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NaCl-KCl-H2O

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Solubility diagram for the system KCl-NaCl-H2O. A solution of composition A, in contact with a crystal of NaCl, reequilibrates by moving towards the eutonic point E. At any point along the reaction path, the molar amount of NaCl dissolved is greater than the molar amount of KCl precipitated.
Published: 01 October 2002
F ig . 8. Solubility diagram for the system KCl-NaCl-H2O. A solution of composition A, in contact with a crystal of NaCl, reequilibrates by moving towards the eutonic point E. At any point along the reaction path, the molar amount of NaCl dissolved is greater than the molar amount of KCl
Journal Article
Journal: Economic Geology
Published: 01 March 2009
Economic Geology (2009) 104 (2): 157–184.
... pressure of ~1 kbar, from high temperature (670°–400°C), saline and iron-rich (>50 wt % NaCl equiv, NaCl ± KCl ± FeCl 2 ) magmatic fluids (garnet δ 18 O H2O = 7.2–8.5‰) with intermediate oxygen fugacity. Iron ore and retrograde exoskarn assemblages formed under hydrostatic condition after the fracturing...
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Journal Article
Published: 01 October 2018
Mineralogical Magazine (2018) 82 (5): 1169–1185.
... in LVHS, LV 1  and LV 3  inclusions is between –35°C and –40°C, suggesting high concentrations of divalent cations (i.e. Ca, Mg and Fe) in addition to Na and K (Crawford, 1981 ). LV 2  inclusions show a T e of about –21/–23°C, suggesting that NaCl ± KCl are the principal salts in solution. Fig. 5...
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Journal Article
Published: 04 August 2022
Geological Magazine (2023) 160 (1): 1–21.
... , final ice-melting; T m NaCl , halite dissolution; T m KCl , sylvite dissolution; Th total , total homogenization temperature to liquid or vapour; n , the total number of available analyses inclusions of each FIA. Fig. 6. Photomicrographs of typical fluid inclusions in vein quartz from...
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Fig. 8.  Temperature vs. salinity diagrams for selected fluid inclusion samples. Geologic data pertinent to interpretation and a key to symbols are contained in Figure 7. Where a number also appears in a box, this indicates the number of points associated with the symbol plotted at that location. All liquid-rich inclusions are simply plotted at the appropriate temperature, in the manner of a histogram, below the horizontal line at the bottom of each diagram; for the system H2O-NaCl-KCl, these would have salinities of less than 29 wt percent. For CX-158-1416, fields of points are outlined for obviously secondary fluid inclusions (many displaying negative crystal habits) that were assigned to two particular planes during petrographic examination made prior to heating. Note that the salinity scale is condensed by 50 percent in the upper two diagrams compared to the lower three. For samples illustrated from the suite of assemblages above intrusive centers (bottom four diagrams), there is a general trend of decreasing temperature and decreasing maximum salinity in the sequence from top to bottom after geologic constraints (Fig. 7) are considered.
Published: 01 January 2004
at that location. All liquid-rich inclusions are simply plotted at the appropriate temperature, in the manner of a histogram, below the horizontal line at the bottom of each diagram; for the system H2O-NaCl-KCl, these would have salinities of less than 29 wt percent. For CX-158-1416, fields of points are outlined
Journal Article
Published: 01 October 2007
European Journal of Mineralogy (2007) 19 (5): 671–680.
... the quality of the paper. This work was funded by the DFG (project Ho1337/11). References Anderko , A. & Pitzer , K.S. ( 1993 a): Phase-equilibria and volumetric properties of the systems KCl-H 2 O and NaCl-KCl-H 2 O above 573 K - Equation of state representation . Geochim. Cosmochim...
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Journal Article
Journal: Economic Geology
Published: 01 August 2008
Economic Geology (2008) 103 (5): 957–980.
... - 0.01–0.06 0–0.02      X H2O 0.78–0.88 0.40–0.88 0.86      X NaCl 0.01 0.01–0.07 0.01     Th (°C) 332–339 310–410 327–409 Aqueous Type 3a Type 3b Type 3a Type 3b Type 3a Type 3b     System NaCl-MgCl 2 NaCl-KCl NaCl-MgCl 2 NaCl-KCl NaCl-MgCl 2 NaCl-KCl...
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Journal Article
Published: 28 November 2016
Canadian Journal of Earth Sciences (2017) 54 (4): 393–408.
... and Geochemistry , 47 : 539 – 614 . 10.2138/rmg.2002.47.13 . Bischoff , J.L. 1991 . Densities of liquids and vapors in boiling NaCl-H2O solutions: A PVTX summary from 300°C to 500°C . American Journal of Science , 291 : 309 – 338 . 10.2475/ajs.291.4.309 . Burke , E.A.J. 2001...
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Journal Article
Published: 22 August 2018
Canadian Journal of Earth Sciences (2019) 56 (1): 16–31.
... equation and table for determining the freezing point depression of H2ONaCl solutions . Geochimica et Cosmochimica Acta , 57 ( 3 ): 683 – 684 . doi: 10.1016/0016-7037(93)90378-A . Brown , P.E. , and Hagemann , S.G. 1995 . MacFlinCor and its application to fluids in Archean lode-gold...
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Journal Article
Journal: Economic Geology
Published: 01 January 2013
Economic Geology (2013) 108 (1): 79–110.
... varied between −26° and −21°C ( Table 2 ), indicating that the dominant salts were NaCl and KCl. Eutectic temperatures of type Ia inclusions in Cu-Zn-Sn veins could not be determined due to the small inclusion size. Primary type Ib aqueous inclusions in the vein greisens had eutectic temperatures between...
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Journal Article
Published: 01 December 2017
American Mineralogist (2017) 102 (12): 2457–2466.
... in NaCl-H 2 O. Under all conditions, monazite and xenotime dissolve congruently. The solubility of synthetic monazite increases from 8 ppm in pure H 2 O to 335 ppm at X KCl = 0.506. The solubility of synthetic xenotime rises from 46 ppm in pure H 2 O to 126 ppm at X KCl = 0.348, above which it is constant...
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Journal Article
Published: 17 January 2025
American Mineralogist (2025)
... with ice formation at temperatures 499 between -49.5 °C and -22.5 °C. Then, during temperature recovery, initial melting was observed 500 between -26.4 °C and -19.5 °C (eutectic temperature), indicating that the fluid phase belongs to 501 the H2O-NaCl-KCl system (Davis et al. 1990). Final melting occurred...
Journal Article
Published: 01 February 2015
American Mineralogist (2015) 100 (2-3): 522–535.
... runs with comparatively low a H2O since reactions 1 and 2 require H 2 O to react with the platinum chloride salts to form HCl. The phase relations of HSL ± vapor for NaCl-H 2 O, KCl-H 2 O, and KCl-NaCl-H 2 O systems are well established ( Bodnar et al. 1985 ; Chou 1987 ; Driesner and Heinrich...
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Journal Article
Published: 01 February 2017
American Mineralogist (2017) 102 (2): 275–283.
.... For instance, in their solubility study of NaCl and KCl in aqueous fluid, Sterner et al. (1988) delayed crack healing of quartz by cycling pressure between 200 and 600 MPa in the first two hours of the experiment. With this technique, the compression and decompression of the fluid would lead to a continuous...
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Journal Article
Published: 01 July 2007
Reviews in Mineralogy and Geochemistry (2007) 65 (1): 15–47.
... 2007b ). Experimental studies in H 2 O-salt systems are therefore directly relevant to important geologic processes, although some of the above mentioned systems are more adequately described by ternary or quaternary systems (see below). Sodium chloride NaCl, CaCl 2 , and KCl are the most abundant...
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Journal Article
Published: 01 November 2003
American Mineralogist (2003) 88 (11-12): 1943–1948.
... 0.0009914 72.86 ± 0.11 −4.930 ± 0.025 NaCl 11.81 ± 0.24 0.0013856 75.66 ± 0.11 −4.558 ± 0.016 NaNO 3 12.25 ± 0.20 0.0014265 77.06 ± 0.05 −4.511 ± 0.013 KBr 17.49 ± 0.48 0.0019999 82.13 ± 0.09 −4.109 ± 0.030 KCl 20.67 ± 0.51 0.0024386 85.01 ± 0.08 −3.877 ± 0.030...
FIGURES
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A model for the development of mineralization at Clear Creek as constrained by observations, data presented herein, and a bias towards a magmatic origin. (A) Emplacement of magma within extensional zones at ∼2 kbar (5–7 km depth). Chilling of magma forms carapace at top and margins of intrusion. Remaining melt continues to fractionate. Solidus is likely lowered due to significant dissolved CO2 in melt. (B) Continued extension forms sheeted fractures in carapace. Fractures reduce the pressure on melt, causes fluid exsolution, and forms initial ore fluids (81% H2O, 14% CO2, 4% NaCl ± KCl, 1% CH4). Metals are partitioned into the saline aqueous phase. Further reductions in pressure cause fluid unmixing into high- and low-salinity CO2-rich fluids. Melt escapes into extensional zones and forms aplite and pegmatite dykes. Fluids fill and mineralize sheeted fractures with high-temperature (350–300°C) gold-rich veins. (C) Brittle faults develop. Lower temperature (300–250°C) silver-rich assemblage mineralize late structures. (D) Compiled stable isotopic data for the Clear Creek intrusion-related gold systems. Note the similarities of oxygen values between the various rocks, except the silver-rich veins of the contact zone. Calculated fluid values for quartz from the sheeted veins are ∼10% at 325°C. Sulphur isotopes are notably light for the silver-rich veins and cannot be accommodated with lower temperatures but could be due to a sulfur influence from the metasedimentary host rocks.
Published: 27 May 2003
of intrusion. Remaining melt continues to fractionate. Solidus is likely lowered due to significant dissolved CO 2 in melt. (B) Continued extension forms sheeted fractures in carapace. Fractures reduce the pressure on melt, causes fluid exsolution, and forms initial ore fluids (81% H2O, 14% CO 2 , 4% NaCl
Journal Article
Published: 01 October 2004
The Canadian Mineralogist (2004) 42 (5): 1465–1481.
... of halite ranges from 88 to 318°C ( Table 1 ). In the sylvite-and halite-bearing inclusions, sylvite was the first phase to melt between 50 and 157°C, whereas halite melted from 130 to 281°C, as can be inferred from the H 2 O–NaClKCl diagram in Figure 8 . On the basis of these data, we contend...
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Journal Article
Journal: Economic Geology
Published: 01 March 2010
Economic Geology (2010) 105 (2): 329–338.
... spectra of fluid and crystal mixtures : Canadian Mineralogist , v. 42 , p. 1283 – 1314 . Blidin , V.P. , 1953 , Ternary solubility diagrams for the systems LiCl-NaCl-H 2 O and LiCl-KCl-H 2 O : Doklady Akademii. Nauk S.S.S.R. , v. 88 , p. 457 – 459 . Bodnar , R.J. , 1993...
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Journal Article
Journal: GSA Bulletin
Published: 12 March 2025
GSA Bulletin (2025)
... in the system SiO2-H2O-NaCl at 15 20 kbar and 900 1100 °C: Implications for silica polymerization and the formation of supercritical fluids: Contributions to Mineralogy and Petrology, v. 170, 35, httpsdoi .org /10 .1007 /s00410 -015-1187-7. Dai, F.Q., Zhao, Z.F., Zheng, Y.F., and Sun, G.C., 2019...