ABSTRACT The Laramide continental arc formed in southwestern North America at about the same time the Sierra Nevadan arc was shutting down, and the Laramide arc was active concurrent with the progress of the Laramide orogeny, from ca. 80 Ma to ca. 45 Ma. East-central Arizona offers an excellent opportunity to explore aspects of tectonics, structural geology, magmatism, and hydrothermal systems in a segment of the Laramide arc that is exceptionally well endowed with porphyry copper deposits. The structure of this region is especially complicated, with multiple generations of normal faults commonly superimposed on originally moderate-angle reverse faults with associated fault-propagation folds. A large new porphyry copper deposit, Resolution, was discovered near Superior in the mid-1990s. The discovery started a new round of development in the mining life cycle at the Resolution deposit; in the region, it contributed to copper exploration again becoming vigorous in the last decade. In the years since discovery of Resolution, important new scientific insights have been gained, including at the regional scale. Post-ore crustal extension exposed multiple levels of Laramide and older igneous and hydrothermal systems at the surface where they can be more easily mapped and sampled, and palinspastic reconstructions of post-mineral normal faulting permit the exposures to be restored to their original positions. The porphyry-related products that are observed at higher levels include local advanced argillic alteration and Cordilleran-style veins and associated mantos, such as at the Magma mine, Resolution deposit, and Old Dominion mine in the shallowest levels of the Superior-Globe-Miami area. Most porphyry copper ore bodies were developed at intermediate depths, where porphyry intrusions exhibit sericitic and potassic alteration and carbonate rocks were converted to skarn, such as in the heart of the Miami-Inspiration, Resolution, Ray, and Christmas deposits. Plutonic rocks are exposed at deeper paleodepths, where pegmatites, quartz veins, and greisen muscovite are locally observed, especially directly beneath porphyry copper orebodies, as in the Schultze and Granite Mountain plutons. Likewise, sodic-calcic alteration may be developed on the deep flanks of porphyry systems, such as adjacent to the Tea Cup pluton. Subsequent Cenozoic extension variously buried or exhumed the hypogene portions of these hydrothermal systems, leading to the development of various supergene products, both in situ and exotic.

ABSTRACT We describe the time-space evolution of a segment of the Laramide arc in east-central Arizona that is associated with porphyry copper mineralization, as constrained by U-Pb zircon geochronology conducted by laser ablation–multicollector–inductively coupled plasma–mass spectrometry. Mid-Cenozoic normal faulting dismembered and tilted many of the plutons and the associated porphyry copper deposits and produced a wide range in depths of exposure. The study area reconstructs to a 75-km-long slice along the arc, with exposures from <1 to >10 km depth. The copper deposits are related to granodioritic to granitic plutons that exhibit variable magmatic sources and locally severe degrees of zircon inheritance. U-Pb zircon ages of plutons in the study area range from 75 to 61 Ma, with dioritic rocks at the older end of the range. The age range of magmatism and mineralization in a cluster of deposits near the Schultze Granite, including the Globe-Miami, Pinto Valley, and Resolution deposits, is from ca. 69–61 Ma. To the south in the Tortilla and Dripping Spring Mountains, the porphyry systems range from ca. 74 Ma at Kelvin-Riverside to ca. 69 Ma at Ray and ca. 65 Ma at Christmas. At several localities where geologic constraints exist, mineralizing plutons were emplaced following Laramide shortening. The ages of the inherited zircon cores correspond fairly closely to the ages of basement rocks in the immediate vicinity of sample sites, implying that similar basement ages and lithologies contributed to the source areas of magmas that produced Laramide porphyry deposits. The U-Pb results on hypabyssal rocks are typically 1–5 m.y. older than previous K-Ar ages, and U-Pb ages on more deeply emplaced plutonic rocks are as much as 5–10 m.y. older. These results are consistent with predictions from thermal modeling and suggest that temporal evolution of the entire Laramide arc needs revision. For this segment of the arc, magmatism was stagnant for ~15 m.y., with minimal migration over time and mineralization occurring episodically over most of that lifespan. There is no simple geographic progression in ages along or across the strike of the arc. Thus, it is difficult to call upon time-specific far-field or plate margin triggers for magmatism or mineralization. The intrusive flux of the Laramide arc appears to be similar to that of the Sierra Nevada arc during the Mesozoic during its “background” periods, rather than during episodes of flare-up. The wide compositional diversity of the Laramide arc is more akin to northeastern Nevada during the onset of extension in the mid-Cenozoic than to the Mesozoic of the Sierra Nevada.

A satisfactory hypothesis of the development of the hydrosphere and atmosphere depends upon evidence from many sciences and the solution of many other fundamental problems of earth history. But because it is so closely related to many other problems, any progress toward unravelling the history of the hydrosphere and atmosphere limits the range of permissible speculation about such distantly related questions as the origin of the solar system, continents, mountains, and living organisms. Several hypotheses of the source of the earth’s air and waters are examined for their consistency with established principles and observed geologic evidence, and special attention is given to the probable composition of the early atmosphere. Hypotheses of the origin of the atmosphere and hydrosphere fall into two chief categories: (1) that all air and water of the earth are residual from a dense primitive atmosphere that once enveloped a molten globe; or (2) that they have accumulated at the earth’s surface by leakage from the interior. The quantities of water, carbon dioxide, organic carbon, nitrogen, sulfur, etc., that have been or are now part of the earth’s atmosphere and hydrosphere may be estimated within reasonable limits of uncertainty and these “excess” volatiles afford a basis for testing chemical consequences of the alternative hypotheses. Several writers have suggested that the primitive atmosphere may have been composed largely of CH 4 and NH 3 . However, the equilibrium constants for reactions of these and other gases, combined with the evidence of the “excess” volatiles, indicate that CO 2 and N 2 are much more likely. The stabilities of methane and ammonia depend upon the presence of free hydrogen; and the escape rate of hydrogen from the earth is such that methane probably could have persisted in significant amounts in the early atmosphere no more than 10 6 to 10 8 years. For all but a relatively brief period at the very beginning of earth history, the atmosphere probably contained CO 2 and N 2 rather than CH 4 and NH 3 . When the consequences of a dense atmosphere of CO 2 and N 2 (but with almost no free O 2 or H 2 ) are examined, it is found that several chemical effects (such as the quantity of rocks that would have to be weathered, of sodium dissolved in sea water, and of CaCO 3 deposited on the sea floor very early in early history) are not borne out by the observed geologic record. From this and other lines of evidence it seems extremely improbable that the present atmosphere and hydrosphere are residual from any such dense primitive atmosphere. Instead, it seems likely that the atmosphere and hydrosphere have accumulated gradually during geologic time by the escape of water vapor, CO 2 , CO, N 2 , and other volatiles from intrusive and extrusive rocks that have risen more or less continuously from the deep interior of the earth. The amount of free oxygen in the early atmosphere is a separate problem that cannot be solved until the evidence of the earliest rocks has been appraised more fully. Current hypotheses of the origin of life appear to require a reducing atmosphere, yet it seems likely that oxygen has been accumulating from the photodissociation of water vapor ever since the earth was formed. The oxidation of ferrous iron and sulfides in the earliest sediments may have kept the oxygen content very low, and life may have begun in local reducing environments.