ABSTRACT Much of the early prograde history in metamorphic rocks is lost due to overprinting at near-peak conditions or through retrograde modification during exhumation. Fortunately, inclusions encapsulated in rigid porphyroblasts may preserve a record of early burial conditions. Quartz inclusions in garnet porphyroblasts from the Strafford Dome, eastern Vermont, have homogeneous Ti concentrations ([Ti]) that differ from matrix quartz, which retains a history of Si-liberating metamorphic reactions and fluid influx. We applied growth-composition models to evaluate potential processes associated with Ti partitioning in quartz before encapsulation in garnet, including a model for constant-volume growth of quartz due to mineral dissolution-transfer processes and growth as a result of Si-liberating diagenetic and metamorphic reactions. Because these processes typically occur at low temperatures, quartz with exceedingly low [Ti] (<<1 ppm) would be formed and cannot account for the homogeneous Ti distribution at concentrations between 2.5 and 5 ppm observed in the sample. This suggests that chemical reequilibration through dynamic recrystallization must have taken place prior to encapsulation in garnet. Analysis of fluid and graphite inclusions with Raman spectroscopy in different microstructural settings allowed the characterization of fluid composition and temperature of microstructure development early in the prograde history. The findings from this study exemplify the utility of garnet hosts to shield inclusion minerals from chemical modification and recrystallization during later events. As such, they provide a window into the early stages of orogenesis and provide insights concerning the mechanisms controlling equilibration of quartz.

The northwestern New England and adjacent Quebec region is an area of 30,000 square miles on the northwest side of the northeastern Appalachian Mountains belt, and extends into the adjacent Hudson, Champlain, and St. Lawrence Valleys to the northwest. It is athwart a major change in trend of this belt from northerly to northeasterly. The synthesis is a rationale of the tectonic relations of this region, discussed in chronological order. The Precambrian basement, exposed at the core of a Paleozoic anticlinorium in the mountain belt, is made up of complexly deformed diaphthoritic miogeosynclinal rocks intruded by granitic plutons and pegmatite dikes. The exposed rocks are part of a northeast-trending Precambrian mobile shelf at least 300 miles wide that includes a wide belt to the northwest in the North American craton. The lower (Cambrian and Ordovician) and middle (Silurian and Devonian) Paleozoic orthogeosyncline, which coincides mainly with the Appalachian belt, includes a broad eugeosynclinal zone, a miogeosynclinal zone to the northwest and probably also to the southeast of the eugeosynclinal zone, several geanticlines, and a quasi-cratonic belt; it thus contrasts with the broadly miogeosynclinal Precambrian rocks of the basement. The eugeosynclinal deposits, whose maximum thickness is more than 50,000 feet, average at least three times the thickness of those in the miogeosynclinal zone. Pelitic and semipelitic rocks dominate the upper deposits and lap over geanticlines, a quasi-cratonic belt, and the margin of the craton. The sources of sediments include cratonal areas, geanticlines that formed tectonic islands, and volcanic islands. The transition between the miogeosynclinal and eugeosynclinal zones is one of sedimentary facies and thickness change, and of stratigraphic convergence and unconformity. In the lowest Paleozoic rocks the transition is west and north-west, respectively, of the Green and Sutton Mountains. The miogeosynclinal zone is missing in Quebec northwest of the northern Sutton Mountains and the eugeosynclinal zone extends to the northwestern margin of the orthogeosyncline. The belt of transition, however, moved southeast in younger rocks, so that in the middle Paleozoic rocks it lies between the Green, Sutton, and Notre Dame Mountains and the Connecticut and St. Johns Rivers. Unconformities indicate stillstand in the miogeosynclinal zone, and general uplift of the northwestern part of the orthogeosyncline, followed by subaerial denudation of the geanticlines in both the eugeosynclinal and the miogeosynclinal zones and by repeated geosynclinal folding. The unconformities are within the lower Paleozoic (especially beneath the Middle Ordovician), are the most extensive between the lower and middle Paleozoic, and are within the middle Paleozoic (especially beneath the Lower Devonian). Geanticlines, two of which coincide with gravity highs, are recognized by unconformable overlap and convergence of bedded rock units toward their axes. The lower Paleozoic Vermont-Quebec geanticline is northwest of the Green and Sutton Mountains in northwestern Vermont and neighboring parts of Quebec, but to the south and northeast it swings more into line with the mountains. It coincides with the lower Paleozoic belt of northwest-southeast transition from the miogeosynclinal to the eugeosynclinal zone, except near the north end of the Sutton Mountains where it trends into the eugeosynclinal zone. The lower Paleozoic Stoke Mountain geanticline coincides with the Stoke Mountains in Quebec, contains eugeosynclinal lower Paleozoic rocks, and is a little north-west of the belt of transition southeastward between the middle Paleozoic miogeosynclinal and eugeosynclinal zones. The lower and middle Paleozoic Somerset geanticline, which nearly coincides with the upper Connecticut River valley and the Boundary Mountains between Quebec and Maine, is cored by rocks of the lower Paleozoic eugeosynclinal zone and is truncated by the unconformity beneath middle Paleozoic rocks. The distribution of the preorogenic igneous rocks of the eugeosynclinal zone reflects the southeastward retreat of this zone during the lower and middle Paleozoic. These rocks include mafic to intermediate metavolcanic and hypabyssal bodies, prevailingly of oceanic theoleiitic composition, and mafic and ultramafic plutons. The plutons reach Lower Cambrian to possibly Middle Ordovician stratigraphic levels. The eugeosynclinal zone, and to a lesser extent the miogeosynclinal zone, are sites of regional metamorphism, shown most universally by the foliation that began to form with compaction of the shales. Isograds climb from low stratigraphic levels in the geanticlines to higher stratigraphic levels in the intervening geosynclinal troughs, showing a direct correlation between the thickness of bedded rocks and metamorphic intensity. Zones of highest grade metamorphism coincide with uplifts, but were probably originally deepest in the geosynclines. Undeformed garnet and staurolite-kyanite coincide with domes and arches, and deformed garnet and chloritoid-kyanite zones with anticlines. Some staurolite and sillimanite zones adjoin granitic plutons, but others are not so associated. Retrograde metamorphic effects in the Precambrian basement include replacement of garnet and hornblende by biotite and chlorite, and sillimanite by muscovite; these effects are caused by folding of the dry basement with the wet Paleozoic. In wet Paleozoic rocks, midway between the dry terranes of the basement and the domes and arches, garnet was replaced by chlorite and kyanite was replaced by muscovite as a result of uplift, denudation and cooling. In Quebec, an exogeosyncline containing about 5000 feet of rocks overlies the northwestern part of the orthogeosyncline and the adjoining craton north-west of the Sutton Mountains. This is a secondary geosyncline northwest of the Vermont-Quebec geanticline. It contains Upper Ordovician sandstone, shale, and limestone which overlie shale at the top of the lower Paleozoic miogeo-synclinal zone but which are eroded from the eugeosynclinal zone. The orthogeosyncline swings through the wide bend of the northwesterly bulge of the New England salient in northern New England and adjacent Quebec—all facies zones and tectonic features show a similar salient. It is deepened near the axis of the salient in a transverse trough that contains as much as 80,000 feet of strata. This section thins by stratigraphic convergence to less than 50,000 feet toward the flanks of the salient. The rocks are most varied in the salient, but thick sections of mafic volcanic rocks and carbonaceous pelites are characteristic. Similar (passive and flexural flow) folds confined to the lower and middle Paleozoic bedded rocks and commonly overturned to the northwest toward the craton, are of an early regime of variously oriented folds. Cross folds, chiefly minor folds, trend northwest at right angles to the northeast structural trends. Longitudinal folds, slides, intrastratal intrusions, and syntectonic bodies of ultramafic rock that intruded in the solid state parallel the latter trends. Oblique folds parallel the flanks of the New England salient and swing into continuity with the longitudinal folds northeast and south of the salient and at its axis. The largest major longitudinal folds are thousands of feet above the Precambrian basement. The recumbent middle Paleozoic Skitchewaug nappe, the best known of the major longitudinal folds, is rooted to the southeast in the eugeosynclinal zone. Other recumbent folds exist, but their relations are more controversial. A middle Paleozoic intrastratal diapiric fold has been described west of the Skitchewaug nappe. Major longitudinal folds northwest of the Stoke Mountain geanticline underlie a Middle Ordovician unconformity; others in the same area are truncated by a pre-Silurian unconformity. Longitudinal folds on the Vermont-Quebec geanticline in the vicinity of the international boundary are nearly upright rather than overturned to the northwest. The lower Paleozoic Taconic slide is beneath Cambrian and Lower and Middle Ordovician eugeosynclinal rocks in the Taconic klippe and above autochthonous miogeosynclinal rocks of the same age west of the Vermont-Quebec geanticline and south of the New England salient. The oblique folds face southwest on the south flank of the New England salient in general harmony with the west-facing longitudinal folds, but on the northeast flank of the salient they face southeast. The largest of the oblique folds, like the large longitudinal folds, are thousands of feet above the basement. The early folds and slides were produced by laminar flow and slip and by minimal flexing and thrusting, principally to the northwest. Several episodes of uplift in the eugeosynclinal deposits are probably accountable. The New England salient provided a basement framework that deflected, blocked, or reversed the northwestward movements to form especially the oblique folds and possibly the cross folds. The westward movement of the Taconic slide was probably assisted by maintenance of fluid pore pressure in the root zone near the top of the Vermont-Quebec geanticline by means of westward migration of water expelled from the thick eugeosynclinal deposits to the east during metamorphism. The semiconcordant ultramafic, mafic, and intermediate intrusive rocks in the eugeosynclinal zone are subparallel to the foliation of the bedded rocks and syntectonic with the early longitudinal folds. The ultramafic rocks were emplaced in a solid and cool state, after transport that is interpreted as northwestward movement as the enclosing strata were folded. The less widely distributed gabbro and diorite, which lost their mobility with crystallization from magma, participated less actively in the folding. Concordant calc-alkalic plutons, also emplaced in eugeosynclinal rocks, are synkinematic magmatic features that are less commonly parallel to foliation than are the semiconcordant intrusive rocks and are truncated upward by unconformities at successively higher levels in the direction of southeastward offlap of the eugeosynclinal zone. Regional foliation, subparallel to both the axial surfaces and limbs and the axial-plane cleavage of the early folds, approaches parallelism with the bedding in most places inasmuch as early minor folds are sparse. Thus restored, the foliation conforms to the geosynclines and geanticlines, masking the Taconic slide. Sericitic mica and fine-grained chlorite, the principal foliate minerals, are features of low-grade regional metamorphism that progressed upward as the eugeosynclinal deposits accumulated, as shown by successive unconformities that mark sharp upward decreases in the foliate condition of the bedded rocks. A longitudinal tract of middle Paleozoic domes and arches, characterized by drag folds that face downdip and some of which are cored by Precambrian basement rocks, trends northeastward across the Vermont-Quebec geanticline in southern Vermont. Largest in this tract is the Strafford-Willoughby arch which extends about equal distances northeast and southwest of the axis of the New England salient. The reverse drag folds are in the regional foliation, which near the crest of the domes and arches is obliterated by a new foliation that parallels the axial surfaces of the drag folds. The reverse drags indicate that the domes and arches were raised by vertical upward pressure, probably of buoyant rock beneath. Grossly parallel (concentric) or flexural folds that trend northeast with the Appalachian structural trends, and the largest of which include the Precambrian basement, are of a late, middle Paleozoic regime. Smaller and variously oriented steeply plunging folds of this regime are above the basement. The principal form surfaces of these folds are the regional foliation in the eugeosynclinal zone and the bedding in the miogeosynclinal zone. Thrust faults, also of this regime, parallel the trend of the major folds. Axial-plane cleavage varies from fracture cleavage through crenulation cleavage to slip cleavage and slip-cleavage schistosity. The parallel fold style gives way to similar (passive-slip and flow) folds in parts of the eugeosynclinal zone. In these parts the form surfaces are offset on the axial-plane cleavage in directions both the same and the opposite of that of flexural drag folds, and the offsets opposite in sense predominate, accentuating the amplitude of the folds. Mineral lineations, less commonly slickensides, and some minor folds plunge downdip on the bedding and bedding foliation near thrust faults and on steep homoclinal limbs of major folds. The late folds form anticlinoria that rudely coincide with the previously formed geanticlines, and synclinoria that coincide with the intervening and adjoining geosynclinal troughs. The axial surfaces of most folds in and south of the New England salient dip steeply southeast and the folds face northwest, but to the north of the axis of the salient the folds are nearly upright. The folds are also nearly upright in eastern Vermont, New Hampshire, and neighboring areas The orientation of the axial surfaces of the folds changes gradually to subparallel with the flanks and tops of the domes and arches as the latter are approached. The folds in the northwestern part of the orthogeosyncline are tipped over to the northwest toward the craton, and the thrust faults in this same belt dip east in the same direction as the axial surfaces of the folds. The late folds of first magnitude are, from northwest to southeast, the Middlebury-Hinesburg-St. Albans synclinorium, the Green Mountain-Sutton Mountain anticlinorium, the Connecticut Valley-Gaspé synclinorium, the Bronson Hill-Boundary Mountain anticlinorium, and the Merrimack synclinorium. The Middlebury-Hinesburg-St. Albans synclinorium is a major foreland fold in lower Paleozoic miogeosynclinal rocks and correlative allochthonous eugeosynclinal rocks of the Taconic klippe. This synclinorium is bordered to the west and east by thrust faults, which are most extensive on the south flank of the New England salient. The Green Mountain-Sutton Mountain anticlinorium, containing chiefly lower Paleozoic eugeosynclinal rocks, coincides with the Vermont-Quebec geanticline in the Green Mountains in central Vermont and the Notre Dame Mountains in Quebec, but near the axis of the New England salient it is southeast of the geanticline. The Connecticut Valley-Gaspé synclinorium, which contains middle Paleozoic rocks transitional from the miogeosynclinal to the eugeosynclinal zone, coincides with a geosynclinal trough between the Stoke Mountain and Somerset geanticlines and southeast of the southern part of the Vermont-Quebec geanticline. The configuration of the folds in the synclinorium is determined principally by the domes and arches near the synclinorial axis The Bronson Hill-Boundary Mountain anticlinorium, which contains both lower and middle Paleozoic rocks, coincides in its northern parts with the Somerset geanticline. The Merrimack synclinorium to the southeast, which also contains lower and middle Paleozoic rocks, is a relic of a geosynclinal trough southeast of the Somerset geanticline. The late folds and thrust faults were probably produced by subhorizontal movements as part of outward spread from the rising domes and arches. Rocks moved from the southeast into the New England salient. Steeply plunging minor folds, free from basement control, evolved in response to horizontal adjustments between major folds, and domes and arches in the thick eugeosynclinal section in the salient. Thrust faults evolved in the miogeosynclinal rocks south of the axis of the salient. The resulting counterclockwise movement of the thrust slices and their included folds and the folded rocks to the east of them in the eugeosynclinal zone continued until the present northward trend was achieved. Monoclinal flexures and related kink layers, which dip northwest and parallel to which rock to the northwest was displaced upward and to the southeast, have been recognized in north-central and northwestern Vermont. Joints include systematically oriented undeformed planar sets that dip almost vertically and cross the trend of the longitudinal folds and thrust faults at large angles. They also include less extensive nonsystematic joints that are curved or irregular and that end against the systematic joints. Some conjugate joint sets, the bisectrices of whose acute angles trend at right angles to the axes of the longitudinal folds, are possibly shear joints. Tension produced by bending of folds into the New England salient seems a doubtful cause of the joints, especially in the thick and deeply confined rocks of the eugeosynclinal zone. Discordant and commonly nonfoliate middle Paleozoic calc-alkalic plutons are postkinematic magmatic features randomly emplaced in rocks deformed in both the early and late folds. They are most abundant near the axis of the New England salient where it crosses the eugeosynclinal zone. Superimposed unconformably on the southeastern part of the orthogeosynclinal belt is an epieugeosyncline, containing upper Paleozoic clastic coal-bearing rocks. Before being eroded it probably covered wider areas of the eugeosynclinal zone, especially in the Merrimack synclinorium. Systems of early Mesozoic high-angle faults, made up of nearly parallel longitudinal sets, strike north-northeast south of the axis of the New England salient and northeast north of the salient axis, parallel to the trends of the late longitudinal folds. Faults in the foreland belt of the Champlain-St. Lawrence Valley are downthrown to the southeast of domal structural features, and others in the Connecticut Valley are downthrown mainly to the northwest of similar features. Lower Mesozoic terrestrial clastic and mafic volcanic (and hypabyssal) rocks unconformably overlie the eugeosynclinal zone and the epieugeosynclines (in taphrogeosynclines bounded by the high-angle faults) in southern New England and the Maritime Provinces. Discordant and nonfoliate Mesozoic alkalic plutons are in curvilinear tracts that transect both the orthogeosynclinal belt and the craton. Dike rocks, also alkalic, are associated with the plutons and occur widely in areas between the plutons. The chronology of the region is supported by biostratigraphic, radiometric, and structural data punctuated by unconformities. The Precambrian chronologic record is inherently scanty. Metasedimentary basement rocks exposed in the Green Mountain-Sutton Mountain anticlinorium in Vermont provide late Precambrian radiometric ages and a regional metamorphic overprint dating from about a billion years ago. Comparable metasedimentary rocks in the basement of the Adirondack Mountains were deposited in the late Precambrian. Pegmatites provide radiometric ages about the same as those of the metamorphic overprint, which records erosional unloading and cooling that restarted the potassium-argon systems about 0.4 b.y. before the end of the Precambrian. The earliest Paleozoic rocks, which are assigned to the Cambrian(?), overlie the Precambrian basement unconformably and are overlain conformably by miogeosynclinal strata containing fossils of Early, Middle, and Late Cambrian and Early and Middle Ordovician age. All epochs of the Cambrian and Ordovician are represented in the eugeosynclinal zone, and Late Ordovician fossils are found in the exogeosyncline. Potassium-argon radiometric values corresponding to Middle and Late Ordovician are mostly hybrids, between Cambrian to Early Ordovician metamorphic dates and the dates of widespread middle Paleozoic metamorphic overprints that with yet later overprints, have been revealed by Rb-Sr whole-rock isochron dating. Granitic plutons emplaced in Middle Ordovician rocks have yielded Middle or Late Ordovician Rb-Sr whole-rock isochron ages. Quasi-cratonic middle Paleozoic strata, eroded from the Champlain-St. Lawrence Valley belt, were probably Upper Silurian or higher. Chiefly in the miogeosynclinal zone, or in comparable thin lithofacies, southeast of the Green Mountain-Sutton Mountain anticlinorium, are Early, Middle, and Late Silurian and Early and Middle Devonian fossils. The middle Paleozoic K-Ar values suggest mainly the time of metamorphism and several are probably hybrids of early dates and true Devonian dates. Southeast of the belt of rocks of hybrid ages is a belt that shows true K-Ar dates of Middle (?) Devonian Acadian metamorphism and deformation about 360 m.y. ago; this belt is without later (Appalachian?) metamorphic overprint, contains Early Devonian fossils, and its tightly folded strata are overlain unconformably by gently flexed strata of Middle Devonian age. Discordant calc-alkalic granitic plutons of comparable radiometric age transect some of the late folds. Rb-Sr whole-rock and Pb/alpha determinations to the southeast in the area of the post-Devonian overprint approximate the Acadian metamorphic date. The late Paleozoic chronology in the northwestern New England and Quebec region is limited to a middle Permian metamorphic overprint with a K-Ar age of 250 ± 10 m.y. in the Merrimack synclinorium and environs. Unmetamorphosed felsic volcanic rocks that lie unconformably on the metamorphic rocks are possibly of Permian age. If this age is correct, the unconformity marks the Appalachian orogeny. The Mesozoic chronology is furnished by high-angle faults that bound the Late Triassic taphrogeosynclinal deposits in southern New England, and by alkalic intrusives of various radiometric ages (96 m.y.-to-180 m.y.), that intersect or are transected by the faults. The Cenozoic chronology is recorded by valleys and uplands produced by a continued selective downwasting, by Tertiary residual deposits containing lignite that were let down into valleys formed partly by solution of carbonate rocks, and by various Quaternary features related principally to glaciation. The orthogeosyncline was formed in the earliest Paleozoic or possibly the latest Precambrian. The Vermont-Quebec geanticline started to form during the Cambrian by tectonic stillstand relative to subsiding adjacent geosynclinal troughs; other geanticlines probably first appeared in the Early to Middle Ordovician. As the geosynclinal troughs subsided, especially in the New England salient, volcanics were extruded and sediments that were derived from the craton, from geanticlines, from volcanic accumulations, and from intrageosynclinal uplifts, were deposited mainly in the troughs. Ultramafic, mafic, and intermediate plutonic rocks were first emplaced at the end of the Cambrian or beginning of the Ordovician in the eugeosynclinal zone, and the ultramafics were transported northwestward tectonically as serpentinization continued. Albitic granitic plutons were emplaced in the Early or Middle Ordovician. Regional foliation that had first appeared in the Cambrian as the geosynclinal troughs subsided continued to form. In the Middle Ordovician, stillstand of the Vermont-Quebec and Stoke Mountain geanticlines gave way to general uplift and denudation which included a westward sliding of the Taconic allochthon. During the late Middle and Late Ordovician, the Somerset geanticline appeared, granitic rocks were emplaced, and the other geanticlines continued as sources of sediments deposited in adjacent geosynclinal troughs, including the exogeosyncline. New generations of early folds formed as geosynclinal subsidence and uplift was renewed. The early Paleozoic closed with general uplift and erosion at and northwest of the Somerset geanticline, culminating in the climax of the Taconic disturbance. The northwestern part of the orthogeosyncline stabilized to a quasi-cratonic belt early in the middle Paleozoic. The miogeosynclinal zone overlapped south-eastward on the eugeosynclinal zone and eventually across the Stoke Mountain geanticline in the Late Silurian and Early Devonian. In the Late Silurian, rapid subsidence resumed in a geosynclinal trough southeast of both the Stoke Mountain geanticline and the southern part of the Vermont-Quebec geanticline that contained the belt of lateral transition from the miogeosynclinal to the eugeosynclinal zone. Meanwhile, the Somerset geanticline continued as a source of part of the eugeosynclinal clastics. An intrageosynclinal uplift from which sediments, recumbent folds, and intrastratal diapiric folds moved northwest and possibly southeast, probably formed in the geosynclinal trough southeast of the Somerset geanticline. Mafic to felsic intrusive rocks, especially concordant calc-alkalic plutons, continued to be emplaced and the regional foliation continued to form in the eugeosynclinal zone. Growth of the domes and arches and concomitant evolution of the late longitudinal folds and thrust faults during the Acadian orogeny climaxed the middle Paleozoic. The discordant calc-alkalic plutons were emplaced soon after, and then, 360 m.y. ago, northwest of the Merrimack synclinorium uplift and erosion followed, as did cooling, opening of joints, and restarting of K-Ar systems. In the late Paleozoic the Merrimack synclinorium stood still, or possibly resumed subsidence to form the northwestern extremity of the epieugeosyncline that is preserved in southeastern New England. The epieugeosyncline was folded, faulted, and uplifted in the Appalachian orogeny, and then, with the adjacent Acadian uplift, was deeply eroded in the early Mesozoic. The taphrogeosyncline in southern New England was formed in the early Mesozoic and was followed in the middle Mesozoic by the alkalic intrusives. Thereafter until the present time, the Paleozoic and Mesozoic terranes were selectively weathered and eroded, and streams that possibly survived from the Appalachian orogeny flowed north-westward in northwestern New England and adjacent Quebec.

Abstract Massive sulfide deposits of the Vermont copper belt yielded approximately 3.6 Mt of ore during intermittent production from 1793 to 1958. The deposits consist of stratabound and generally stratiform pyrrhotite, chalcopyrite, and minor sphalerite and pyrite within metasedimentary rocks and minor mafic metavolcanic rocks of Silurian to Early Devonian age. At the largest deposits (Elizabeth, Ely, Pike Hill), massive sulfides are generally associated with metabasaltic amphibolite. The deposits are structurally complex, and have been deformed together with their host rocks during two stages of nappe-related, largely isoclinal folding, and during a later stage of dome-related folding; syntectonic shears and thrust faults commonly mark the contacts between massive sulfide bodies and silicate wall rocks. Postore re-gional metamorphism took place under amphibolite-grade conditions, producing locally abundant kyanite and staurolite in pelitic country rocks during peak prograde events. Geochemical studies of clastic metasedimentary host rocks in the district indicate a significant mafic component that suggests a continental island-arc provenance. The amphibolites, in contrast, have immobile trace element and rare earth element (REE) geochemical signatures similar to that of midocean ridge basalt (MORB). Lithologically unusual wall rocks at the Elizabeth deposit, including coarse garnet-mica schist, laminated plagioclase-rich granofels, quartz-mica-carbonate schist, tremolite-phlogopite schist, and quartz-albite tourmalinite, have high contents of Cr and MORB-type REE patterns that suggest protoliths of tholeiitic basalt. Massive sulfide, metachert, Mn-rich garnet-quartz rocks (coticule), and magnetite iron formation in the district are believed to have formed as exhalative chemical precipitates on the sea floor. Chemical analyses of unoxidized massive sulfide from the Elizabeth, Ely, and Pike Hill mines show that in addition to very high Cu (to 23.6 %) and in rare cases very high Zn (to 26.2 %), some ore samples contain minor Ag (to 100 ppm), Au (to 0.85 ppm), Cd (to 1500 ppm), Co (to 1469 ppm), Mn (to 5600 ppm), Mo (to 420 ppm), and Se (to 87 ppm). The ores have uniformly low As, Ba, Bi, Cr, Hg, Ni, Pb, REEs, Sb, Sn, Te, Th, Tl, U, and W. The overall geologic and geochemical features of the Vermont copper belt ores are similar to those of the Besshi deposits in Japan. Possible modern analogs include the actively forming massive sulfides of Guaymas Basin in the Gulf of California, Escanaba Trough on the Gorda Ridge, and Middle Valley on the Juan de Fuca Ridge.

Abstract T he F irst day of the field trip covers the regional geology of the Vermont copper belt and a visit to the Elizabeth mine, near South Strafford, Vermont (Fig. 1, Stops 13). The second day of the trip is a half-day visit to the Ely mine near West Fairlee, Vermont (Fig. 1, Stops 4 and 5). Several of our stops were included in the 1993 Society of Economic Geologists Guidebook Volume 17 trip titled “Besshi-type Massive Sulfide Deposits of the Vermont Copper Belt” (Slack et al., 1993). The purpose of that trip was to acquire an understanding of the regional stratigraphy, structure, and genesis of the mineral deposits. The purpose of our trip is quite different. This trip will examine the environmental geochemistry and mining history of massive sulfide deposits in the Vermont copper belt. Massive sulfide deposits are among the most likely types of mineral deposits to develop acid mine drainage because (1) ores are enriched in iron-sulfide minerals which are likely to produce acid upon weathering; (2) iron-sulfide minerals (pyrrhotite and pyrite) are ubiquitous as gangue minerals that end up in flotation tailings and mine waste; (3) copper, lead, zinc and other sulfide minerals are present in ore assemblages, so weathering can release a variety of heavy metals; and (4) host rocks typically are carbonatepoor metasedimentary or metavolcanic rocks that have little or no capacity to neutralize acid. Streams draining both the Elizabeth mine (Copperas Brook) and the Ely mine (Ely Brook) are impacted by acid mine drainage. In