE SULFOSALTS IN THE MALETOYVAYAM EPITHERMAL Au-Ag DEPOSIT ( Kamchatka )
> Russian Geology and Geophysics
Published: 01 May 2025
., 2022 ]; argentotetrahedrite-(Zn,Fe) – solid solutions between argentotetrahedrite-(Zn) and argentotetrahedrite-(Fe), here and below. 1 – ideal compositions of sulfosalts; 2 – goldfieldite; 3 – stibiogoldfieldite; 4 – tetrahedrite-(Zn, Fe); 5 – argentotetrahedrite-(Zn,Fe); 6
Journal Article
Argentotetrahedrite-(Cd), Ag 6 (Cu 4 Cd 2 )Sb 4 S 13 , a new member of the tetrahedrite group from Rudno nad Hronom, Slovakia. Available to Purchase
Journal: Mineralogical Magazine
Published: 19 December 2022
Mineralogical Magazine (2023) 87 (2): 262–270.
...Fig. 2. (a) Argentotetrahedrite-(Zn) (Attr-Zn) and tetrahedrite-(Zn) (Ttr-Zn) associated with argentotetrahedrite-(Cd) (Attr-Cd) replaced by acanthite (Aca) and galena (Gn), Johan de Deo vein, Rudno nad Hronom, back-scattered electron (BSE) image (holotype, P1P 8/2022). (b) Argentotetrahedrite...
FIGURES
Journal Article
EVOLUTION OF COMPOSITION OF TETRAHEDRITE AND ENARGITE SULFOSALTS IN THE MALETOYVAYAM EPITHERMAL Au-Ag DEPOSIT ( Kamchatka ) Available to Purchase
Journal: Russian Geology and Geophysics
Publisher: Novosibirsk State University
Published: 01 May 2025
Russ. Geol. Geophys. (2025) 66 (5): 613–629.
...Fig. 1. BSE images of tetrahedrite-(Zn) and argentotetrahedrite-(Zn) sulfosalts from the pre-gold association. a – large (about 1.2 mm) segregation of Fe-bearing tetrahedrite-(Zn) in quartz; b – fragment of Fig. 1 a : lamellar inclusions of senarmontite in the outer part of the tetrahedrite...
FIGURES
Journal Article
Argentopolybasite, Ag 16 Sb 2 S 11 , a new member of the polybasite group Open Access
Journal: Mineralogical Magazine
Published: 17 February 2023
Mineralogical Magazine (2023) 87 (3): 382–395.
... (pseudo)hexagonal tabular crystals up to 4 mm in size or as complex crystalline aggregates and groups up to 5 mm in size in cavities of quartz. It is associated with pyrargyrite, polybasite, stephanite, miargyrite, rozhdestvenskayaite-(Zn), argentotetrahedrite-(Zn), naumannite, gold and pyrite...
FIGURES
Journal Article
New Mineral Names Free
Journal: American Mineralogist
Publisher: Mineralogical Society of America
Published: 01 August 2023
American Mineralogist (2023) 108 (8): 1571–1572.
...Aaron J. Celestian Abstract This issue of New Mineral Names provides a summary of the newly described minerals donowensite, mikehowardite, bortolanite, fluorsigaiite, alumolukrahnite, ferro-ferri-katophorite, tomsquarryite, and argentotetrahedrite-(Zn). Bortolanite ( Day et al. 2022 ), ideally Ca...
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