Abstract The Kibali district in the Democratic Republic of Congo hosts the large Karagba-Chaffeur-Durba (KCD) deposit and smaller satellite deposits that together contained 20 million ounces (Moz) of gold when mining recommenced in 2013. An additional 3 Moz of gold was probably mined from the district before 2013. Gold deposits in the Kibali district are located along the KZ trend, a series of folds, contractional shear zones, and altered lithostratigraphic units that coincide with the margin of an earlier 2630 to 2625 Ma intraorogenic basin within the Neoarchean Moto belt. Fluids first responsible for barren carbonate-quartz-sericite alteration, and later for siderite and/or ankerite (±quartz, magnetite, pyrite, and/or chlorite) alteration with associated auriferous pyrite ± rare arsenopyrite veinlets, infiltrated and replaced the siliciclastic, banded iron formation (BIF), and chert host rocks via fold axes, shear zones, and reactive BIF horizons. The complex shape and gentle northeast plunge of the lodes across the Kibali district reflect the shape and plunge of coincident folds that formed during early barren alteration. Many other folded BIF horizons across the wider Moto belt remain barren or only weakly mineralized, suggesting deep extensional structures that may have developed in the vicinity of the KZ trend during basin opening and prior to gold mineralization, were important fluid pathways during later contractional deformation and mineralization.