Abstract Calcic pedocomplexes in the Siluro-Devonian Old Red Sandstone (ORS) of the Anglo-Welsh Basin (UK) have traditionally been interpreted as paleosols developed in dryland depositional environments. Their recognition has been used to indicate a range of controls, including climate, landscape stability, sedimentation rate, soil residence time, and proximity to alluvial channels (the pedofacies concept). A study of the Devonian Ridgeway Conglomerate Formation (RCF) in Pembrokeshire, southwest Wales, has, however challenged some of these notions, recognizing that many calcretes were not developed in soil horizons. The RCF was deposited as part of a dryland alluvial fan and axial fluvial valley complex. Regionally, structural blocks and basins were defined by a series of extensional faults, with the RCF being deposited in a half-graben as a hanging-wall alluvial fan. The RCF is heterolithic, comprising conglomerates, sandstones, and mudstones that reflect differences in processes, suggesting sheetfloods, low-relief lateral accretion, and cohesive debris flows across the alluvial fan. Pedogenic calcretes are common in all areas of the fan and axial fluvial zone. In mudstone and sandstone-grade lithofacies they comprise common horizonated nodules and subhorizontal crystallaria sheets in association with pedogenic indicators such as drab haloes, desiccation cracks, and ped textures. Also observed are both horizontal and vertical root traces, some of which have been the focus of micrite nodule growth (rhizogenic calcretes). Wedge-shaped peds are absent. Pedogenic profiles display upward-increasing percentages of nodules, and may be capped by blocky, massive calcrete and laminated micrite that developed in small ponded areas. In gravel-grade lithofacies, the pedogenic expression is different, and comprises carbonate-coated clasts with pendant and pore-occluding calcrete fabrics. Pedogenic calcretes are best developed in proximal areas of the fan, possibly on terraces adjacent to fan-channel entrenchment zones (the pedofacies concept). Proximal fan areas may also have had increased soil residence times due to reduced sedimentation rates compared to distal fan and axial fluvial valley zones. In distal fan and axial alluvial zones, thin layerbound micritic groundwater calcretes are common, typically being sharp based with upper surfaces comprising vertical and cylindrical nodules that possibly developed in the capillary-fringe zone. Inclined heterolithic bedsets, the deposits of laterally accreted ephemeral channels also commonly contain layer-bound micritic calcretes, again interpreted as having a groundwater origin. Lake-margin calcretes comprising centimeter-thick, laminated micrite, represent possible calcretized matgrounds in fan-toe, ephemeral ponds. The identification of common non-pedogenic calcretes in the RCF begs the question: how much of the ORS calcretes are similarly non-pedogenic in nature? Our analysis may act as a cautionary check for subsurface work where carbonate horizons in alluvial suites are being modelled solely in accordance with the pedofacies concept.