ABSTRACT Detailed diagenetic studies of the late Cambrian Alum Shale in southern Sweden were undertaken across an interval that includes the peak Steptoean Positive Carbon Isotope Excursion (SPICE) event to evaluate the pyrite mineralization history in the formation. Samples were collected from the Andrarum-3 core (Scania, Sweden); here the Alum was deposited in the distal, siliciclastic mudstone-rich end of a shelf system. Abundant cryptobioturbation is observed in the Alum, which points to oxic–dysoxic conditions prevailing during deposition. Petrographic examination of polished thin sections ( n = 65) reveals the presence of numerous texturally distinct types of pyrite, including matrix framboids, two different types of framboid concretions (those with rims of iron-dolomite and those lacking rims), disseminated euhedral pyrite crystals, concretions of euhedral pyrite crystals, overgrowths of pyrite on these different pyrite generations, anhedral pyrite intergrown with bedding parallel mineralized fractures (i.e., “beef”), and massive vertical/subvertical accumulations of pyrite. Paragenetic relationships outline the relative timing of formation of the texturally distinct pyrite. Framboids and framboid concretions formed prior to precipitation of any euhedral pyrite crystals, and these pyrite generations precipitated prior to the pyrite overgrowths on them. As Alum Shale sediments are all distorted by these texturally different pyrite generations, they are likely to have formed early in the postdepositional history of the formation. In contrast, pyrite associated with “beef” is likely temporally related to the onset of hydrocarbon generation, which in this part of Sweden is thought to have been many tens of millions of years after deposition. Because vertical/subvertical massive pyrite features distort “beef,” they clearly postdate it. Of all these pyrite textures, only framboid concretions appear to be restricted to the SPICE interval. The texturally distinct nature of the pyrite generations, along with evidence of their formation at different times in the postdepositional history of the Alum Shale, is the key outcome of this petrographic study. Because the petrographic data presented herein point to a postdeposition origin for all generations of pyrite, diagenetic processes—not those processes associated with deposition—were responsible for the complex pyritization history observed in the Alum, in the Andrarum-3 core.

Abstract The strata of the Steptoean Stage (Figure 1 ) are exposed in several mountain ranges across the eastern Great Basin of western Utah and eastern Nevada (Figure 2 ). Palmer (1962 , 1965 ) described the trilobite faunas of this interval, and many subsequent studies have focused on the faunal provincialism, paleoenvironments, and biochronostratigraphy. The Steptoean positive isotope carbon excursión (SPICE) event spans this interval, with a δ 13 C maximum occurring in the Dunderbergia Zone, near the middle of the succession ( Saltzman et al., 1998 ). The interpreted sea level changes during this interval have been somewhat controversial (e.g., Palmer, 1965 ; Lochman-Balk, 1970 ). Evans (1997) described the depositional environments of the Steptoean and has interpreted that these strata record two major sea level falls during the Dunderbergia and early Elvinia Chrons and a major sea level rise during the late Elvinia Chron. Saltzman et al. (2004) considered that the SPICE maximum coincided with a sea level fall in the latest Dunderbergia Chron, which they considered to be the Sauk II-III unconformity. This chapter provides an overview of the depositional environments of the Steptoean Stage, together with a series of gamma-ray profiles that help illustrate the sequence stratigraphy. The gamma-ray profiles make it possible to correlate measured stratigraphic sections with one another and to correlate them with subsurface well logs (see Evans et al., 2012 ).

Abstract The sedimentological and ichnological data of the Mila Group in the Alborz Basin, northern Iran indicate that the appearance of exotic facies and resurgence of microbialites resulted from the development of extraordinary palaeoceanographic conditions with widespread environmental stress and enhanced precipitation of CaCO 3 . Inhospitable environmental conditions in the Mila Group platform led to a considerable reduction in ichnodiversity, bioturbation intensity and depth and size of burrows, which led to periods of dominating calcimicrobe ecology. The development of exotic or anachronistic facies started around the Cambrian Stage 4–Wuliuan boundary, probably simultaneous with the SPICE event, whereas the Furongian exotic facies period probably took place simultaneous with the HERB event. Biotic and physico-chemical changes in the ocean during these events may have led as well to the virtual absence of the mixed layer and infaunal ecospace utilization in the deposits of the Mila Group. Nevertheless, the local presence of metazoan-microbial build-ups that established between the two suggested exotic facies developments indicates that these periods started at the Cambrian Stage 4–Wuliuan boundary interval, but a fluctuation of abnormal palaeoceanographic conditions and ambient normal marine conditions took place during the Miaolingian and Furongian in the Alborz Basin as a representative of the northern Gondwanan margin.