ABSTRACT Avalonia and Ganderia are composite microcontinental fragments in the northern Appalachian orogen likely derived from Gondwanan sources. Avalonia includes numerous Neoproterozoic magmatic arc sequences that represent protracted and episodic subduction-related magmatism before deposition of an Ediacaran–Ordovician cover sequence of mainly siliciclastic rocks. We characterized the nature of the basement on which these arcs were constructed using zircon grains from arc-related magmatic rocks in Atlantic Canada that were analyzed for their Lu-Hf isotope composition. The majority of zircon grains from Avalonia are characterized by initial 176 Hf/ 177 Hf values that are more radiogenic than chondritic uniform reservoir, and calculated crust formation Hf T DM (i.e., depleted mantle) model ages range from 1.2 to 0.8 Ga. These data contrast with those from Ganderia, which show typically positive initial εHf values and Hf T DM model ages that imply magmatism was derived by melting of crustal sources with diverse ages ranging from ca. 1.8 to 1.0 Ga. The positive distribution of initial εHf values along with the pattern of Hf T DM model ages provide a clear record of two distinct subduction systems. Cryogenian–Ediacaran magmatism is interpreted to have resulted from reworking of an evolved Mesoproterozoic crustal component in a long-lived, subduction-dominated accretionary margin along the margin of northern Amazonia. A change in Hf isotope trajectory during the Ediacaran implies a greater contribution of isotopically evolved material consistent with an arc-arc–style collision of Ganderia with Avalonia. The shallow-sloping Hf isotopic pattern for Paleozoic Ganderian magmatism remains continuous for ~200 m.y., consistent with tectonic models of subduction in the Iapetus and Rheic Oceans and episodic accretion of juvenile crustal terranes to Laurentia.

Abstract The Neoproterozoic tectonomagmatic evolution of West Avalonia comprises four major events. Tectonism started with the formation of a Tonian passive margin on a Baltica-derived ribbon dispersed into the Mirovoi Ocean. Obduction of an oceanic terrane onto the ribbon produced olistostromes, deformation and metamorphism before 750 Ma. Obduction was followed by a Tonian (750–730 Ma) arc on the created composite crust. A pause in magmatism between 730 and 700 Ma is the next event. Subsequently, a Cyrogenian (700–670 Ma) arc was formed, which may have collided with Baltica or another buoyant element nearby. Thereafter, a long-lasting (640–565 Ma) continental arc was erected which, combined with the late Ediacaran–Early Paleozoic sedimentary cover, represents the hallmark of West Avalonia. A Caribbean-style incursion of the Ediacaran arc into the widening Tornquist gap between Amazonia and Baltica led to a diachronous collision with the Ganderian arc. Strike-slip slivering produced a complex transfer of terranes to both: Carolinia and smaller terranes to Ganderia, and East Avalonia to West Avalonia. The Rheic Ocean opened diachronously at c. 500 Ma, following a plate reorganization and re-establishment of an oblique subduction zone beneath Amazonia. As a result, Avalonia and Ganderia became progressively separated and dispersed into the Iapetus Ocean.

The evolution of many modern intra-oceanic and continental arc systems is exemplified by cycles of arc construction, rifting, and separation of remnant and active arcs by a backarc basin floored by oceanic crust. Rifted arc complexes and backarc basins are inherently subductable, and hence only a fragmentary record of rifting and arc construction is preserved in the ancient record. In this contribution, we synthesize available geochronological, geochemical, isotopic, and stratigraphic data in order to discuss the evolution of the Cambrian to Ordovician Penobscot-Victoria Arc, which developed on the leading edge of Ganderia, a peri-Gondwanan microcontinent. Although the Penobscot and Victoria stages of arc-backarc development occurred in a predominantly extensional suprasubduction-zone setting, they each display a distinctly different character of magmatism and sedimentation. These stages are separated by an orogenic episode marked by the obduction of backarc ophiolites onto the Ganderian passive margin. The Cambrian to Lower Ordovician Penobscot Arc is characterized by the continuous migration of the magmatic front and development of multiple volcanically active rift zones. The rift basins display a variety of characteristics, including bimodal calc-alkaline magmatism, felsic-dominated incipient rift magmatism, and formation of rifts floored by tholeiitic to boninitic suprasubduction-zone ophiolite. Comparison to modern analogues suggests that part of the Penobscot Arc area developed in a similar setting to the volcanically active Havre Trough and Taupo volcanic zone. In contrast, the Victoria Arc phase was dominated by multiple epiclastic rich, volcano-sedimentary basins overlying tectonically modified Penobscot basement. Igneous rocks are sparse, typified by calc-alkaline felsic volcanic and tholeiitic to alkaline backarc basin basalts. The change in character of the backarc volcanic rocks over time is interpreted to reflect multiple tectonic factors, including the variation of slab retreat rate, degree of extension in the arc (Cambrian Penobscot Arc) versus the backarc basin (Ordovician Exploits-Tetagouche backarc), reactivation of inverted Penobscot extensional faults during Middle Ordovician rifting, and/or depletion of fertile components by the Middle Ordovician.