Abstract The northernmost coastal sector of the Italian peninsula from the La Spezia Gulf to Monte Pisano, including the Alpi Apuane mountain range, represents a special morpho-structural domain of the inner northwestern Apennines. Described by naturalists since the Roman age, its location on the land and sea track of the Italian Grand Tour makes it a special zone in the Italian peninsula that was visited by some of the most eminent European geologists of the nineteenth century, including Brongniart, Buckland, De la Beche, Hoffman, Escher von der Linth, Murchison and Lyell. The area has been also the homeland of naturalists and scientists who played a significant role during the nineteenth century in the advancement of geological studies in Italy. Thanks to Capellini's ‘Geological map of the La Spezia Gulf and surroundings’ (1863) and Zaccagna's ‘Geological maps of the Alpi Apuane’ (1879–97), the area became central in the history of the foundations of modern Italian geological maps. However, the opportunities provided by early mapping and palaeontological discoveries for developing tectonic concepts were squandered by Italian Apennines geologists, who remained stuck on explanations of autochthonism, thus missing an early recognition of nappe tectonics that was only accepted in the middle of the twentieth century.