U-Pb zircon data from three undeformed to slightly deformed, megacrystic, granitoid plutons in the northern Acatlán Complex of southern México has indicated that all three are part of a larger suite of late Ordovician plutons. 40 Ar/ 39 Ar data from hornblende and biotite show mainly disturbed spectra, but biotite from the Palo Liso and Los Hornos plutons yields plateaus with ages of 305 ± 26 Ma and 157 ± 12 Ma, respectively. These thermal events may be correlated, respectively, with Permo-Triassic and Jurassic tectonothermal events recorded elsewhere in the Acatlán Complex. All three plutons are peraluminous with calc-alkaline affinities, characteristics that are consistent with inherited zircon ages and together suggest a source in Mesoproterozoic calc-alkaline rocks similar to those exposed in the neighboring Oaxaca terrane. We interpret these granites to be related to the early Ordovician separation of peri-Gondwanan terranes from Gondwana during the opening of the Rheic Ocean. Elsewhere in the Acatlán Complex, Ordovician megacrystic granitoids of the Piaxtla Suite were subjected to high-grade metamorphism, which we infer to be related to subduction along the Gondwanan margin during the Devonian–Carboniferous. The three plutons reported here were not affected by Devono-Carboniferous metamorphism and thus are inferred to have remained outside the subduction zone.

Abstract Cambrian and Ordovician shelf, platform, and basin rocks are present in Sonora, México, and southern Arizona and were deposited on the southwestern continental margin of North America (Laurentia). Cambrian and Ordovician rocks in Sonora, México, are mostly exposed in scattered outcrops in the northern half of the state. Their discontinuous nature results from extensive Quaternary and Tertiary surficial cover, from Tertiary and Mesozoic granitic batholiths in western Sonora, and from widespread Tertiary volcanic deposits in the Sierra Madre Occidental in eastern Sonora. Cambrian and Ordovician shelf rocks were deposited as part of the southern Laurentian miogeocline on the southwestern continental margin of North America. Lower Cambrian shelf units in Sonora consist mainly of quartzite, siltstone, and silty limestone; limestone increases upward in the sequence. Middle Cambrian shelf rocks consist mostly of limestone, dolostone, and siltstone. Upper Cambrian shelf rocks are sparse in Sonora; where present, they consist chiefly of siltstone and minor limestone. Cambrian shelf rocks display subtle facies changes from west to east across Sonora. In northwestern Sonora, these rocks attain their maximum thickness and may represent the Early Cambrian shelf margin. At the Sierra Agua Verde section, 110 km (68 mi) east of Hermosillo, these rocks thin, have greater proportions of clastic material, and were probably deposited in an inner-shelf setting. A major unconformity is present near the base of the Cambrian in Sonora and is similar to the Sauk I unconformity in the Wood Canyon Formation in Nevada and California. The top of the Cambrian is transitional with overlying Ordovician strata. Cambrian cratonic platform rocks are exposed in northern Sonora and southern Arizona and include the Middle Cambrian Bolsa Quartzite and Middle and Upper Cambrian Abrigo Limestone. The most complete sections of Ordovician shelf rocks in Sonora are 50 km (31 mi) northwest of Hermosillo. In these sections, the Lower Ordovician is characterized by intraclastic limestone, siltstone, shale, and chert. The Middle Ordovician is mostly silty limestone and quartzite, and the Upper Ordovician is cherty limestone and some argillaceous limestone. A major disconformity separates the Middle Ordovician quartzite from the overlying Upper Ordovician carbonate rocks and is similar to the disconformity between the Middle and Upper Ordovician Eureka Quartzite and Upper Ordovician Ely Springs Dolomite in Nevada and California. In parts of northwestern Sonora, Ordovician rocks are disconformably overlain by Upper Silurian rocks. Northeastward in Sonora and Arizona, toward the craton, Ordovician rocks are progressively truncated by a major onlap unconformity and are overlain by Devonian rocks. Except in local areas, Ordovician rocks are generally absent in cratonic platform sequences in northern Sonora and southern Arizona.

The Acatlán Complex of southern México comprises metasedimentary and metaigneous rocks that represent the vestige of a Paleozoic ocean. Juxtaposed against granulite-facies gneisses of Mesoproterozoic (ca. 1 Ga) age, the complex has previously been related to the Iapetus Ocean and interpreted to preserve a tectonostratigraphic record linked to that of the Appalachian orogen: (1) Cambro-Ordovician deposition of a trench or forearc sequence (the Petlalcingo Group: the Magdalena, Chazumba, and Cosoltepec Formations) and an oceanic assemblage (the Piaxtla Group), (2) polyphase Late Ordovician–Early Silurian deformation (the Acatecan orogeny) during which the Piaxtla Group underwent eclogite-facies metamorphism synchronous with megacrystic granitoid emplacement, (3) deposition of the arc-related Tecomate Formation and intrusion of megacrystic granitoid plutons during the Devonian, and (4) deformation under greenschist-facies conditions during the Late Devonian Mixtecan orogeny. However, recent structural, geochronological, and geochemical studies have shown that (1) the Cosoltepec Formation is bracketed between ca. 455 Ma and the latest Devonian and may be part of a continental rise prism with slivers of oceanic basalt; (2) the Magdalena and Chazumba Units represent a clastic wedge assemblage of Permo-Triassic age; (3) the eclogitic metamorphism is locally Mississippian in age; (4) the Tecomate Formation is an arc complex of latest Pennsylvanian–Middle Permian age; (5) the megacrystic granitoid rocks span the Ordovician and have a calc-alkaline geochemistry, whereas accompanying mafic units have mixed continental arc–tholeiitic affinities and are locally as young as the earliest Silurian; (6) the greenschist-facies tectonothermal event occurred in the Permo-Triassic; and (7) the complex records a Jurassic tectonothermal event that resulted in local high-grade metamorphism and migmatization. This revised geological history precludes any linkage to Iapetus, but is consistent with that of the Rheic and paleo-Pacific Oceans and is interpreted to record (1) development of a rift or passive margin on the southern flank of the Rheic Ocean in the Cambro-Ordovician, (2) formation of either an arc or an extensional regime along the formerly active northern margin of Gondwana throughout the Ordovician, (3) ocean closure documented by subduction-related eclogite-facies metamorphism and exhumation during the Late Devonian–Mississippian, (4) Permo-Triassic convergent tectonics on the paleo-Pacific margin of Pangea, and (5) overriding of a Jurassic plume.

Abstract Detrital zircon age populations from Palaeozoic sedimentary and metasedimentary rocks in Mexico support palinspastic linkages to the northwestern margin of Gondwana (Amazonia) during the late Proterozoic–Palaeozoic. Age data from: (1) the latest Cambrian-Pennsylvanian cover of the c . 1 Ga Oaxacan Complex of southern Mexico; (2) the ?Cambro-Ordovician to Triassic Acatlán Complex of southern Mexico's Mixteca terrane; and (3) the ?Silurian Granjeno Schist of northeastern Mexico's Sierra Madre terrane, collectively suggest Precambrian provenances in: (1) the c . 500–650 Ma Brasiliano orogens and c . 600–950 Ma Goias magmatic arc of South America, the Pan-African Maya terrane of the Yucatan Peninsula, and/or the c . 550–600 Ma basement that potentially underlies parts of the Acatlán Complex; (2) the Oaxaquia terrane or other c . 1 Ga basement complexes of the northern Andes; and (3) c . 1.4–3.0 Ga cratonic provinces that most closely match those of Amazonia. Exhumation within the Acatlán Complex of c . 440–480 Ma granitoids prior to the Late Devonian–early Mississippian, and c . 290 Ma granitoids in the early Permian, likely provided additional sources in the Palaeozoic. The detrital age data support the broad correlation of Palaeozoic strata in the Mixteca and Sierra Madre terranes, and suggest that, rather than representing vestiges of Iapetus or earlier oceanic tracts as has previously been proposed, both were deposited along the southern, Gondwanan (Oaxaquia) margin of the Rheic Ocean and were accreted to Laurentia during the assembly of Pangaea in the late Palaeozoic.

ABSTRACT We will embark on a five-day journey through northern, western, and central Sonora, in which we will see excellent examples of mostly Mesozoic to Cenozoic tectonics, sedimentation, and metallogeny. On Day 1, we will visit the porphyry copper deposit at Ajo, Arizona, and several Pleistocene cinder cones and maar craters in the Pinacate Biosphere Reserve. On Day 2, we will see L- and L-S tectonites at the type locality of the Mojave-Sonora megashear in Sierra Los Tanques, Noche Buena orogenic gold deposit, Ediacaran Gamuza beds in Caborca, and have an overview of the Carnero detachment fault on the south side of Sierra La Gloria. Day 3 will explore faults and related sedimentary and volcanic rocks associated with the late Miocene oblique opening of the Gulf of California rift and visit outcrops that record late Miocene timing constraints for flooding of the Gulf of California seaway, including several localities on southern Isla Tiburón accessible only by boat. Day 4 will visit exposures of Permian sedimentary to Paleogene igneous rocks in Hermosillo (Cerro La Campana); Puerto del Sol detachment fault zone; Aconchi batholith and a hot spring localized on a Basin and Range normal fault; Santa Elena low-sulfidation epithermal gold mine; and the Upper Jurassic Cucurpe Formation. On Day 5, we will visit several exposures of different crustal levels of the Magdalena-Madera metamorphic core complex, including the spectacular stretched pebble conglomerates in Arroyo Amolares.

Epithermal ore deposits have traditionally been the most economically important in México, with renowned world-class deposits like those in the Pachuca–Real del Monte, Guanajuato, Fresnillo, Taxco, Tayoltita, and Zacatecas districts. Whereas in certain areas (like the Great Basin in Nevada) intermediate and low sulfidation deposits have been found to be mutually exclusive in time and space; in the case of epi thermal deposits in México, the intermediate and low sulfidation types do not appear to be mutually exclusive and, to the contrary, they coexist in the same regions, formed during the same time spans, and even occur together within a single deposit. These deposits are all Tertiary in age, ranging from middle Eocene to early Miocene, with the possible sole exception of a Paleocene deposit. Their space and time distribution follows the evolution of the continental arc volcanism of the Sierra Madre Occidental and Sierra Madre del Sur. The vast majority of epithermal deposits in México belong to the intermediate (IS) or low (LS) sulfidation types; only a few high sulfidation (HS) deposits have been described in the NW part of the country (e.g., El Sauzal, Mulatos, Santo Niño, La Caridad Antigua, all of them in Sonora and Chihuahua). Because most epithermal deposits in México exhibit composite characteristics of both IS and LS mineralization styles (as well as scarce characteristics of HS), they cannot be simply characterized as IS (polymetallic deposits associated with the most saline brines) or LS deposits (mainly Ag and Au deposits associated with lower salinity brines). Thus, in this paper we propose to use an empirical classification for IS + LS deposits (that is, alkaline/neutral epithermal deposits) into three types of mineralization; namely, A, B, and C. Type A (or IS type) comprises those deposits that generally formed at greater depths from highly saline but unsaturated brines and contain exclusively from top to bottom IS styles of mineralization with a consistent poly-metallic character. Type B (or LS-IS type) comprises those deposits that exhibit dominant LS characteristics but have polymetallic IS roots (Zn-Pb-Cu); this is the most widespread type of epithermal mineralization in México. Types A and B generally exhibit mineralogic and/or fluid inclusion evidence for boiling. Type C (or LS type) comprises those deposits that exhibit only LS styles of mineralization, formed generally by shallow boiling of low salinity fluids, and have relatively high precious metal and low base metal contents. In this paper, we also review other known or attributable aspects of Mexican epithermal deposits, including ore and gangue mineralogy and their evolution in time and space, structure, geothermometry, stable iso topic composition of mineralizing fluids and other components of the deposits, chemistry and sources for mineralizing fluids, and the plausible mechanisms for the mobilization of deep fluid reservoirs and for mineral deposition in the epithermal environment.

Abstract Complex tectonic plate interactions at the end of the Paleozoic and early Mesozoic, particularly the undefined relationship between circum-Atlantic and circum-Pacific tectonic domains, do not permit a complete understanding of the crustal structure of north-central Mexico. Pre-Oxfordian geologic history, especially the existence of Permian-Early Triassic and Late Triassic-Middle Jurassic volcanic arcs, and general crustal structure of north-central Mexico are approached through gravity modeling and analysis of geologic and well data. Bouguer and isostatic residual gravity-anomaly maps were interpreted to illustrate anomalies caused mostly by Mesozoic and Cenozoic tectonic events, including a large-amplitude, northerly trending gradient marking the edge of Cretaceous thrusting in the Sierra Madre Oriental in Tamaulipas and Nuevo León. This gravity gradient diverges in western Nuevo León with one branch trending into southern Coahuila, which also marks the northern limit of Cretaceous thrusting. However, the other branch that trends into northern Nuevo León, may be caused partially by pre-Cretaceous intrusive and metamorphic rocks or changes in the structural style of the thrust belt north of Monterrey. Lower Bouguer and isostatic residual gravity-anomaly values in central Mexico, as compared with eastern Mexico, indicate a thicker crust formed by the addition of Mesozoic magmatic arcs and sedimentary sequences. Smaller-wavelength isostatic residual gravity-anomalies correspond to Late Permian-Early Triassic plutons or density variations in the Precambrian basement rocks in eastern Tamaulipas and Nuevo León, possible Laramide-age intrusions along the Cretaceous thrust front in Tamaulipas and Nuevo León, and Mesozoic sedimentary basins, including the Parras Basin. There is no evidence for large-scale linear anomalies that would correspond to the Late Jurassic Mojave-Sonora megashear transpressive structure across northern Mexico.

ABSTRACT This work presents new geochronological and mineralogical data to investigate the provenance of sediments accumulated in deep-water environments in the southern and southwestern regions of the Gulf of Mexico during the Cenozoic. We integrated U-Pb geochronology with heavy and light minerals data to better understand the provenance of the Paleocene–Miocene strata and the evolution of the sediment source terranes. The analyzed samples came from drill cuttings of sandy levels in five exploration wells offshore in the Gulf of Mexico: Puskon-1, Aktum-1, Kunah-1, Kabilil-1, and Chuktah-201. The material contained abundant barite, a component of the drilling mud. Consequently, a semiquantitative approach to discriminate mineral phases and to quantify concentrations was used. Overall, we recognized 10 zircon populations that range from Proterozoic to Cenozoic ages. Proterozoic ages show a prominent peak at ca. 1.0 Ga and a minor peak at ca. 1.8 Ga. The Neoproterozoic to Cambrian population displays a broad distribution with a peak at ca. 600 Ma. Ordovician–Silurian zircons exhibit minor peaks at ca. 460 and 445 Ma. Devonian and Carboniferous zircons are very scarce in our data set. Permian–Triassic zircons are abundant, and they show a prominent peak at ca. 255 Ma and a minor one at ca. 228 Ma. Jurassic zircons are not common and display several minor peaks at ca. 185, 170, and 155 Ma. The Early Cretaceous population displays a noticeable peak at ca. 120 Ma. Late Cretaceous–Paleocene zircons exhibit several peaks at ca. 92, 82, 72, and 65 Ma. Cenozoic zircons also display several prominent peaks at ca. 40, 35, 25, and 18 Ma. Zircons of Proterozoic to Early Cretaceous ages are interpreted to be derived from the Mesozoic sedimentary cover of basement blocks in southern and eastern Mexico terranes due to their rounded to subrounded morphology. Late Cretaceous and Cenozoic zircons are the most abundant populations in the analyzed samples. These zircon populations exhibit euhedral and subhedral morphology indicating derivation from primary sources in the magmatic arcs. This has important implications in assessing the reservoir quality, since the sediments were directly delivered from the magmatic arc into the deep-water environments. Our results allow us to conclude that the sedimentary provenance of the southwestern and southern strata in the Gulf of Mexico was not associated with Laurentian terranes, as has been proposed for Late Cretaceous–Paleogene strata of northern Mexico and the northern Gulf of Mexico, such as the world-class Wilcox-type hydrocarbon reservoirs. We propose that the provenance of the analyzed strata was related to the tectono-magmatic evolution of the southern Mexico terranes during the Cenozoic; therefore, large NW-SE dispersal systems that eroded Laurentian terranes in the southern United States did not deliver sediments into the southern sectors of the Gulf of Mexico, probably constrained by the Tamaulipas Arch and the Gulf Stream.

Abstract Fluid inclusion and metal-ratio data have been compiled for 52 low-sulfidation precious metal and base metal-rich low-sulfidation epithermal deposits in Mexico. Precious metal deposits typically have inclusion salinities that range from 0 to 7.5 wt percent NaCl equiv, whereas base metal-rich deposits have salinities that are as high as 23 wt percent NaCl equiv. Salinities are typically high in fluids included in sphalerite, suggesting a genetic relationship between base metal mineralization and saline fluids. Silver/gold and Ag + Au/Pb + Zn + Cu ratios correlate with fluid inclusion salinity, a relationship that underscores the importance of chloride complexing in base metal transport and polymetallic mineralization. Fluid inclusion gas chemistry of 21 low-sulfidation epithermal deposits plotted on N 2 -Ar-He and N 2 -Ar-CH 4 diagrams indicate that meteoric, mantle or evolved crustal, and magmatic fluids were present in the ore-forming hydrothermal systems, although in different proportions in individual deposits. The N 2 /Ar ratios of sulfide mineral fluid inclusions are all higher than that of air-saturated water, indicating a mag-matic source, whereas a significant proportion of inclusions in barren gangue minerals have N 2 /Ar ratios near that of air-saturated water. Plots of N 2 /Ar vs. H 2 S/Ar show a correlation between N 2 and H 2 S concentrations. The data suggest that low-sulfidation epithermal deposits in Mexico comprise both meteoric waters and magmatic waters, with a significant contribution of H 2 S of magmatic origin. New oxygen and hydrogen isotope data are presented for seven deposits. Fluids responsible for precious metal and base metal deposition contain consistently heavy oxygen isotope signatures and shifts as high as +10 to +20 per mil from the meteoric water line, regardless of host rock type. Boiling and/or water-rock interaction processes alone cannot explain adequately the consistently heavy oxygen isotope signatures of Mexican low-sulfidation deposits. Rather, these results are best accounted for by a significant contribution of magmatic waters to the deep fluid, subsequently modified by water-rock interaction, boiling, and mixing with meteoric water. A classification of low-sulfidation deposits of Mexico is presented based on depth of formation and whether or not boiling is thought to have occurred in the system. Three end-member types are recognized: shallow with boiling, deep with boiling, and deep without boiling. In shallow-formed deposits boiling fluids rise to depths of <500 m below the paleowater table, and ore occupies a vertical range of a few hundred meters. In deep-formed deposits, boiling occurs at temperatures that may exceed 300°C, and ore is generally deposited between 400 and 1,000 m from the paleowater table as fluids rise within the area of liquid-vapor immiscibility. Vein deposits related to fluids that rise within the liquid-phase field and do not reach the field of liquid-vapor immiscibility deposit ore at depths of >1,000 m below the paleo-water table.

Abstract Deep-water turbidite sandstone reservoirs in the Gulf of Mexico have been sourced from a variety of provenance terrains. As a result, the framework composition of each reservoir in the basin varies widely, including volcanic-rich litharenite (Oligocene Vicksburg), feldspathic-rich lithic arkose (Oligocene Frio), metamorphic-rich feldspathic litharenite (Palaeogene Wilcox), lithic-poor quartzarenite (Miocene), quartz-rich sublitharenite (Cretaceous) and quartz- and feldspar-rich subarkose (Norphlet). Provenance-driven differences in composition have a complex but critical influence on how each of these reservoirs responds to burial-induced changes in depth, fluid pressure, effective stress and temperature. A combination of Petromod® and Touchstone™ modelling programs are used in this study to simulate the influence of provenance on compaction and cementation of the main reservoir types in the Gulf of Mexico. For example, modelling results predict that at higher levels of thermal exposure, some lithic-rich sands, although more ductile and highly compacted, will experience less quartz cementation than less ductile, quartz-rich sands, thereby preserving a higher range of porosity and permeability. Furthermore, modelling results predict that temperature/effective stress/depth windows for optimal reservoir quality preservation vary widely depending on sandstone provenance.