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Naica Mine

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Series: Geological Society, London, Special Publications
Published: 01 January 2018
DOI: 10.1144/SP466.4
EISBN: 9781786203786
... Abstract The mine caves of Naica (Chihuahua, Mexico) are famous because they host large gypsum crystals. Mine works intersected new caves hosting the largest crystals in the world in the year 2000. From 2006 these caves became the object of a multidisciplinary research project with the goal...
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Journal Article
Journal: Economic Geology
Published: 01 February 1979
Economic Geology (1979) 74 (1): 95–108.
...R. J. Erwood; S. E. Kesler; P. L. Cloke Abstract Naica is a chimney-manto, limestone-replacement, skarn-sulfide deposit typical of those that have yielded much of the silver, lead, and zinc production of the western hemisphere. Fluid inclusions in fluorite deposited throughout late skarn and most...
Image
The giant gypsum crystals of the Naica mine, Mexico. (A) Geology of the Naica mine indicating the location of the different cavities filled with gypsum crystals. Adapted fromGarcia-Ruiz et al. (2007). The red lines indicate the major faults in the Naica range. (B) Cave of Swords located at level −120 m (Degoutin 1912) and (C) Cave of Crystals located at level −290 m. (D) Solubility curves of gypsum and anhydrite as a function of temperature, indicating the difference in supersaturation for the Cave of Swords and Cave of Crystals. The inset illustrates the release of Ca2+ and SO42− ions from dissolving anhydrite, which are subsequently incorporated into growing gypsum.
Published: 01 February 2025
Figure 1. The giant gypsum crystals of the Naica mine, Mexico. ( A ) Geology of the Naica mine indicating the location of the different cavities filled with gypsum crystals. A dapted from G arcia -R uiz et al . (2007) . The red lines indicate the major faults in the Naica range. ( B ) Cave
Image
Figure 1. Cross section of Naica mine. Mine exploits hydrothermal Pb-Zn-Ag deposit with irregular manto and pipe morphologies entirely enclosed in subhorizontally dipping carbonates (not represented for simplicity). Cavities of gypsum crystals are located in carbonates close to main and secondary faults. Galleries have been excavated down to −760 m, requiring average pumping rate of 55 m3/min to depress groundwater to –580 m with respect to phreatic level located at –120 m; Naica and Gibraltar faults act as main drains.
Published: 01 April 2007
Figure 1. Cross section of Naica mine. Mine exploits hydrothermal Pb-Zn-Ag deposit with irregular manto and pipe morphologies entirely enclosed in subhorizontally dipping carbonates (not represented for simplicity). Cavities of gypsum crystals are located in carbonates close to main and secondary
Image
April 2007: “Cave of Crystals” in the Naica mine, Chihuahua, Mexico. See García-Ruiz et al., https://doi.org/10.1130/G23393A.1. Photo by: Javier Trueba (Madrid Scientific Films).
Published: 16 February 2022
Figure 5. April 2007: “Cave of Crystals” in the Naica mine, Chihuahua, Mexico. See García-Ruiz et al., https://doi.org/10.1130/G23393A.1. Photo by: Javier Trueba (Madrid Scientific Films).
Series: DNAG, Geology of North America
Published: 01 January 1991
DOI: 10.1130/DNAG-GNA-P3.259
EISBN: 9780813754703
... Abstract The Naica mining district is located in the municipality of Saucillo in south-central Chihuahua State, 110 km directly southeast of Chihuahua, the state capital, at an altitude of 1,382 m and geographic coordinates 27°52′00″N, 105°26′15″W (Fig. 1). Access to the district is by a 26-km...
Journal Article
Published: 01 March 2016
The Journal of Geology (2016) 124 (2): 235–245.
... selenite crystals in the Naica mine (Chihuahua, Mexico). Gypsum was precipitated in the laboratory from CaSO 4 -NaCl-H 2 O solutions across a broad temperature range to establish the isotopic fractionation behavior of the sulfate molecule between the solid and dissolved phase. Oxygen isotopes show...
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Journal Article
Journal: Economic Geology
Published: 01 September 1959
Economic Geology (1959) 54 (6): 1002–1034.
...John Grover Stone Abstract In the Naica mining district of N-central Mexico, pyrometasomatic and mesothermal replacement bodies of base-metal sulfides with minor amounts of Ag and Au occur in a thick sequence of locally marmorized Cretaceous limestone. The only igneous rocks known in the Sierra de...
Series: Society of Economic Geologists Guidebook Series
Published: 01 January 1990
EISBN: 9781934969595
... Abstract The main item of interest is the visit to the Naica mine, which is reached by travelling southwards along valley floors to Delicias, and then southwestward to the mining community. The deposits comprise a lead-zinc-silver assemblage and are well developed in numerous mantos and breccia...
Journal Article
Journal: Geology
Published: 01 April 2007
Geology (2007) 35 (4): 327–330.
...Figure 1. Cross section of Naica mine. Mine exploits hydrothermal Pb-Zn-Ag deposit with irregular manto and pipe morphologies entirely enclosed in subhorizontally dipping carbonates (not represented for simplicity). Cavities of gypsum crystals are located in carbonates close to main and secondary...
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Journal Article
Journal: Geology
Published: 01 December 2013
Geology (2013) 41 (12): e305.
..., Mexico. The authors focus on two of the several caves documented in that underground mine, namely Cueva de las Espadas (depth: –120 m) and Cueva de los Cristales (depth: –290 m). Note that the 1 °C correction brings better agreement between fluid inclusion data and geological constraints at Naica...
Image
Figure 3. Isotope composition of sulfate molecules in gypsum, anhydrite, and water collected at Naica mine. Polygonal surface enveloping the isotope composition of water from which the gypsum crystals grew is obtained by subtracting from the gypsum values the enrichment factor of 1.65‰ for sulfur and 3.3‰ for oxygen (Thode and Monster, 1965).
Published: 01 April 2007
Figure 3. Isotope composition of sulfate molecules in gypsum, anhydrite, and water collected at Naica mine. Polygonal surface enveloping the isotope composition of water from which the gypsum crystals grew is obtained by subtracting from the gypsum values the enrichment factor of 1.65‰ for sulfur
Image
(A) Coccolithophore cells covered with protective calcified scales, called coccoliths, which are produced in an intracellular compartment and then secreted to the surface. Photo: A. Taylor. (B) Chalk cliffs along the English Channel, formed by the sedimentation and subsequent compaction of microscopic mineralized plankton (c.f. image A) on the sea floor. Photo: Kallerna. (C) Evaporation pounds in Salinas Grandes (Argentina), one of the earliest applied crystallization techniques used by humankind. Photo: G. Rivero. (D) Idiomorphic gypsum crystals from the Naica Mine, Mexico (width of large crystal ~30 cm).
Published: 01 February 2025
compaction of microscopic mineralized plankton (c.f. image A ) on the sea floor. P hoto : K allerna . ( C ) Evaporation pounds in Salinas Grandes (Argentina), one of the earliest applied crystallization techniques used by humankind. P hoto : G. R ivero . ( D ) Idiomorphic gypsum crystals from the Naica Mine
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Figure 4. A: Variation of anhydrite and gypsum solubility with temperature for three different values of salinity: (0) for pure calcium sulfate solutions; (1) for salinity equal to and (2) twice that found in present-day water collected at Naica mine. B: Induction time for homogeneous and heterogeneous nucleation calculated for supersaturated solutions forming by differences in solubility between anhydrite and gypsum at different temperatures. C: Homogenization temperatures of 31 fluid inclusions showing actual temperature of growth.
Published: 01 April 2007
Figure 4. A: Variation of anhydrite and gypsum solubility with temperature for three different values of salinity: (0) for pure calcium sulfate solutions; (1) for salinity equal to and (2) twice that found in present-day water collected at Naica mine. B: Induction time for homogeneous
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Isotope composition analysis (δ34S and δ18O) of dissolved sulfate, anhydrite, and gypsum samples obtained at different locations inside the Naica Mine (Chihuahua, Mexico). The arrows indicate the fractionation (dashed, or inverse, dash-dotted) during gypsum precipitation from solution using the experimental values obtained in this work for Δ34Sgypsum-fluid = 1.7 and for Δ18Ogypsum-fluid = 3.0 (average of the values obtained at 40° and 60°C for low-ionic-strength experiments; fig. 1a, 1d).
Published: 01 March 2016
Figure 3. Isotope composition analysis (δ 34 S and δ 18 O) of dissolved sulfate, anhydrite, and gypsum samples obtained at different locations inside the Naica Mine (Chihuahua, Mexico). The arrows indicate the fractionation (dashed, or inverse, dash-dotted) during gypsum precipitation from
Journal Article
Journal: Elements
Published: 01 February 2025
Elements (2025) 21 (1): 46–53.
...Figure 1. The giant gypsum crystals of the Naica mine, Mexico. ( A ) Geology of the Naica mine indicating the location of the different cavities filled with gypsum crystals. A dapted from G arcia -R uiz et al . (2007) . The red lines indicate the major faults in the Naica range. ( B ) Cave...
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Journal Article
Journal: Geology
Published: 01 December 2013
Geology (2013) 41 (12): e306.
... Garofalo P.S. Fricker M.B. Günther D. Forti P. Mercuri A.-M. Loreti M. Capaccioni B. , 2010 , Climatic control on the growth of gigantic gypsum crystals within hypogenic caves (Naica mine, Mexico)? : Earth and Planetary Science Letters , v. 289 , p. 560 – 569 , doi:10.1016...
Journal Article
Journal: Geology
Published: 16 February 2022
Geology (2022) 50 (3): 259.
...Figure 5. April 2007: “Cave of Crystals” in the Naica mine, Chihuahua, Mexico. See García-Ruiz et al., https://doi.org/10.1130/G23393A.1. Photo by: Javier Trueba (Madrid Scientific Films). ...
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Journal Article
Journal: Geology
Published: 01 February 2013
Geology (2013) 41 (2): 119–122.
... at different sites in the Naica mine. (For more details, see the GSA Data Repository 1 .) We used an amplified Ti:sapphire femtosecond-laser system (Coherent, Inc.) to induce the vapor bubble in metastable monophase inclusions ( Krüger et al., 2007 ). Subsequent microthermometric measurements were...
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Journal Article
Journal: Geology
Published: 15 October 2019
Geology (2019) 47 (12): 1161–1165.
... of the CC-BY license. One of the milestones of recent mineralogy has been the discovery of large gypsum crystals in different locations around the planet ( García-Ruiz et al., 2008 ). Among them, the most spectacular is the Cave of Crystals in Naica (Mexico). However, there are other places...
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